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dense-membranes
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Pore Network Modeling of Membrane Mass Transport for Gas Separation
, M.Sc. Thesis Sharif University of Technology ; Soltanieh, Mohammad (Supervisor) ; Bastani, Daryush (Supervisor) ; Jamshidi, Saeed (Co-Supervisor)
Abstract
The purpose of this research is to model transport and separation of single and gas mixtures through pore network modeling in dense membranes. In the first part of the project, the mass transfer and governing mechanisms of transport are investigated. In the second part of the project, simulation of membrane pore network in 3D of Cartesian coordinate is done. In the third part of the project permeability of single gas and ideal selectivity of binary gases for an actual membrane by desired mechanism are calculated. Then the results of pore network modeling were compare with the results from molecular dynamic simulation for single gas in polyurethane membrane with reasonable agreement. In this...
Comparison of oxygen permeation through some perovskite membranes synthesized with EDTNAD
, Article Reaction Kinetics, Mechanisms and Catalysis ; Volume 100, Issue 2 , August , 2010 , Pages 459-469 ; 18785190 (ISSN) ; Nazari, K ; Seyed Matin, N ; Safekordi, A. A ; Ghanbari, B ; Zarrinpashne, S ; Ahmadi, R ; Sharif University of Technology
Abstract
Three dense membranes of types SrCo0.8Fe0.2O 3-δ (SCF(82)), La0.6Sr0.4Co 0.8Fe0.2O3-δ (LSCF(6482)) and La 0.8Sr0.2Co0.6Fe0.4O 3-δ (LSCF(8264)) perovskites were prepared by complexation applying a chelating agent, ethylene diamine N,N,N′,N′-tetra-N- acetyl-diamine (EDTNAD). The oxygen permeation flux through the perovskite membranes was measured as a function of temperature within 1,073-1,223 K as well as the oxygen partial pressure of 0.1-1.0 bar. The oxygen permeation fluxes for the membranes, SCF(82), LSCF(6482), LSCF(8264) with the thickness of 0.85 mm were observed as 9.2×10-7 (mol/cm2 s), 1.7×10-7 (mol/cm2 s), and 1.0×10-7 (mol/cm2 s) in these cases at 1,153 K. The results indicated the...
Effect of Sintering Temperature on Microstructure and Hydrogen Permeation Properties of Perovskite Membrane
, Article Journal of Materials Science and Technology ; Volume 29, Issue 2 , 2013 , Pages 137-141 ; 10050302 (ISSN) ; Zamaniyan, A ; SafeKordi, A ; Ganji Babakhani, E ; Amanipour, M ; Sharif University of Technology
2013
Abstract
The BaCe0.9Y0.1O3-δ (BCY) perovskite membrane was successfully synthesized by liquid citrate method. The phase structure of the powder was characterized by X-ray diffraction (XRD). Scanning electron microscopy (SEM) was used to characterize microstructures of the membrane sintered under various conditions. Sintering temperatures and dwell time during sintering influence the final microstructure of the ceramic. Results showed that increasing sintering temperature resulted in a dense membrane with clear grains. An increase of dwell time was favorable to produce membranes with larger grains in the sintered ceramics. A density of 5.87 g/cm3 was reached for the membrane after sintering at 1200 °C...