Sharif Digital Repository

In this work, asphaltene adsorption in a sandstone core sample under dynamic conditions and during miscible CO2 injection was studied using live oil sample which is close to real conditions in petroleum reservoirs. In order to investigate of damage in sandstone core sample by the deposited material such as asphaltene, the morphology analysis of sandstone core sample using scanning electron microscopic method was studied. Also analyses of the adsorbed material in sandstone core sample by Soxhlet extraction using an azeotrope mixture and with SARA method were performed. The experimental results show that by increasing the flow rate of injected CO2, the amount of asphaltene in retained material... 

Spontaneous imbibition, defined as the displacement of nonwetting phase by wetting phase in porous media by action of capillary forces, is important in many applications within earth sciences and in particular in naturally fractured oil and gas reservoirs. Hence, it is critical to investigate the various aspects of this process to correctly model the fractured reservoir behavior. In this study, twenty four experiments were conducted to study the effect of rock properties, lithology of porous medium, brine viscosity and boundary conditions on displacement rate and final recovery by cocurrent spontaneous imbibition (COCSI) in brine-oil systems. The results can be extended to brine-gas systems,... 

Although CO2 injection significantly increases the amount of oil recovered, it can cause asphaltene deposition in oil reservoirs. Asphaltene deposition leads to formation damage, in which treatment is a costly and problematic operation. In this work, impact of asphaltene precipitation and deposition during CO2 injection are investigated for recombined oil both in sandstone and carbonate core samples through dynamic flow experiments. Injection of oil and CO2 was performed simultaneously. Then, pressure drops along the core were recorded continuously to estimate permeability reductions during the experiments. Online viscosity of injected fluid was measured by a designed capillary viscometer.... 

In order to investigate the feasibility and effects of core permeability on capillary imbibition recoverable oil from carbonate cores, some laboratory tests were carried out at the EOR research laboratories of Sharif University, Iran. Outcrop rocks with different permeabilities were taken away from a recognized outcrop and used in these experiments. Special core analysis tests were run on two core samples to find out relative permeability and end point saturations. Wellhead separator oil and gas samples were collected and recombined to a reservoir gas - oil ratio. A core flooding system with a capability of free and forced imbibition testing was designed and installed. A number of free and... 

Production of sand is a common issue in oil and gas fields causing various production problems. However, as a result of sand production, rock permeability can also be increased at near-wellbore areas, which is considered to be an advantage of solid particles production. Therefore, this study aims to investigate sand production behavior and permeability changes during sand production experimentally. To do so, a specific core flooding system capable of applying different radial and axial stresses has been designed which is equipped with a special fluid distributer at the outlet to prevent any sand particle blockage during fluid production. As part of this study, eleven unconsolidated synthetic... 

In this work, experimental studies were conducted to determine the effect of asphaltene deposition on the permeability reduction and porosity reduction of carbonate, sandstone and dolomite rock samples using an Iranian bottom hole live oil sample which is close to reservoir conditions, whereas in the majority of previous work, a mixture of recombined oil (a mixture of dead oil and associated gas) was injected into a core sample which is far from reservoir conditions. The effect of the oil injection rate on asphaltene deposition and permeability reduction was studied. The experimental results showed that an increase in the oil injection flow rate can result in an increase in asphaltene... 

A large amount of the discovered oil reserves are reserved in carbonate formations, which are mostly naturally fractured oil-wet. Wettability alteration towards more water-wet state reduces the capillary barrier, hence improving the oil recovery efficiency in such reservoirs. In this study, wettability alteration towards favorable wetting state was investigated by combining modified low salinity brine with surfactant during water flooding. The diluted brine was modified by increasing the concentration of Mg2+ and SO4 2−, individually as well as both ions in combination. Different brine formulations were tested experimentally through the observations of contact angle measurements and... 

This study investigates the effect of stress magnitude and stress history on porosity and permeability values of anhydride and carbonate rocks. Porosity and permeability properties are measured for twelve anhydride and carbonate core samples under stress loading and unloading conditions. The results of permeability measurements show that tighter core samples are more stress dependent while the anhydride samples are generally more sensitive to the stress. The gap between stress loading and unloading (hysteresis) is more considerable at lower effective stress values. The results also indicate that the hysteresis is more noticeable in the anhydride core samples. The gas slippage factor is also... 

In this paper, oil recovery and permeability reduction of a tight sandstone core sample in miscible CO2 flooding processes due to asphaltene deposition were studied using an Iranian bottom hole live oil sample in order to distinguish between the mechanical plugging and adsorption mechanisms of asphaltene involved in the interfacial interaction of the asphaltene/mineral rock system. A novel experimental method was designed and proposed to measure the amount of deposited asphaltene due to different mechanisms using the cyclohexane or toluene reverse flooding and spectrophotometer. In this work, the bottom hole live oil sample was injected first to a long core and then CO 2 injection was... 

In this work, a new model based on the multilayer adsorption kinetic mechanism and four material balance equations for oil, asphaltene, gas, and water phase has been developed to account for asphaltene deposition in porous media under dynamic conditions and the model was verified using experimental data obtained in this work and also with those reported in the literature. The results showed that the developed model based on multilayer adsorption kinetic mechanism can correlate more accurately the oil flooding experimental data in comparison to the previous models based on the mechanical plugging mechanism, in particular in carbonate core samples. Also, a series of experiments was carried to... 

This work concerns the experimental investigation of surfactant alternating CO 2 injection in carbonate rocks. The core samples provided from a low-temperature fractured light oil reservoir, located in southwest Iran. The experiments were designed to observe the effect of CO 2-foam injection on gas mobility and oil recovery at different surfactant concentrations. The core samples were initially saturated with synthetic/field brine, 5,000 ppm, and then flooded with live oil to reach connate water saturation at reservoir condition, 115F and 1,700 psia. The commercial surfactant used was sodium lauryl sulfate as an anionic surfactant. The results of this work, along with field-scale simulation... 

We synthesized a titanium dioxide–polyaniline core–shell nanocomposite and implemented it as an efficient sorbent for the needle-trap extraction of some volatile organic compounds from urine samples. Polyaniline was synthesized, in the form of the emeraldine base, dissolved in dimethyl acetamide followed by diluting with water at pH 2.8, using the interfacial polymerization method. The TiO2 nanoparticles were encapsulated inside the conducting polymer shell, by adapting the in situ dispersing approach. The surface characteristics of the nanocomposite were investigated by Fourier transform infrared spectrometry, scanning electron microscopy, and transmission electron microscopy. After...