Sharif Digital Repository

The inhibitory action of N,N′-1,3-propylen-bis(3- methoxysalicylidenimine) {PMSI} on mild steel corrosion in sulfuric acid medium was investigated through electrochemical methods and evaluations based on infrared spectroscopy and scanning electron micrographs. The studies revealed that the molecule is a good mixed-type inhibitor (mostly anodic), acts as a multi-dentate ligand and repels the corrosive agents by hydrophobic forces. Its adsorption on metal surface has a physicochemical nature and obeys the Langmuir isotherm. At a critical (optimum) concentration, an anomalous inhibitory behavior was observed and interpreted at microscopic level by means of desorption/adsorption process and... 

Heaters are one of the central parts of natural gas reduction stations using turboexpanders to prevent the formation of hydrate and corrosion failure. This study intends to design a fired heater by applying a combustion sub-model to derive an optimal model for this kind of application. This model is developed to accurately consider all subsections of the fired heater namely radiation, convection, and shield sections, as well as flue gas composition, and its volume. Within this context, a multi-objective optimization is employed to identify the optimal design of the gas-fired heater in the natural gas reduction station for the Ramin power plant case study. The total economic and environmental... 

Corrosion inhibition properties of some heterocyclic compounds (3-mercapto 1,2,4 triazole, benzotriazole, thiophene, and tetra hydro-thiophene) in Cu/H3PO4 medium were investigated theoretically and experimentally via cluster/polarized continuum and gravimetric approaches. Second-order Møller-Plesset perturbation and density functional theories were applied, and the electronic chemical potential, molecular softness, and extent of charge transfer were determined for inhibitor molecules at the metal/solution interface. Good correlations were observed for both theories between the calculated quantities and experimental data. To reveal the quality of metal-inhibitor interactions, comprehensive... 

The recently study of the corrosion in some bronze artefacts from the Sangtarashan Iron Age site, western Iran, was established to identify corrosion morphology and mechanism in these objects. The corrosion layers in 22 samples were studied by optical microscopy, scanning electron microscopy–energy-dispersive X-ray spectroscopy and X-ray diffraction methods. The results showed that a thin corrosion crust has formed on the surface of bronzes with a triple-layer structure, including two internal and one external corrosion layers. The formation of these layers is due to copper leaching from the bronze surface. The internal corrosion part has been a compact, tin-rich corrosion/oxidation product... 

Due to size minimization and increment in the frequency of electronic devices, efficient and reliable methods for thermal management are required to reduce operating temperature, enhance stability, increase lifetime and user comfort. To prevent the damages of leakage and corrosion which occur in conventional heat sinks, proposing innovative thermal management methods has always been welcomed. Regarding these issues and based on the energy storage unit concept, in this study, a passive heat sink (HS) is fabricated and characterized for electronic chipset cooling with heat fluxes of 2000 to 4000 W/m2 utilizing phase change material (PCM) and nano-additive PCM (NPCM). The presented cooling... 

Separating produced water is a key part of production processing for most crude oils. It is required for quality reasons, and to avoid unnecessary transportation costs and prevent pipework corrosion rates caused by soluble salts present in the water. A complicating factor is that water is often present in crude oil in the form of emulsions. Experiments were performed to evaluate the performance of ultrasonic fields in demulsifying crude oil emulsions using novel pipe-form equipment. A horn-type piezoelectric ultrasonic transducer with a frequency of 20 kHz and power ranging from 80 W to 1000 W was used for experimental purposes. The influences of the intensity of ultrasonic fields,...