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    Formation of Zn-Ca-Ni tri cation's phosphate coating on steel and study that properties

    , Article TMS 2009 - 138th Annual Meeting and Exhibition, San Francisco, CA, 15 February 2009 through 19 February 2009 ; Volume 1 , 2009 , Pages 615-623 ; 9780873397384 (ISBN) Zarei, M ; Afshar, A ; Sharif University of Technology
    2009
    Abstract
    A new Zinc phosphating bath, which produces coatings at relatively lower temperatures within a reasonable time by using of chemical accelerators has been devised. Improvement of the bath performance by the addition of divalent cations like calcium, nickel has been studied. Bath formulation and operating conditions have been optimized by coating weight determinations. Stable samples of phosphating formulations with and without calcium and nickel salts were prepared and the structure and morphology of the phosphate coatings were determined by using X-ray diffraction (XRD) techniques, scanning electron microscopy. ASTMB117 salt spray test and electrochemical impedance spectroscopy (EIS) were...