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desorption-analysis
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Solid state preparation and photocatalytic activity of bismuth oxybromide nanoplates
, Article Research on Chemical Intermediates ; Volume 42, Issue 3 , 2016 , Pages 2429-2447 ; 09226168 (ISSN) ; Tadjarodi, A ; Akhavan, O ; Moghaddasi Khiavi, M ; Sharif University of Technology
Springer Netherlands
2016
Abstract
A mechanochemical method was applied to prepare bismuth oxybromide (BiOBr) nanoplates using bismuth nitrate pentahydrate and potassium bromide for 15 (A15), 30 (A30) and 60 (A60) minutes. Scanning electron microscopy studies showed that all the products were comprised of nanoplates. Aggregated nanoplates along with microblocks were observed for A15 and A30 and the entire morphology was not homogenous. The morphology of A60 was uniform and consisted of thin and isolated nanoplates. Evaluation of the X-ray diffraction patterns showed that the purity and crystallinity of the products improved by increasing the milling time. The energy dispersive X-ray analysis confirmed the high purity of the...
Effect of heating profile on desorption curve in temperature programmed desorption analysis: Case study of acid sites distribution of SAPO-34
, Article Journal of Porous Materials ; Volume 16, Issue 5 , 2009 , Pages 599-603 ; 13802224 (ISSN) ; Farhadi, F ; Khorasheh, F ; Yan, Z. F ; Sharif University of Technology
2009
Abstract
Comparison of the traditional linear heating method of TPD with an original stepwise heating scheme was reported for the first time. Stepwise heating TPD was carried out by keeping the temperature constant as soon as ammonia desorption signal rises until the signal returns to the baseline. More ammonia desorption peaks on a SAPO-34 catalyst were identified using TPD with stepwise heating. The effect of temperature ramp on desorption peak broadening in TPD curve was also addressed. The more distinct ammonia desorption peaks in stepwise TPD indicates that ammonia adsorbs in about five or six different ways on SAPO-34, and attribution of different adsorptions may be explained considering some...
Enhanced electrochemical hydrogen storage by catalytic Fe-doped multi-walled carbon nanotubes synthesized by thermal chemical vapor deposition
, Article Journal of Power Sources ; Volume 188, Issue 2 , 2009 , Pages 404-410 ; 03787753 (ISSN) ; Mortazavi, S.Z ; Moshfegh, A.Z ; Golikand, A.N ; Amiri, M ; Sharif University of Technology
2009
Abstract
Hydrogen storage capacities of raw, oxidized, purified and Fe-doped multi-walled carbon nanotubes (MWCNTs) were studied by electrochemical method. Based on transmission electron microscopy and Raman spectroscopic data, thermal oxidation removed defective graphite shells at the outer walls of MWCNTs. The analysis results indicated that the acid treatment dissolved most of the catalysts and opened some tips of the MWCNTs. Thermal gravimetric analysis and differential scanning calorimetry results illustrated that by oxidation and purification of MWCNTs, the weight loss peak shifts toward a higher temperature. N2 adsorption isotherms of the purified and oxidized MWCNTs showed an increase in N2...