Sharif Digital Repository

The aim of this paper was to improve the magnetic properties of magnetoplumbite-type (M-type) strontium hexaferrite substituted with Co 2+-La3+ produced by conventional ceramic forming techniques. The effect on the magnetic properties of varying the composition of the target compound Sr1-xLaxFe12-yCo yO19 and the primary and secondary firing temperatures was investigated. Microstructure studies and XRD phase analysis indicated that optimum values of the remanent magnetization Br and coercive field Hcj were obtained with a primary firing temperature of 1240 C and a final firing temperature of 1180 C, where (x=y)th 1=0.15, (y/x)exp 2=0.75 and the molar ratio of ferric oxide to strontium... 

Analcime shell-nickel ferrite core microspheres were decorated with Pd and Pt nanoparticles with the aid of an ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF6). The samples thus prepared were characterized using X-ray powder diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), nitrogen adsorption-desorption isotherms, transmission electron microscopy (TEM) and vibrating sample magnetometer (VSM) methods. The XRD patterns confirmed the growth of a zeolitic layer on the surface of the magnetic cores. The thermogravimetric analysis (TGA) curve clearly indicated the thermal decomposition of the loaded IL, which confirmed the presence of... 

A relationship between ferrite grain size, cooling rate from austenitising temperature, austenitising time, and austenitising temperature is developed to predict the ferrite grain size of a low carbon steel. The coefficients of that relationship are determined experimentally. A Hall-Petch relationship is used to predict the yield stress and fracture stress from the predicted ferrite grain size. Considering the experimental results, maximum errors of 12-5% and 6·5% were found in the prediction of ferrite grain size and strengths, respectively  

Aromatic and cyclic organic compounds such as nitrobenzene (NB) are widely used in various industries and are present in their wastewater. In addition, the photocatalytic process has received considerable attention due to its lower chemical consumption and more efficient degradation of refractory pollutants. In this study, a CoFe2O4-ZnO (CFZ) composite was prepared and evaluated its efficiency in the degradation of NB from aqueous solution under UV light. The optical, structural, and physicochemical properties of catalysts were characterized using PL, UV–vis DRS, XRD, TEM, FESEM-EDS, and VSM techniques and then discussed in detail. It was found that not only does the use of CF facilitate the... 

The Sonogashira reaction using nickel ferrite nanoparticles as catalyst and under copper-free conditions was investigated in water as a green solvent. Various types of aryl and alkyl halides were successfully coupled with phenyl acetylene under the optimized reaction conditions with very good to excellent yields at a short time. The catalyst is easily recoverable and can be reused for several runs with a good turnover number  

Nickel ferrite nanoparticle is a soft magnetic material whose appealing properties as well as various technical applications have rendered it as one of the most attractive class of materials; its technical applications range from its utility as a sensor and catalyst to its utility in biomedical processes. The present paper focuses first on the synthesis of NiFe2O4 nanoparticles through co-precipitation method resulting in calcined nanoparticles that were achieved at different times and at a constant temperature (773 k). Afterward, they were dispersed in water that was mixed by chitosan. Chitosan was bonded on the surface of nanoparticles by controlling the pH of media. In order to assess the... 

We propose a wideband circularly polarized antenna that consists of a metallic patch and some parasitically coupled elements mounted on a grounded dielectric-ferrite substrate. The metallic patch is fed by a proximity-coupled feed line placed between the ferrite and the dielectric layers. The parasitically coupled elements are included to improve the impedance bandwidth of antenna and are excited through the metallic patch. The antenna utilizes the resonant modes of the structure, which rotate only in the clockwise or counter-clockwise direction. A semi-Analytical solution based on the magnetic wall approximation shows that the resonance frequencies of the clock-and counter-clockwise... 

This study focuses on developing an efficient material that integrates high adsorption performances of dye and antibiotics as well as effective oxidation activity of it. Herein, we report a facile method to synthesize polyresorcinol@CoFe2 O4 via a one-step hydrothermally route. The prepared composite possesses multifunctional performance for methylene blue (MB) and tetracycline (TC) removal with appropriate magnetic separation operation and significant removal ability with an adsorption capacity of 51.48 and 28.16 mg g–1, respectively. Meanwhile, the aforementioned composite exhibits a high oxidation activity toward MB and TC molecules where the adsorption capacity increases to 1,723 and 120... 

The effects of Misch-Metal (MM) oxide addition on magnetic properties, crystal structure and microstructure of the M-type strontium ferrite have been studied. By MM substitution of Sr a significant increase in intrinsic coercivity and a slight decrease in remanence was observed. The highest value of energy product was obtained at 4 wt.% MM addition. By calculating the lattice constants of 4 and 8 wt.% MM added specimens, it was found that the length of c-axis decreases by 4 wt.% MM addition and then undergoes a considerable increase at 8 wt.%, while the a-axis increases monotonously. The SEM observations revealed that the migration of MM oxides to the grain boundaries could be the major... 

An enhancement in heat transfer due to nanofluids is essentially required in various thermal systems. Hybrid nanofluids possess high thermal conductivity and, have ability to embellish and enhance the thermal strength of common fluids. Our concern in this paper is to examine the innovative attributes of hybrid nanofluids like Manganese zinc ferrite (MnZnFe2O4) and Nickel zinc ferrite (NiZnFe2O4) in the bio-convective flow of motile gyrotactic microorganisms subject to Darcy Forchheimer medium. The effect of activation energy has also been taken into account. Mathematical treatment is carried out via MATLAB software. The use of MnZnFe2O4 - NiZnFe2O4/H2O exhibits improved thermal... 

We propose, for the first time, a tunable left-handed (LH) waveguide consisting of an array of complementary split-ring resonators built on the broad wall of a rectangular waveguide filled with ferrite material. The left-handed behavior is caused by the negative permittivity of the complementary split-ring resonators together with the negative permeability of the transversely magnetized ferrite. The electromagnetic behavior of this structure is studied by means of an equivalent circuit model. From this model, the dispersion relation of the guide is derived and validated numerically by the finite element method. It is shown that this structure has a left-handed frequency band that can be... 

In this research, an algorithm based on the Q-state Potts model is presented for modeling the austenite to ferrite transformation. In the algorithm, it is possible to exactly track boundary migration of the phase formed during transformation. In the algorithm, effects of changes in chemical free energy, strain free energy and interfacial energies of austenite-austenite, ferrite-ferrite and austenite-ferrite during transformation are considered. From the algorithm, the kinetics of transformation and mean ferrite grain size for different cooling rates are calculated. It is found that there is a good agreement between the calculated and experimental results  

In this study nickel ferrite magnetic nanoparticles were applied as an efficient and reusable catalyst in the four-component synthesis of substituted pyrroles under neat conditions. The reaction was conducted using various amounts of catalyst at different temperatures and finally, application of 5 mol% of catalyst at 100 °C was determined as the optimum reaction condition. Results showed that nickel ferrite nanoparticles could catalyze the reaction at relatively short times (3-4 h) with high to excellent yields (70-96%). The catalyst could be recovered easily using an external magnetic field and reused nine times without any significant activity lost  

We have designed and fabricated a dual-band circularly polarized antenna using a normally magnetized ferrite disk. The disk is metallized on top and is mounted on a grounded dielectric substrate. A hole is then punched at the center of the top metallization. The dual band operation of the antenna is due to two separate unidirectional resonances. The field intensity at the lower resonance is largest close to the outer periphery of the disk whereas at the higher resonance the electromagnetic field is concentrates near the punched hole. A two-section feeding network is used to feed the antenna. Central frequencies of the upper and lower bands are 4.62 GHz and 5.97 GHz, respectively.... 

Ca-doped Ni–Mg–Mn spinel ferrites with compositions of Ni0·5Mg0·3Mn0.2CaxFe2-xO4 (x = 0, 0.1, 0.2, 0.3, 0.4, 0.5) were prepared via sol-gel auto-ignition technique. TGA/DTA, FTIR, XRD, FESEM, and VSM were employed to evaluate the thermal, spectral, structural, morphological, and magnetic features of Ca-doped Ni–Mg–Mn spinel ferrites. TGA/DTA curves show the weight loss in the sample. This weight loss was attributed to the oxidation and decomposition of the sample contents at a temperature of 500 °C. XRD reveals a single-phase structure of the Ni–Mg–Mn nano ferrites. A single-phase orthorhombic structure was confirmed for Ca-doped Ni–Mg–Mn ferrites. Structural parameters such as lattice... 

We theoretically investigate the formation of hotspots at microwave frequencies in a partially filled, ferrite-loaded rectangular waveguide. When the unidirectional mode of this waveguide approaches an impenetrable conducting barrier, its magnetic field rises sharply due to the absence of reflection. To study this phenomenon, we use the magnetostatic approximation and derive a surface integral equation for the normal component of magnetic flux density on the surface of the ferrite layer. For a half-filled waveguide, an analytic solution is found, which shows the magnetic field to diverge near the barrier as | x | - q, where | x | is the distance from the barrier edge and q is slightly less... 

A partially filled, ferrite-loaded rectangular waveguide can support a unidirectional propagating mode. We theoretically study the tunneling of this mode through finite conducting and non-conducting barriers. For a half-filled waveguide and a conducting barrier, the problem is treated analytically. Other filling factors and/or barrier types are investigated by means of a numerical technique. It is found that despite the absence of back-scattering, the passage of the unidirectional wave through a barrier is accompanied by significant power loss, even for short barriers. This phenomenon is caused by the sharp rise in field amplitude close to the barrier, and cannot be eliminated by reducing... 

AISI 4340 steel was heated to 910 °C for 1 h then directly transferred to 750 °C and intercritically annealed for different times to obtain different ferrite volume fractions and then isothermally held at 350 °C for 40 min followed by air cooling to room temperature. Samples of these steels with dual phase ferrite-bainite structure were tensile tested at room temperature. The tensile flow stress data for this steel with different ferrite volume fraction was analyzed in term of Hollomon equation. It is seen that the two Hollomon equations can describe the flow behavior adequately and found that the work hardening takes place in two stages which each equation belong to the one of work... 

We experimentally demonstrate a circularly polarized antenna that utilizes unidirectional surface waves that propagate on the boundary of a small ferrite disk. The ferrite disk is metalized on top and is mounted on a grounded dielectric substrate. The disk is normally biased by a magnetic field that is provided by two permanent magnets below and above the structure. A two-section feeding network is used to feed the antenna. The operation frequency of the antenna can be adjusted by changing the magnitude of the applied magnetic bias. The sense of polarization can be reversed by reversing the direction of the applied bias. © 2020 Elsevier B.V