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    Development of a structured monolithic support with a CNT washcoat for the naphtha HDS process

    , Article Journal of the Taiwan Institute of Chemical Engineers ; Vol. 45, issue. 3 , May , 2014 , p. 887-895 Soghrati, E ; Kazemeini, M ; Rashidi, A. M ; Jozani, K. J ; Sharif University of Technology
    Abstract
    An acid treatment of the cordierite monolith followed by coating of the CNT onto it by means of catalytic decomposition of methane was performed. The resulting material utilized as the support for the CoMo catalyst. The characterization outcomes showed that the CNTs were distributed uniformly on the surface of the monolith leading to a high BET surface area and relatively good adhered mesoporous layer of CNTs. Moreover, the catalytic activity of the resulting catalysts determined in an HDS reaction of naphtha. It was concluded that the activity of the CoMo catalyst over the CNT coated monolithic support (FACNT) was higher than that of the CoMo deposited onto the acid-treated monolith and... 

    Modeling and sensitivity analysis of styrene monomer production process and investigation of catalyst behavior

    , Article Computers and Chemical Engineering ; Volume 40 , 2012 , Pages 1-11 ; 00981354 (ISSN) Tamsilian, Y ; Ebrahimi, A. N ; Ramazani S.A., A ; Abdollahzadeh, H ; Sharif University of Technology
    2012
    Abstract
    In this work, a fundamental kinetic model based upon the Hougen-Watson non-porosity formalism was derived and used to simulate dehydrogenation and oxidation axial flow reactors. In addition, partial pressure profiles of components during styrene production process inside porous catalyst were obtained using Dusty-Gas model. The preservation equations are adopted to calculate temperature and flow profiles in the reactors filled with iron-potassium promoted catalyst pellets. The presented mathematical model for ethylbenzene dehydrogenation consists of nonlinear simultaneous differential equations with multiple dependent variables. Simulation results such as selectivity and operating temperature...