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    An experimental study on permeability, diffusivity, and selectivity of CO2 and CH4 through [bmim][PF6] ionic liquid supported on an alumina membrane: Investigation of temperature fluctuations effects

    , Article Journal of Membrane Science ; Volume 362, Issue 1-2 , 2010 , Pages 346-352 ; 03767388 (ISSN) Barghi, S. H ; Adibi, M ; Rashtchian, D ; Sharif University of Technology
    2010
    Abstract
    In order to define a new temperature correction factor in this study, accurate experimental values were presented for permeability and diffusivity of carbon dioxide and methane in imidazolium-based room temperature ionic liquid: [bmim][PF6] (1-butyl-3-methylimidazolium hexafluorophosphate) immobilized on an inorganic membrane support. Results were presented as a function of temperature and pressure for temperatures within 300-320K and pressures below 50kPa. According to the literature, experimental values of permeability and diffusivity for CH4 in [bmim][PF6] vs. temperature are reported for the first time in this study. Results obtained for CO2 permeability revealed good agreement with data...