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    Effect of treatment time and temperature on microstructure and corrosion behavior of Zn-Ni electrophosphate coating

    , Article Journal of Alloys and Compounds ; Volume 688 , 2016 , Pages 596-604 ; 09258388 (ISSN) BaratiDar Darband, G ; Afshar, A ; Rabani, M ; Sharif University of Technology
    Elsevier Ltd  2016
    Abstract
    In this study, the effect of phosphating time and temperature on microstructure and corrosion behavior of Zn-Ni electrophosphate coating with a galvanized steel as a substrate, were investigated. SEM and X-ray diffraction methods were used for investigation the microstructure and phase analysis, respectively. And immersion test, potentiodynamic polarization test, and Electrochemical Impedance Spectroscopy tests were used for the study of corrosion behavior. The results of this study indicated that the best coating morphology is obtained in the range between 20 and 30 min and 40–50° C. Moreover, results of corrosion studies showed that the corrosion mechanism is under diffusion control due to... 

    Characterization of Zn–Mn phosphate coating deposited by cathodic electrochemical method

    , Article Transactions of the Indian Institute of Metals ; Volume 72, Issue 2 , 2019 , Pages 307-317 ; 09722815 (ISSN) Hajisafari, M ; Chakerizade, A ; Fallah, M ; Barati Darband, G ; Sharif University of Technology
    Springer  2019
    Abstract
    Electrophosphating is a novel method that is used for accelerating the low-temperature phosphating bath. In this study, Zn–Mn phosphate coating was fabricated on mild steel substrate using the cathodic electrochemical method. Afterward, the effect of electrolyte pH and applied current density was investigated on coating properties. Microstructure, phase analysis and corrosion resistance of coating were evaluated using SEM, X-ray diffraction, potentiodynamic, immersion test and electrochemical impedance spectroscopy tests, respectively. Results indicated that the metallic and nonmetallic phases are present in the coating fabricated by the cathodic electrochemical method. The results of the... 

    Investigation and Synthesis of Zn-Ni-Mn Three Cationic Electrophosphate Coating

    , M.Sc. Thesis Sharif University of Technology Alimi, Zahra (Author) ; Ghorbani, Mohamad (Supervisor)
    Abstract
    The purpose of this study was to create a three-cationic electro phosphate coating of zinc-nickel-manganese by cathodic method and to investigate the effect of operating variables on the properties of zinc-nickel-manganese tri-cationic electro phosphate coating. Hence, the effects of variables such as coating acidity, coating thickness, coating temperature, coating time and concentration of manganese were studied in the bath on the properties such as coating morphology, corrosion resistance, coating thickness. Coating morphology was characterized by scanning electron microscopy and corrosion resistance by polarization test. The pH values of 1.4, 1.8, 2 and 2.2 were selected, and the results... 

    Formation and Investigation of Zinc-Nickel Two Cathionic Electrophospahte Coating Properties on Galvanized Steel

    , M.Sc. Thesis Sharif University of Technology Barati Darband, Ghasem (Author) ; Afshar, Abdollah (Supervisor)
    Abstract
    By using electrophoaphating treatment in the metal coating process, the operating temperature of chemical phosphating bath is decrease and also difficulties with the use of high temperature bath is eliminated. The aim of this study is investigate the effect of operating parameter on coating properties and also investigation the deposition mechanism of Zn-Ni electrophosphate coating. Coating properties such as morphology, corrosion resistance and porosity of the coating characterized using SEM, polarization test and electrochemical method respectively. The values used for pH effect was 1.6,1.8,2 and 2.2 results indicated that by increasing the pH value from 1.6 to 1.8 the icorr decrease from... 

    Zn-Ni Electrophosphating on galvanized steel using cathodic and anodic electrochemical methods

    , Article Surface and Coatings Technology ; January , 2015 ; 02578972 (ISSN) Darband, G. B ; Afshar, A ; Aliabadi, A ; Sharif University of Technology
    Elsevier  2015
    Abstract
    Electrophosphating is the novel method for accelerating the low temperature phosphating bath. This method can be performed as cathodic and anodic treatments. Both of them influence the coating deposition mechanism and therefore coating properties. In this study Zn-Ni electrophosphate coating was applied on galvanized steel using cathodic and anodic electrochemical methods. Microstructure, composition and corrosion resistance of coating were characterized by using a scanning electron microscopy, X-ray diffraction method and potentiodynamic polarization test respectively. The results of this study indicated that, by using cathodic method, compact phosphate coating with high corrosion... 

    Zn–Ni electrophosphating on galvanized steel using cathodic and anodic electrochemical methods

    , Article Surface and Coatings Technology ; Volume 306 , 2016 , Pages 497-505 ; 02578972 (ISSN) Barati Darband, Gh ; Afshar, A ; Aliabadi, A ; Sharif University of Technology
    Elsevier B.V  2016
    Abstract
    Electrophosphating is the novel method for accelerating the low temperature phosphating bath. This method can be performed as cathodic and anodic treatments. Both of them influence the coating deposition mechanism and therefore coating properties. In this study Zn–Ni electrophosphate coating was applied on galvanized steel using cathodic and anodic electrochemical methods. Microstructure, composition and corrosion resistance of coating were characterized by using a scanning electron microscopy, X-ray diffraction method and potentiodynamic polarization test respectively. The results of this study indicated that, by using cathodic method, compact phosphate coating with high corrosion...