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    Simultaneous electrodeposition of reduced graphene oxide/ag nanoparticles as a sensitive layer for voltammetric determination of tinidazole

    , Article Nano ; Volume 12, Issue 6 , 2017 ; 17932920 (ISSN) Shahrokhian, S ; Navabi, M ; Mohammadi, R ; Sharif University of Technology
    World Scientific Publishing Co. Pte Ltd  2017
    Abstract
    A stable composite film of silver nanoparticles (Ag NPs) decorated on reduced graphene oxide is prepared by a two-step simple procedure. The surface morphology of the modified electrode is characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM) techniques. The electrochemical behavior of tinidazole (TNZ) on the surface of the modified electrode is investigated by linear sweep voltammetry and electrochemical impedance spectroscopy. The prepared composite electrode acts as a highly sensitive platform for the voltammetric determination of TNZ, leading to a significant increase in the reduction peak current of TNZ. The effects of experimental parameters such as the... 

    Investigation of the electrochemical behavior of tizanidine on the surface of glassy carbon electrode modified with multi-walled carbon nanotube/titan yellow–doped polypyrrole

    , Article Journal of Electroanalytical Chemistry ; Volume 823 , 2018 , Pages 146-154 ; 15726657 (ISSN) Shahrokhian, S ; Shamloofard, M ; Salimian, R ; Sharif University of Technology
    Abstract
    The present paper describes a voltammetric sensor based on glassy carbon electrode (GCE) modified with a thin film of multi-walled carbon nanotubes (MWCNTs) coated with an electro-polymerized layer of titan yellow-doped over–oxidized polypyrrole (OPPY) for the determination of tizanidine (TIZ). A significant enhancement was observed in the anodic peak current of TIZ on the surface of OPPY/CNT/GCE, relative to the bare, CNT- and OPPY-coated GCEs. The microscopic structure and surface morphology of the composite film was thoroughly characterized by means of atomic force microscopy (AFM), scanning electron microscopy (SEM) and cyclic voltammetry (CV) techniques. The effect of various...