Sharif Digital Repository

Diffusion flame from electrospray of liquid ethanol and butanol was investigated experimentally. Stable flames were observed at two distinct modes recognized at different flow rates, applied voltages, and distances between the nozzle and counter electrode. The first mode occurred at minimum voltages in which individual larger droplets are dominantly generated. The second mode at higher voltages corresponds to multijets, which produce finer distribution of droplets. Using flame-imaging anal- ysis, flammability margins are introduced and flame lengths are measured versus nondimensional parameters for both fuels and modes of spraying. The fluctuation of the flames is characterized and the... 

The feasibility of fabricating relatively monodispersed polymeric nanoparticles by the electrospray method in a modified electrospray set-up is demonstrated in this study. The polymer solution is electrosprayed in the single cone-jet regime through a nozzle. After solvent evaporation, during which particles pave from the nozzle to collector, the fabricated nanoparticles can be collected in deionized water, which plays the role of surfactant for particles, not allowing them to aggregate. The results of scanning electron microscope and dynamic light scattering analysis clearly confirm the fabrication of monodispersed spherical polymeric nanoparticles with diameter range from 80 to 120nm with... 

Electrospray technique is one of the commonly used methods for generating nanoparticles. In this method, the chemical solution which consists of a polymer and its solvent are injected into an electric field via a nozzle. At the end of this nozzle, due to electric forces, a certain part of this liquid is separated. Then, the separated part is divided into smaller particles and the solvent is evaporated and hence, the nanoparticles are acquired. Produced nanoparticales are collected in deionized water placed under the certain distant from nozzle. However, construction of this method is generally based on practical results. In this paper, modeling and performance evaluation of high voltage... 

The mononuclear complex [Mn(tptz)(CH3COO)(OH2)2]NO3 (1) was investigated by electrospray ionization mass spectrometry in aqueous solution at pH 4.5. Electrospray ionization mass spectrometry shows that mononuclear and dinuclear manganese cationic species are present in solution, probably in equilibrium with neutral 1. An experiment showed that the most important reaction in the presence of oxone (2KHSO5·KHSO4·K2SO4) is decoordination  

The behavior of an electrified liquid jet breakup and modes of disintegration were investigated at different flow rates and voltages. The current phenomenology belongs to a new injector introduced recently by Morad et al. (2016). This injector has proven to highly extend the stability and flow rate of electrospray particularly in the Taylor cone-jet mode. The experimental investigation was performed using a high-power light-emitting diode (LED) illumination as the light source. The light source was developed to operate in the pulsing condition when synchronized with a digital camera and was particularly designed to function properly in the presence of high electromagnetic interference (EMI).... 

Electrospray cooling is experimentally examined for high volumetric flow rates (80 mL/h) stabilized by a novel hemispherical nozzle. Stability of the Taylor cone-jet mode of this nozzle is increased by interaction of the discharging liquid with the outer wall of a hemispherical cap, installed at the tip of a simple nozzle. The liquid can then be discharged at high flow rates at the same mode. The liquid is ethanol and the test surface temperature as well as the cooling heat flux are measured. The results of the surface temperature, the heat flux and the heat transfer coefficient are compared between the three cases. The first and main case is the electrospray using the novel hemispherical... 

Nitro-reduction by the vinyl halide radical cation CH 2 = CH-X +· (X = Cl or Br) converts nitroaromatics into arylnitrenium ions, significant intermediates in carcinogenesis, and the present study reports on the scope and regioselectivity of this versatile reaction. The reaction is general for different kinds of substituted nitroaromatics; para/meta substitutents have little effect on the reaction while ortho substitutents result in low yields of arylnitrenium ions. The phenylnitrenium ion PhNH + can be generated by chemical ionization (CI) of nitrobenzene using 1,2-dichloroethane as the reagent gas or by atmospheric pressure chemical ionization (APCI) of 1,2-dichloroethane solution doped...