Sharif Digital Repository

In this work, an exergy analysis is performed for the waste heat recovery section (WHRS) of the steam-natural gas reforming (SNGR) process as a major energy intensive process. Two alternate conditions are investigated to evaluate the required thermodynamic parameters: normal operating condition and increase of C2+ components in the process feed stream. At normal operating condition, the exergy efficiency of WHRS amounts to 0.58 while some 17.2 kJ energy is destructed for each mole of H2 produced. If heavier than methane components are increased in the feed up to 8.5 mole %, despite the increase of H2 production, the exergy efficiency decreases down to 0.54... 

In this work, steady state and dynamic performances of quaternary distillation column sequences designed based on steady state and dynamic cost functions have been investigated. To quantify the dynamic performance, product losses due to disturbances have been considered in the objective function. In addition, variations of operating costs such as utilities have been considered in the objective function. To separate a quaternary mixture into four products, 22 configurations have been used. It has been observed that the feed composition, disturbance frequency and magnitude affect the dynamic behavior strongly. To decrease the optimization computational load, a scheme that provides a suboptimal... 

This article reports the first oil-absorbent cross-linked copolymer consisting of modified multiwalled carbon nanotube (MWCNT) and showing high oil absorbency. Also, to investigate and evaluate the effective parameters on oil absorbency, cross-linked dodecyl methacrylate (DDMA)-diphenylacrylamide (DPAA) and DDMA-butyl acrylate (BA) copolymers were synthesized. DDMA was copolymerized with different mol% of DPAA or BA and cross-linked using azobisisobutyronitrile as the initiator and various weight percentages of 1,4-butandiol dimethacrylate, methylene bisacrylamide, or vinyl group-modified MWCNT cross-linkers. The effects of monomer feed composition, cross-linker concentration, and the... 

The objective of this study is the investigation of formaldehyde degradation in a bioreactor with pumice stone as a support. The reactor was tested at different synthetic wastewater concentrations with total COD of 500, 1000 and 1500 mgL, respectively, at 24 h hydraulic retention time. The effect of feed composition was tested by changing the COD TCOD FA ratio in order to analyze the impact of formaldehyde concentration. The average formaldehyde and COD removal efficiencies obtained in the reactor were 97.1% and 88%, respectively. The maximum COD and formaldehyde removal efficiencies occurred at the COD TCOD F of 41 at COD T=1000mgL. The effect of toxic shock on reactor performance was...