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    Bioelectricity generation enhancement in a dual chamber microbial fuel cell under cathodic enzyme catalyzed dye decolorization

    , Article Bioresource Technology ; Volume 102, Issue 12 , June , 2011 , Pages 6761-6765 ; 09608524 (ISSN) Bakhshian, S ; Kariminia, H. R ; Roshandel, R ; Sharif University of Technology
    2011
    Abstract
    Enzymatic decolorization of reactive blue 221 (RB221) using laccase was investigated in a dual-chamber microbial fuel cell (MFC). Suspended laccase was used in the cathode chamber in the absence of any mediators in order to decolorize RB221 and also improve oxygen reduction reaction in the cathode. Molasses was utilized as low cost and high strength energy source in the anode chamber. The capability of MFC for simultaneous molasses and dye removal was investigated. A decolorization efficiency of 87% was achieved in the cathode chamber and 84% COD removal for molasses was observed in the anode chamber. Laccase could catalyze the removal of RB221 and had positive effect on MFC performance as... 

    Simultaneous decolorization and bioelectricity generation in a dual chamber microbial fuel cell using electropolymerized-enzymatic cathode

    , Article Environmental Science and Technology ; Volume 46, Issue 12 , 2012 , Pages 6584-6593 ; 0013936X (ISSN) Savizi, I. S. P ; Kariminia, H. R ; Bakhshian, S ; Sharif University of Technology
    2012
    Abstract
    Effect of cathodic enzymatic decolorization of reactive blue 221 (RB221) on the performance of a dual-chamber microbial fuel cell (MFC) was investigated. Immobilized laccase on the surface of a modified graphite electrode was used in the cathode compartment in order to decolorize the azo dye and enhance the oxygen reduction reaction. First, methylene blue which is an electroactive polymer was electropolymerized on the surface of a graphite bar to prepare the modified electrode. Utilization of the modified electrode with no enzyme in the MFC increased the power density up to 57% due to the reduction of internal resistance from 1000 to 750 Ω. Using the electropolymerized-enzymatic cathode...