Sharif Digital Repository

Two kinds of carbon coated and uncoated 316L stainless steel are studied to use as bipolar plates in fuel cells. The results show that the conductive amorphous carbon film has a low corrosion rate in simulated PEMFC environment. Rather long term potentiostatic tests and SEM investigations indicate that carbon thin films can be a good candidate to use as bipolar plate  

In this study, tri-cation phosphate coating of zinc, calcium and iron was applied electrochemically to stainless steel 316 substrates. Cathodic current was used as an accelerator for the phosphating process. The effects of current density on the microstructures of the coatings and the time necessary for the reduction of the oxide layer have been established. For this purpose, analyses such as chronopotentiometery, SEM, EDS and linear polarization were carried out. Results indicated that higher electrophosphating current densities result in finer crystal size of the coating. This effect is detrimental to the quality of the layer. In addition, chemical analyses of the layer revealed that the... 

In the present work, the effect of brazing pa rameters on the properties of the brazed joint of pure titanium and 304 stainless steel (304SS) was investigated. Three different Ag-Cu filler metals were used, while the temperature and time of brazing were in the range of 800-950°C and 5-45 minutes, respectively. The microstructural observations show that, depending on the brazing conditions, different intermetallic phases such as CuTi2, CuTi, Cu3Ti4, and FeTi were formed at the phases interface. Based on the microstructural observations, a model was developed to characterize the formation of phases at the interfaces and brazed joint. The results show that, while some phases may form during the... 

In this study two cation coating of calcium and zinc has been developed on stainless steel 316L by electrochemical method. Cathodic current used as an accelerator for phosphating process and the effects of current density on microstructure of the phospahted layer and the time needed for termination of the phosphating process has been evaluated by potential-time, SEM, EDS, etc. Results indicate that higher current densities in electrochemical phosphating will result in heavier phospahted layer with finer crystal size which in turn deteriorates the quality of the layer by its higher porosity. Chemical analysis of the layer reveals that using the electrochemical method for phosphating of... 

Holding yokes made of investment cast 17-4PH stainless steel were too soft (below 20. HRC). Optical microscopy of the parts showed that there is a high fraction of retained austenite after oil quench due to high amount of molybdenum found in parts as an impurity. Subzero treatment in liquid nitrogen after solution heat treating was used to convert retained austenite to martensite but parts became too brittle and fractured during post-heat treating machining. Double and triple aging at 538 °C (1000 °F) after subzero cooling was done on parts. Detailed fractography and tensile testing along with optical microscopy (OM) investigation proved that repeated aging at 538 °C (1000 °F) led to lower... 

Progress in tissue engineering and regenerative medicine necessitates the use of novel materials with promising bio-surface for biomedical applications. In this work, TixNy thin films are applied on biological TC4 substrates in a mixed atmosphere of Ar and N2 via magnetron sputtering system for the protection of TC4 alloy. The effects of N/Ti ratio on the phase structure, growth orientation, contact angle, and the mechanical and corrosion performances of thin films are discussed by implementation of composition-microstructure-property interrelationships. The phase structure of TixNy thin films is changed from amorphous-like to single phase Ti2N structure with increasing N/Ti ratio. In the... 

The Ni-P/Zn-Ni compositionally modulated multilayer coatings CMMCs were electrodeposited from a single bath by switching the deposition current density. The corrosion resistance of the deposits was studied and compared with that of monolayers of Ni-P and Zn-Ni alloys via Tafel polarization, EIS and salt spray tests. Characterization of corrosion products by means of EDS and XRD revealed more details from the corrosion mechanism of the monolayers and multilayers. The corrosion current density of Ni-P/Zn-Ni CMMCs were around one tenth of Zn-Ni monolayer. The CMMC with incomplete layers performed lower polarization resistance and higher corrosion current density compared to the CMMC with... 

Al-Zn-Mg-Cu alloys (7xxx series Al alloys) are extensively used for their superior mechanical and corrosion performance. These properties are microstructure-sensitive and highly dependent on the formation, growth and coarsening of precipitates. To date, a wide variety of ageing procedures have been developed to tailor the evolved microstructures so as to yield a good combination of mechanical capacity and corrosion resistance of 7xxx series Al alloys. Among these methods, isothermal ageing, multi-stage ageing, non-isothermal ageing, retrogression and re-ageing (RRA), and stress ageing (i.e. creep ageing) are the most significant. In the present review, all of these approaches are... 

Abstract: Commercially pure titanium and titanium alloys have been among the most commonly used materials for biomedical applications since the 1950s. Due to the excellent mechanical tribological properties, corrosion resistance, biocompatibility, and antibacterial properties of titanium, it is getting much attention as a biomaterial for implants. Furthermore, titanium promotes osseointegration without any additional adhesives by physically bonding with the living bone at the implant site. These properties are crucial for producing high-strength metallic alloys for biomedical applications. Titanium alloys are manufactured into the three types of α, β, and α + β. The scientific and clinical... 

The effects of Sr additions, heat treatment (T4 and T6), and multi-directional forging on the microstructural evolution, mechanical properties and biodegradability of Mg-4Zn-xSr alloys were investigated. Corrosion behavior of the alloys was evaluated by the polarization and hydrogen evolution tests. Shear punch and hardness tests were employed to determine the mechanical properties. It was found that mechanical properties and corrosion resistance of the as-cast Mg-4Zn alloy increased by 0.3 wt% Sr addition. However, further increasing the Sr content not only did not improve the mechanical strength, but also had detrimental effects on the corrosion resistance, due to the increased size and... 

Coating is an effective approach to address the high corrosion rate of biodegradable Mg alloys, as their main challenge toward their extensive use. In this regard, it was tried to control the degradation process of an Mg-4Zn alloy by Ca addition, equal channel angular pressing (ECAP), and hydrothermal coating. The obtained results indicated that excellent grain refinement induced by Ca incorporation and ECAP simultaneously, improved both mechanical strength and corrosion resistance of the Mg-based substrate. The achieved grain refinement resulted in a thicker, more compact and integrated coating, where the ECAP-processed Mg-4Zn-0.5Ca alloy exhibited the best coating quality with no... 

Titanium alloys are widely used in various areas, particularly in medical and dental industries, due to their remarkable properties. Still, the optimum cutting conditions for titanium alloys are under consideration. Ti alloyed with Cu has been reported to provide unique properties such as good mechanical performance, good biocompatibility, acceptable corrosion resistance, and relatively lower melting point. The properties of Ti-Cu alloys mentioned above are sensitive to microstructure. They are highly dependent on microstructural characteristics such as the formation, growth, and morphological features of intermetallics and precipitates, dependent on the amount of Cu and the manufacturing... 

Magnesium and its alloys have gained significant popularity due to their light weight and their potential for use as bioresorbable materials. However, their application is limited in practice due to their relatively poor corrosion resistance. Several methods are available for improving the corrosion resistance of Mg alloys for bio-applications such as using different coatings, alloying, and modifying the microstructural parameters such as the grain size and the crystallographic texture. This review provides a comprehensive summary of the effects of crystallographic texture and twinning, as one of the most important deformation mechanisms of Mg and Mg alloys, on the corrosion behavior.... 

Abstract: Commercially pure titanium and titanium alloys have been among the most commonly used materials for biomedical applications since the 1950s. Due to the excellent mechanical tribological properties, corrosion resistance, biocompatibility, and antibacterial properties of titanium, it is getting much attention as a biomaterial for implants. Furthermore, titanium promotes osseointegration without any additional adhesives by physically bonding with the living bone at the implant site. These properties are crucial for producing high-strength metallic alloys for biomedical applications. Titanium alloys are manufactured into the three types of α, β, and α + β. The scientific and clinical...