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    Prediction of flooding in a pulsed packed column for continuous pertraction of dysprosium by an emulsion liquid membrane

    , Article Chemical Engineering and Processing - Process Intensification ; Volume 169 , 2021 ; 02552701 (ISSN) Sadehlari, F ; Bastani, D ; Safdari, J ; Raji, M ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    For the first time, Dysprosium was extracted by the novel method of emulsion liquid membrane in a pulsed packed column in a continuous process. Emulsion liquid membrane (ELM) was comprised of D2EHPA (di-2-ethylhexylphosphoric acid) as carrier and Span 80 (Polysorbate 80) as the surfactant in kerosene as the diluent and nitric acid as internal phase. In this work, the packed column was characterized from a hydrodynamic point of view including flooding condition and holdup at flooding points. Operational parameters affecting the flooding points, such as pulsation intensity and flow rate of continuous and dispersed phases have been studied. It was found that increase in pulsation intensity up... 

    Study of Effects of Operational Parameters on Flooding in Pertraction of Dysprosium in a Vertical Pulsed Packed Column

    , M.Sc. Thesis Sharif University of Technology Sadelari, Farzin (Author) ; Bastani, Dariush (Supervisor) ; Safdari, Jaber (Supervisor) ; Raji, Maliheh (Co-Supervisor)
    Abstract
    Pulsed packed columns are among the most important devices used in liquid-liquid extraction, with wide application in petroleum and petrochemical industries, metal salt extraction, pharmaceutical industries, metallurgy, and other areas. Liquid-membrane technology is an alternative separation technique to the liquid-liquid extraction for the extraction and recovery of metal ions from aqueous solutions. There are three main types of liquid membranes: emulsion liquid membrane (ELM), Bulk Liquid Membrane (BLM), and Supported Liquid Membrane (SLM). Liquid emulsion membrane is one of the pertraction methods with phase dispersion. It is a three-phase dispersion system, consisting: external phase,... 

    Geochemical characteristics of rare earth elements in different types of soil: a chemometric approach

    , Article Chemosphere ; Volume 184 , 2017 , Pages 673-678 ; 00456535 (ISSN) Khan, A. M ; Behkami, S ; Yusoff, I ; Md Zain, S. B ; Bakar, N. K. A ; Bakar, A. F. A ; Alias, Y ; Sharif University of Technology
    Abstract
    Rare earth elements (REEs) are becoming significant due to their huge applications in many industries, large-scale mining and refining activities. Increasing usage of such metals pose negative environmental impacts. In this research ICP-MS has been used to analyze soil samples collected from former ex-mining areas in the depths of 0–20 cm, 21–40 cm, and 41–60 cm of residential, mining, natural, and industrial areas of Perak. Principal component analysis (PCA) revealed that soil samples taken from different mining, industrial, residential, and natural areas are separated into four clusters. It was observed that REEs were abundant in most of the samples from mining areas. Concentration of the...