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    Thermal degradation behavior and kinetic analysis of ultra high molecular weight polyethylene based multi-walled carbon nanotube nanocomposites prepared via in-situ polymerization

    , Article Journal of Macromolecular Science, Part A: Pure and Applied Chemistry ; Volume 49, Issue 9 , 2012 , Pages 749-757 ; 10601325 (ISSN) Shariati, J ; Saadatabadi, A. R ; Khorasheh, F ; Sharif University of Technology
    T&F  2012
    Abstract
    Thermal degradation behavior of multi-wall carbon nanotubes (MWCNTs)/ultra high molecular weight polyethylene (UHMWPE) nanocomposites, with different nanotubes contents (0.5, 1.5 and 3.5 wt%) prepared via in-situ polymerization technique have been investigated using thermal gravimetric analysis (TGA). TGA spectra revealed that these nanocomposites had enhanced thermal stability and no significant mass loss (<0.4 wt%) occurred up to 350°C. Thermal degradation of these UHMWPE/MWCNT nanocomposites was investigated in terms of parameters such as the onset temperature of degradation (T 10), the decomposition temperature at 50% wt loss (T 50), the degradation temperature of maximum rate of the... 

    Application of nanostructured aluminium titanate (Al2TiO5) photocatalyst for removal of organic pollutants from water: Influencing factors and kinetic study

    , Article Materials Chemistry and Physics ; Volume 256 , 2020 Azarniya, A ; Soltaninejad, M ; Zekavat, M ; Bakhshandeh, F ; Madaah Hosseini, H. R ; Amutha, C ; Ramakrishna, S ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    In this study, aluminum titanate (Al2TiO5)-based nanostructure with the outstanding photocatalytic performance was prepared via the simple citrate sol-gel method. The effects of thee operational variables such as pH, temperature, catalyst dosage, and initial dye concentration on the photodegradation efficiency of methylene blue (MB) were explored in some details. The results showed that compared to TiO2, AT benefits a superior photocatalytic activity due to its narrow band gap (2.88 eV) and low recombination rate of charge carriers. Increasing the wastewater temperature from 25 to 60 °C can improve the degradation percent from 22.15 to 52%. Based on the thermokinetic calculations, the...