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    Microfluidics Desulfurization of Hydrocarbons Components

    , M.Sc. Thesis Sharif University of Technology Ranjbar Koleibi, Amir (Author) ; Mohammadi, Aliasghar (Supervisor) ; Kazemeini, Mohammad (Supervisor)
    Abstract
    Microfluidic is a science and technology in which they study the behavior of fluids, control them and design devices or systems with dimensions of tens to hundreds of micrometers. The technology has the ability to design and manufacture macro-scale and micro-scale equipment, such as micro-pumps, micro-valves, micro-filters, micro-mixers, micro-reactors, and other equipment. The benefits of this technology include the use of low sample size, low waste of energy, low power consumption, short response time, high system performance, portability and performance of several operating phases in a compressed piece such as production, isolation and analysis. Also, the very low amount of chemicals and... 

    Fabrication and Evaluation of Catalytic Microreactors to Verify the Conversion of Ethyl Mercaptan

    , M.Sc. Thesis Sharif University of Technology Karami Basiri, Mohammad (Author) ; Kazemeini, Mohammad (Supervisor)
    Abstract
    Sulfur compounds are largely an impurity in fossil fuels such as natural gas, crude oil and coal. In natural gas, the main sulfur compounds are hydrogen sulfide (H2S), carbonyl sulfide (COS),and C1-C3 mercaptans.Commercial methods for removing these compounds require the introduction of additional reactive substances (O2, H2, Olefins, NaOH, etc.), which often results in the production of other pollutants. Microfluid is a branch of science and technology that involves studying the behavior of fluid, the use of fluid and the manufacture of equipment or systems that are carried out in micro-channels.The dimensions of these canals are about ten to several hundred micrometers, and high of... 

    Using Molecular Dynamics Simulation for Investigation of Sulfuric Compounds Adsorption on Zeolite

    , M.Sc. Thesis Sharif University of Technology Ramezani Shabolaghi, Kianoush (Author) ; Mohammadi, Aliasghar (Supervisor)
    Abstract
    There are different sulfur compounds in the crude oil, and after combustion all of these sulfuric compounds produce sulfur dioxide, this sulfur dioxide cause acid rain, deactivation of catalysts and also environmental bad effects. So the amount of sulfur that is released should be controlled and this is done by removing sulfuric compounds before combustion. zeolites as adsorbent of sulfuric compounds has been used widely by researches and had given good results. molecular dynamics simulation as an effective way for describing the behavior of these compounds in the molecular level and in scales of angstrom has been used and the effect of van der waals and electrostatic forces between sorbates... 

    The Investigation of Adsorption Desulfurization of Ethyl Mercaptan by Microfluidic Technology

    , M.Sc. Thesis Sharif University of Technology Alizadeh, Ayda (Author) ; Mohammadi, Ali Asghar (Supervisor)
    Abstract
    In recent years, desulfurization has received much attention due to its devastating environmental effects. The existence of sulfur compounds has effects such as corrosion, poisoning of catalysts, reduction of heat of combustion and reduction of price. Sulfur compounds in hydrocarbon fuels also produce sulfur oxides caused by combustion then they enter the atmosphere, and cause acid rain. Acid rain dissolves building materials, poisons lakes, and destroys forests. Therefore, removing sulfur or converting it to less harmful substances is one of the most important processes in refineries. The method studied in this research is the use of adsorption desulfurization method by microchannel which... 

    Design, manufacture and application of a microreactor for the decomposition of ethyl mercaptan on an H-ZSM-5 catalyst

    , Article Journal of Cleaner Production ; Volume 292 , 2021 ; 09596526 (ISSN) Hosseinpour, V ; Kazemeini, M ; Mohammadi, A ; Rashidi, A ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    Catalytic decomposition of the ethyl mercaptan over an H-ZSM-5 zeolite in a newly designed microreactor was undertaken in this study. A numerically developed distributor possessing superior flow distribution was amended to 24 parallel microchannels with 64 mm length, 700 μm width, and 600 μm depth. Ethyl mercaptan complete conversion required 350 °C through the developed microreactor while in a conventional fixed-bed-reactor 400 °C was needed. Higher selectivity towards the main products of this decomposition (hydrogen sulfide and ethylene) were observed in this microreactor in comparison to that of a fixed-bed-reactor. In addition, lower selectivity towards formation of byproducts was... 

    Micro-Channel Fabrication and Evaluation to Remove Mercaptan from Gas Streams

    , Ph.D. Dissertation Sharif University of Technology Hosseinpour, Vahid (Author) ; Kazemeini, Mohammad (Supervisor) ; Mohammadi, Ali Asghar (Supervisor) ; Rashidi, Alimorad (Supervisor)
    Abstract
    Due to the potential risk of sulfur compounds in fossil fuels and according to today’s regulations, sulfur content should be kept as low as possible, e.g., below 5 ppm. Mercaptans are one of the sulfur components in natural gas. Scope of this research defined as catalytic removal of ethyl mercaptan from the gas stream. For this purpose, two microreactor systems placed in series. In the first microreactor, catalytic decomposition of ethyl mercaptan has been investigated. In the first step of this survey, a microreactor with 24 microchannels with a newly designed distributor has been developed with a computational fluid dynamic technique. in comparison to the conventional triangular...