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    Direct production of carbon nanotubes decorated with Cu2O by thermal chemical vapor deposition on Ni catalyst electroplated on a copper substrate

    , Article Journal of Nanoparticle Research ; Volume 13, Issue 10 , October , 2011 , Pages 4681-4689 ; 13880764 (ISSN) Nayeb Sadeghi, S ; Shafiekhani, A ; Vesaghi, M. A ; Sharif University of Technology
    2011
    Abstract
    Carbon nanotubes (CNTs) decorated with Cu2O particles were grown on a Ni catalyst layer deposited on a Cu substrate by thermal chemical vapor deposition from liquid petroleum gas. Ni catalyst nanoparticles with different sizes were produced in an electroplating system at 45 °C using the corrosive effect of H2SO4 which was added to solution. These nanoparticles provide the nucleation sites for CNT growth avoiding the need for a buffer layer. The surface morphology of the Ni catalyst films and CNT growth over this catalyst was studied by scanning electron microscopy (SEM). High temperature surface segregation of the Cu substrate into the Ni catalyst layer and its exposition to O2 at...