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    Communication - Co-electrodeposition of Ni/SiO2(CH2)3SH composite: Modified Guglielmi’s model and mechanism of nucleation

    , Article Journal of the Electrochemical Society ; Volume 164, Issue 13 , 2017 , Pages E472-E474 ; 00134651 (ISSN) Fazlolahzadeh, O ; Rouhollahi, A ; Dolati, A ; Ghahramanifard, F ; Sharif University of Technology
    Electrochemical Society Inc  2017
    Abstract
    This work studies the influence of surface modification of silica nanoparticles by mercaptopropyl trimethoxysilane on silica weight percent in Ni coating during electrodeposition. Results showed SiO2(CH2)3SH particles were embedded in the Ni coating up to 11%. Also, modified Guglielmi’s model and mechanicsm of nucleation of Ni-SiO2(CH2)3SH composite were studied. © 2017 The Electrochemical Society. All rights reserved  

    An electrochemical synthesis of reduced graphene oxide/zinc nanocomposite coating through pulse-potential electrodeposition technique and the consequent corrosion resistance

    , Article International Journal of Corrosion ; Volume 2018 , 2018 ; 16879325 (ISSN) Moshgi Asl, S ; Afshar, A ; Yaghoubinezhad, Y ; Sharif University of Technology
    Hindawi Limited  2018
    Abstract
    Pulse-potential coelectrodeposition of reduced graphene oxide/zinc (rGO-Zn) nanocomposite coating is directly controlled upon a steel substrate from a one-pot aqueous mixture containing [GO-/Zn2+]δ+ nanoclusters. GO nanosheets are synthesized by modified Hummer's approach while Zn cations are produced in the solution and deposited on GO nanosheets using anodic dissolution technique. Eventually, nanoclusters are reduced to rGO-Zn film through an electrochemical process. Chemical composition, surface morphology, and corrosion resistance of the thin film are characterized. Results show that the corrosion resistance of rGO-Zn coating is approximately 10 times more than the bare steel. © 2018 S....