Sharif Digital Repository

The molecular behavior of some pyridine derivatives as corrosion inhibitors of iron and aluminum in acid media, were studied quantum electrochemically. The calculations were made for three conditions; isolated inhibitor molecule, metal cluster, and finally polarized continuum media. It is concluded that for aluminum the vertical adsorption through nitrogen atom is prevailing, while for iron both vertical and planar adsorptions (through π electrons of aromatic ring) are possible, but the vertical is predominant. The inhibitor chemical potential (μ) and the extent of charge transfer (ΔN) to the metal were determined. A linear correlation between each of these and the inhibition efficiencies... 

Just a few investigations have been conducted to study the mixed nanofluids(MNs), which contain more than one type of nanoparticles, despite considerable advances in the field of nanofluids thermal conductivity. In present research, by combining different volume fractions of various nanoparticles, the variation of mixed nanofluids thermal conductivity was considered. The mentioned nanofluids have different fabrication cost. First, the effect of each specific nanoparticle presence in the base fluid on the thermal conductivity of nanofluid was surveyed both experimentally and theoretically. Then, the thermal conductivities of two MNs, one consisted of a metallic nanoparticle (high thermal... 

The present study considers both the hydrodynamic and thermal characteristics of combined electroosmotic and pressure driven flow in a microannulus. Analytical solutions are presented using the Debye-Hückel linearization along with the uniform Joule heating and negligible viscous dissipation assumptions, whereas exact results are achieved numerically. Here, the range of validity for the Debye-Hückel linearization is found to be about two times of that for a parallel plate microchannel. Accordingly, this linearization may successfully be used to evaluate the potential and velocity distributions up to the zeta potentials of 100 mV, provided that the dimensionless Debye-Hückel parameter is... 

The present study attempts to analyze the extended Graetz problem in combined electroosmotic and pressure driven flows in rectangular microchannels, by employing a variational formulation. Both the Joule heating and axial conduction effects are taken into consideration. Since assuming a uniform inlet temperature profile is not consistent with the existence of these effects, a step change in wall temperature is considered to represent physically conceivable thermal entrance conditions. The method of analysis considered here is primarily analytical, in which series solutions are presented for the electrical potential, velocity, and temperature. For general treatment of the eigenvalue problem...