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Synthesis and Characterization of Cyclometalated Platinum Complexes Containing 2-Vinylpyridine Ligand
, M.Sc. Thesis Sharif University of Technology ; Jamali, Sirous (Supervisor)
Abstract
The cyclometalated platinum(II) complex [Pt(Me)(bhq)(2-vpy)], 2, in which bhq = benzo{h}quinolone, 2-vpy = 2-vinylpyridine, has been prepared by reaction of the cyclometalated complex [Pt(Me) bhq)(SMe2)], 1 with one equiv 2-vinylpyridine. The similar complex [Pt(p-tolyl)(ppy)(2-vpy)], 3 in which ppy = 2-phenyl pyridine, has been prepared from reaction of the platinum(II) complex cis-[Pt(p-MeC6H4)2(SMe2)2] with one equiv 2-phenylpyridine and one equiv 2-vinylpyridine. Reaction of 2 with one equiv Br2 in acetone gave the cyclometalated platinum(IV) complex [Pt(bhq)Me(Br)(NC5H4CHCH2Br)], 4. The structure of the complexes 1-3 were determined using NMR Spectroscopy. The crystal structure of 3...
Synthesis, Characterization and Emission Study of Bis-cyclometalated Platinum(II) Complexes Containing 2-Phenylpyridine Ligand and its Derivatives
, M.Sc. Thesis Sharif University of Technology ; Jamali, Sirous (Supervisor)
Abstract
The bis(cyclometalated) platinum(II) complexes of the type [Pt(ppy)(p′py)], in which ppy = p′py = 2-(p-tolyl)pyridine, 6; ppy = 2-(3-bromophenyl)pyridine, p′py = 2-(p-tolyl)pyridine, 7; ppy = 2-(2,4-difluorophenyl)pyridine, p′py = 2-(p-tolyl)pyridine, 8; ppy = 2-(2,4-difluorophenyl)pyridine, p′py = 2-(2,4-difluorophenyl)pyridine, 9, have been prepared from the reaction of the cyclometalated platinum(II) complex [Pt(ppy)Me(SMe2)] with one equiv p′py and one equiv B(C6F5)3. The structure of 6, 7 and 10 determined using X-ray crystallography in solid state. However NMR spectroscopy methods have been used for structural characterization of the complexes in solution phase. The bis(cyclometalated)...
Synthesis and Photophysical Study of Heterobinuclear Cyclometalated Pt-Au Complexes
, M.Sc. Thesis Sharif University of Technology ; Jamali, Sirous (Supervisor)
Abstract
The cyclometalated heterobinuclear platinum-gold complexes [PtMe(bhq)(dppy)AuCl], 2, and [PtMe(bhq)(dppy)Au(NHC1)] PF6, 3, in which bhq= benzo{h}quinoline, dppy = 2-diphenylphosphinopyridine and NHC1 = 1,3-dimethylimidazol-2-ylidine have been prepared by reaction of the cyclometalated platinum complex [PtMe(bhq)(dppy)], 1, with 1 equivalent of AuCl(SMe2) or 1 equivalent of [Au(NHC1)]+ (prepared from ClAu(NHC1) and AgPF6), respectively. Complexes 2 and 3 were fully characterized using multinuclear NMR spectroscopy (1H, 31P). However complex 2was further characterized by x-ray crystallography, crystallization of complex 3 leads to form anew dimer complex 4,[Pt2(bhq)2(-dppy)2]2(PF6)2. The NMR ...
Synthesis and Characterization of Multinuclear Platinum Complexes Containing Copper Group Metals and 2,6-Diphenylphosphinopyridin Bridging Ligand
, M.Sc. Thesis Sharif University of Technology ; Jamali, Sirous (Supervisor)
Abstract
In this project, we prepared two new tetranuclear clusters with linear Pt2Ag2 and Pt2Au2 metal cores. First, The tetranuclear cluster [Ag2Pt2(Cl2)(bhq2)(μ-(PPh2)2py)2](OTf)2, 1, from the reaction of 1 equivalent of Pt(bhq)Cl(SMe2), with 1 equivalent of AgOTf and μ-(PPh2)2py ligand has been prepared. Secondly, the tetranuclear cluster [Au2Pt2 (μ-(PPh2)2py)2(Cl2)(bhq2)]( PF6 )2, 3, by the reaction of 1 equivalent of the mononuclear complex [Au(μ-(PPh2)2py)2]PF6 with 1 equivalent of PtbhqClSMe2 and μ-(PPh2)2py ligand has been prepared. Structure of complexes has been fully characterized in solution, solid and gas states using multinuclear NMR spectroscopy, X-ray crystallography and ESI-MS...
Synthesis, Characterization and Optical Study of a New Heterobinuclear Bis(Cyclometalated) Complex Containing Pt(II) and Au(I)
, M.Sc. Thesis Sharif University of Technology ; Jamali, Sirous (Supervisor)
Abstract
The bis-cyclometalated platinum(II) complexes [Pt(ptpy)2], 3, and [Pt(fppy)2], 4, in which, ptpy = 2-(p-tolyl)pyridine and fppy = 2-(2,4-difluorophenyl)pyridine have been prepared. The reaction of 3 with one equiv [Au(PPh3)]+ (prepared from the reaction between AuCl(PPh3) and AgOTf) gave the heterobinuclear complex [Pt(ptpy)2Au(PPh3)].OTf, 5, by formation of a Pt→Au dative bond. The structure of all complexes were characterized using multinuclear NMR spectroscopy in solution phase and the structures of 4 and 5 determined using X-ray crystallography in solid state. The structure of heterobinuclear complex 5 shows an unusual Pt-Au bond that supported by Au-Cipso bond. The absorption and...
Synthesis, Characterization and Photophysical Study of Cationic Cyclometalated Platinum Complexes Containing 2-Phenylpyridine Ligand and its Derivatives
, M.Sc. Thesis Sharif University of Technology ; Jamali, Sirous (Supervisor)
Abstract
The cationic cyclometalated platinum(II) complex [Pt(ⱪ2-2-ppy)(ⱪ1-N-2-ppy)2][OTF], 2, has been prepared by reaction of [PtMe3I]4, 1, with one equiv Ag(OTF) and then three equiv 2-phenylpyridine. The similar complex with formula [Pt(ⱪ2-p′py)(ⱪ1-N-p′py)2][OTF], in which p′py = 2-(3-bromophenyl)pyridine, 4, has been prepared with similar procedure, from the reaction of 1 with one equiv Ag(OTF) and then three equiv of the corresponding cyclometalating ligand. Also, the cationic cyclometalated platinum(IV) complex [Pt(2-(p-tolyl)pyridine)2(Me)(H2O)][OTF], 3, has been prepared from the reaction of 1 with one equiv Ag(OTF) and then three equiv 2-(p-tolyl)pyridine. The structure of complexes 2, 3...
Synthesis, structure and photophysical properties of binuclear methylplatinum complexes containing cyclometalating 2-phenylpyridine or benzo{h}quinoline ligands: A comparison of intramolecular Pt-Pt and π-π Interactions
, Article Dalton Transactions ; Volume 40, Issue 36 , 2011 , Pages 9123-9130 ; 14779226 (ISSN) ; Czerwieniec, R ; Kia, R ; Jamshidi, Z ; Zabel, M ; Sharif University of Technology
2011
Abstract
The binuclear cyclometalated complexes [Pt2Me 2(ppy)2(μ-dppm)], 1a, and [Pt2Me 2(bhq)2(μ-dppm)], 1b, in which ppy = 2-phenylpyridyl, bhq = benzo{h}quinoline and dppm = bis(diphenylphosphino)methane, were synthesized by the reaction of [PtMe(SMe2)(ppy)] or [PtMe(SMe 2)(bhq)] with 1/2 equiv of dppm at room temperature, respectively. Complexes 1a and 1b were fully characterized by multinuclear (1H, 31P, 13C, and 195Pt) NMR spectroscopy and were further identified by single crystal X-ray structure determination. A comparison of the intramolecular Pt-Pt and π-π interactions in complexes 1a and 1b has been made on the basis of data on crystal structures and wave functions analysis. The binuclear...
Stimuli-responsive emissive behavior of 1- and 1,3-connectivities in azulene-based imine ligands: Cycloplatination and Pt-Tl dative bond formation
, Article Dalton Transactions ; Volume 46, Issue 34 , 2017 , Pages 11327-11334 ; 14779226 (ISSN) ; Mousavi, N. A ; Bagherzadeh, M ; Kia, R ; Samouei, H ; Sharif University of Technology
Royal Society of Chemistry
2017
Abstract
The preparation of two new azulene-based imine ligands N-(2,6-diisopropylphenyl)-6-tBu-1-azulenylmethaneimine, 3, and N-(2,6-diisopropylphenyl)-6-tBu-3-(2,6-diisopropylphenyliminomethyl)-1-azulenylmethaneimine, 4, is described. These imine ligands display stimuli responsive emissive behavior and their fluorescence can be switched on and off by protonation and neutralization with trifluoroacetic acid and trimethylamine, respectively. The cyclometalation of the monoimine ligand by platinum gave the cyclometalated complex [PtMe(SMe2)(3′)], 5, (where the prime denotes the cyclometalated ligand 3). The reaction of 5 with TlPF6 yields the trinuclear bent Pt2Tl complex {[PtMe(SMe2)(3′)]2(μ-Tl)}PF6,...
Synthesis and Characterization of Multinuclear Platinum Complexes Containing Copper Group Metals and 2,6-Diphenylphosphinopyridin Bridging Ligand
, M.Sc. Thesis Sharif University of Technology ; Jamali, Sirous (Supervisor)
Abstract
In the current study, we prepared two new tetranuclear clusters with linear and nonlinear Pt2Ag2, Pt2Au2, and Pt2Cu2 metal cores.First, the tetranuclear cluster [Ag2Pt2(μ-Cl)2(bhq)2(μ-(PPh2)2py)2](OTf)2, 1, from the reaction of 1 equivalent of Pt(bhq)Cl(SMe2), with 1 equivalent of AgOTf and μ-(PPh2)2py ligand has been prepared.Secondly, the tetranuclear cluster [Au2Pt2(μ-(PPh2)2py)2(Cl)2(bhq)2](PF6)2, 3, by the reaction of 1 equivalent of the mononuclear complex [Au(μ-(PPh2)2py)2]PF6 with 1 equivalent of PtbhqClSMe2 and (PPh2)2py ligand has been prepared.The third complex [Cu2Pt2(μ-Cl)2(bhq)2(μ-(PPh2)2py)2](OTf)2 has been prepared by the reaction of 1 equivalent of AgOTf and CuBrSMe2 with...