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engineered-water-flooding
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Investigation of rock and fluid interactions during engineered water flooding in dolomite reservoir rocks
, Article Energy Sources, Part A: Recovery, Utilization and Environmental Effects ; 2020 ; Masihi, M ; Safekordi, A. A ; Ayatollahi, S ; Sadeghnejad, S ; Sharif University of Technology
Taylor and Francis Inc
2020
Abstract
Engineered water (EW) flooding is one of the enhanced oil recovery (EOR) techniques in carbonate reservoirs. In this method, the wettability of reservoir rock is altered by controlling the amount of various ions in the injected brine. The thermodynamics of wettability is related to the surface interactions and stability of water film on a rock surface. It can be identified by calculating disjoining pressure isotherms. In this study, core flooding tests, contact angle and zeta potential measurements along with the disjoining pressure isotherm calculation by the DLVO theory were used to investigate the wettability alteration of dolomite rock. Four brines include reservoir formation water...
Novel experimental evidence on the impact of surface carboxylic acid site density on the role of individual ions in the electrical behavior of crude oil/water
, Article Journal of Molecular Liquids ; Volume 362 , 2022 ; 01677322 (ISSN) ; Mahmoodpour, S ; Ayatollahi, S ; Fatemi, M ; Sharif University of Technology
Elsevier B.V
2022
Abstract
Perceiving the electrical behavior of the rock/brine and the crude oil/brine interfaces gives insight into the performance of engineered waterflooding. Compared to the rock surface, few studies have attempted to comprehend the complex behavior of the crude-oil surface electrical behavior. To reveal the impact of each ion on the surface charge of crude oil, the zeta potential of crude oil/single-salt brines (including NaCl, CaCl2, MgCl2, Na2SO4, and NaHCO3) was measured in a wide range of salinity. Then, the counterpart interfacial tension (IFT) was measured to determine the capability of each brine in bringing carboxylic acid groups from crude-oil bulk (COOH) to crude oil/brine interface...
Impact of ionic composition on modulating wetting preference of calcite surface: Implication for chemically tuned water flooding
, Article Colloids and Surfaces A: Physicochemical and Engineering Aspects ; Volume 568 , 2019 , Pages 470-480 ; 09277757 (ISSN) ; Badizad, M. H ; Sharif University of Technology
Elsevier B.V
2019
Abstract
Despite previous researches on ion-engineered waterflooding (IEWF), its underlying mechanisms are not fully understood, particularly in presence of additives, like surfactants. This paper concerned with the contribution of Ca 2+ , Mg 2+ , SO 4 2- and Na + into altering wettability of oil-wet carbonate minerals towards water preferred state. As a mechanistic study, an experiment workflow was conducted to probe the impact of ions' concentrations in SW, either with or without sodium dodecylbenzene sulfonate (SDBS) which is an anionic surfactant. At first, contact angle (CA) measurement was carried out to evaluate the degree of wettability reversal upon treating the oil-aged calcite slabs with...