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    Electrocatalytic Oxidation of 1-Propanol and 2-Propanol on Electro-active Films Derived from Ni II-(N,N′-bis(2-Hydroxy, 3-Methoxy Benzaldehyde)-1,2-Propandiimine) Modified Glassy Carbon Electrode

    , Article Electrocatalysis ; Volume 2, Issue 3 , Volume 2, Issue 3 , 2011 , Pages 163-171 ; 18682529 (ISSN) Jafarian, M ; Rashvand avei, M ; Gobal, F ; Rayati, S ; Mahjani, M. G ; Sharif University of Technology
    Complexes of Ni II-(N,N′-bis(2-hydroxy, 3-methoxy benzaldehyde)-1,2-propandiimine) can be electro-polymerized onto GC electrode in an alkaline solution to give an electro-active film strongly adhered on the electrode surface. In alkaline solution, this poly-(Ni II{sal-1,2-pn(3-OMe) 2})/GC film shows the typical voltammetric response of a surface-immobilized redox couple, as can be anticipated for the Ni 2+/Ni 3+ transitions into the film. In addition, the film exhibits a potent and persistent electro-catalytic activity towards the oxidation of 1- and 2-propanol. In CV studies, in the presence of these alcohols, poly-(Ni II{sal-1,2-pn(3-OMe) 2})/GC electrode shows a new oxidation peak for the... 

    Facile preparation of a highly sensitive non-enzymatic glucose sensor based on the composite of Cu(OH)2 nanotubes arrays and conductive polypyrrole

    , Article Microchemical Journal ; Volume 169 , 2021 ; 0026265X (ISSN) Manafi Yeldaghermani, R ; Shahrokhian, S ; Hafezi Kahnamouei, M ; Sharif University of Technology
    Elsevier Inc  2021
    A novel amperometric non-enzymatic glucose sensor is designed by the facile preparation method. It is made by electrodeposition of Cu clusters and converting them to Cu(OH)2 nanotubes (Cu(OH)2NTs) arrays along with thin-film electro-polymerized of spindle-shaped polypyrrole (PPy@Cu(OH)2NTs), which have been doped by using sodium Benzene-1,3-disulfonate as an anion dopant. Various electrochemical methods investigate the electrochemical performance of the modified electrode toward glucose detection. Under the optimized conditions, a significant electrochemical response improvement is observed toward the electro-oxidation of glucose on the PPy@Cu(OH)2NTs electrode's surface relative to the... 

    In-situ electro-polymerization of graphene nanoribbon/polyaniline composite film: Application to sensitive electrochemical detection of dobutamine

    , Article Sensors and Actuators, B: Chemical ; Vol. 196 , June , 2014 , pp. 582-588 ; ISSN: 09254005 Asadian, E ; Shahrokhian, S ; Zad, A. I ; Jokar, E ; Sharif University of Technology
    The present paper demonstrates the capability of narrow graphene nanoribbons (GNRs) in constructing new sensing platforms. Graphene nanoribbons have been synthesized via a simple solvothermal route through unzipping of carbon nanotubes, which was confirmed by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and Raman spectroscopy analysis. These narrow carbon sheets were used to form a composite film by in-situ electro-polymerization with aniline. The produced graphene nanoribbon/polyaniline (GNR/PANI) composite film showed impressive performance in electrochemical determination of dobutamine (DBT). Under optimal conditions, in comparison to... 

    Electrochemical determination of l-dopa in the presence of ascorbic acid on the surface of the glassy carbon electrode modified by a bilayer of multi-walled carbon nanotube and poly-pyrrole doped with tiron

    , Article Journal of Electroanalytical Chemistry ; Volume 636, Issue 1-2 , 2009 , Pages 40-46 ; 15726657 (ISSN) Shahrokhian, S ; Asadian, E ; Sharif University of Technology
    Elsevier  2009
    There are high attractions in the development of conducting polymer (CP) coatings to improve the electrochemical properties and biocompatibility of electrodes in the area of biosensors. A new type of the modified electrodes is prepared in a layer-by-layer process by using multi-walled carbon nanotube (MWCNT) and poly-pyrrole. In this procedure, the glassy carbon electrode is casted by a drop suspension of MWCNT, which leads to form a thin film of nanotube on its surface. In the second step, electrochemical polymerization of pyrrole in the presence of tiron (used as doping anion) is performed on the surface of the MWCNT pre-coated electrode. The modification procedure led to fabrication of a...