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    Investigation of effects of salinity, temperature, pressure, and crude oil type on the dynamic interfacial tensions

    , Article Chemical Engineering Research and Design ; Volume 115 , 2016 , Pages 53-65 ; 02638762 (ISSN) Lashkarbolooki, M ; Riazi, M ; Ayatollahi, S ; Sharif University of Technology
    Institution of Chemical Engineers  2016
    Abstract
    The main objectives of this study are to determine the influence of crude oil type, salinity, temperature and pressure on the dynamic interfacial tension (DIFT) of crude oil based on the experiments and modeling approaches. DIFT is also modeled using dynamic adsorption models, mono-exponential decay model as well as empirical equations. The results showed that when temperature increases, unlike deionized water which inversion phase temperature was observed, the equilibrium IFT of crude oils/sea water increases due to reduction of surface excess concentration of natural surfactants at the fluid/fluid interface as a dominant mechanism  

    Mechanistic study on the dynamic interfacial tension of crude oil + water systems: Experimental and modeling approaches

    , Article Journal of Industrial and Engineering Chemistry ; Volume 35 , 2016 , Pages 408-416 ; 1226086X (ISSN) Lashkarbolooki, M ; Ayatollahi, S ; Riazi, M ; Sharif University of Technology
    Korean Society of Industrial Engineering Chemistry 
    Abstract
    This study investigates dynamic interfacial tension (DIFT) of acidic crude oil (ACO) and non acidic/basic crude oils (BCO) + deionized water (DW) as a function of pressure from 500 to 4000 psi, and temperature from 30 to 80 °C using an axisymmetric drop shape analysis (ADSA) technique. DIFTs are also modeled using dynamic adsorption model, mono-exponential decay model, and empirical equations. The results showed that if a reduction in the surface excess concentration due to increasing temperature overlooks the total entropy of the molecules in the system, an increase in IFT would be expected  

    Experimental and modeling investigation of dynamic interfacial tension of asphaltenic-acidic crude oil/aqueous phase containing different ions

    , Article Chinese Journal of Chemical Engineering ; 2017 ; 10049541 (ISSN) Lashkarbolooki, M ; Ayatollahi, S ; Sharif University of Technology
    Abstract
    In this way, after experimental measurement of interfacial tension, different models including mono-exponential decay, dynamic adsorption models and empirical equation are used to correlate this time-dependent behavior of interfacial tension (IFT). During the modeling approach, the induction, adsorption, equilibrium, and meso-equilibrium times as well as diffusivity of surface active components known as natural surfactant including asphaltene and resin from crude oil to the interface are obtained. In addition, the surface excess concentration of surface active components at the interface and Gibbs adsorption isotherm are utilized to analyze the measured dynamic IFTs. Finally, the mechanisms... 

    Effect of CO2 and crude oil type on the dynamic interfacial tension of crude oil/carbonated water at different operational conditions

    , Article Journal of Petroleum Science and Engineering ; Volume 170 , 2018 , Pages 576-581 ; 09204105 (ISSN) Lashkarbolooki, M ; Riazi, M ; Ayatollahi, S ; Sharif University of Technology
    Elsevier B.V  2018
    Abstract
    Concerns about climate change have persuaded the researchers to examine CO2 injection in the form of carbonated water (CW) into oil reservoir as a safe and effective CO2 storage and enhanced oil recovery process. Although interfacial tension (IFT) between crude oil and injected fluid has a vital role on the displacement of fluids in porous media, the effect of CO2 and crude oil type on the dynamic IFT of crude oil under different operational conditions is not well understood. Accordingly, this study was carried out to assess the effects of temperature, pressure, crude oil type and CO2 on the dynamic IFT of crude oil/CW. To achieve this goal, two types of crude oil were provided from southern...