Sharif Digital Repository

A relationship between ferrite grain size, cooling rate from austenitising temperature, austenitising time, and austenitising temperature is developed to predict the ferrite grain size of a low carbon steel. The coefficients of that relationship are determined experimentally. A Hall-Petch relationship is used to predict the yield stress and fracture stress from the predicted ferrite grain size. Considering the experimental results, maximum errors of 12-5% and 6·5% were found in the prediction of ferrite grain size and strengths, respectively  

In this work, a three-dimensional model has been proposed to predict temperature distribution and weld-pool shape during dissimilar arc welding of low-carbon steel (CK4) and ferritic stainless steel (AISI 409). The model has been developed using the finite-element software ANSYS, while in the analysis, the effects of process parameters, as well as dilution, in the weld pool have been considered. To verify the predictions, welding experiments were conducted under different welding conditions, and the model results were then compared with the measured weld-pool geometry; a reasonable consistency was observed  

CuCo2O4 spinel nanopowders were synthesized by sol–gel method. The optimal values of pH and molar ratio of citric acid to metal ions (RC), and the influence of the calcination temperature and time were investigated. As-prepared materials were characterized by XRD, TGA, DSC, FE-SEM and electrical and coefficient of thermal expansion (CTE) measurements. It was found that pH = 4.5 and RC = 1 are the optimum conditions to produce pure CuCo2O4 nanopowders. The electrical conductivity was increased remarkably from 15.2 to 27.5 S cm−1 with an increase in temperature from 500 to 800 °C. Over the temperature range of 25–800 °C, the CTE of... 

The conductive CuCo2O4 spinel coating is applied on the surface of the AISI 430 ferritic stainless steel by the dip-coating sol-gel process and it is evaluated in terms of the microstructure, oxidation resistance and electrical conductivity. The results show that the CuCO2O 4 coating forms a double-layer scale consisting of a Cr, Fe-rich subscale and Cu-Co spinel top layer after 500 h in air at 800 °C. This scale is protective, acts as an effective barrier against Cr migration into the outer oxide layer and alleviates the cathode Cr-poisoning. The oxidation resistance is significantly enhanced by the protective coating with a parabolic rate constant of 5.8 × 10-13 gr2 cm-4 s -1, meanwhile... 

In this work, examinations on the microstructure and mechanical properties of plain carbon steel and AISI 430 ferritic stainless steel dissimilar welds are carried out. Welding is conducted in both autogenous and using ER309L austenitic filler rod conditions through gas tungsten arc welding process. The results indicate that fully-ferritic and duplex ferritic-martensitic microstructures are formed for autogenous and filler-added welds, respectively. Carbide precipitation and formation of martensite at ferrite grain boundaries (intergranular martensite) as well as grain growth occur in the heat affected zone (HAZ) of AISI 430 steel. It is found that weld heat input can strongly affect grain... 

In an attempt to reduce the oxidation and Cr evaporation rates, various protective coating layers with a nominal composition of NiCo 2-xFexO4 (x = 0, 0.5, 1) were deposited on the SUS 430 ferritic stainless steel substrate, as interconnect for solid oxide fuel cell application, by sol-gel dip coating method. Then, the coated samples were soaked at 750 C for 2.5 h in N2 and subsequently for 2.5 h in air. Phase composition and microstructure of the coatings were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Moreover, long-term isothermal oxidation experiment and area specific resistance (ASR) measurement were also carried out on the coated samples. Results... 

In the present study, a thermo-elastic-plastic model was developed in order to evaluate the residual stresses in dissimilar automatic tungsten inert gas (TIG) welds between plain carbon steel CK4 and a ferritic stainless steel AISI409. The effect of welding heat input on the magnitude and the distribution of residual stresses was investigated and the results of simulation were validated by X-ray diffraction measurements. It is shown that the calculated residual stresses are in good agreement with the residual stresses determined experimentally. It was found that the magnitudes of stresses at the weld center line increases with increasing the welding speed  

To improve the strength and toughness of AISI 4340 steel, different microstructures, containing full bainite, bainite-ferrite, martensite-ferrite and full martensite were produced by different heat treatment cycles. Tensile, impact and hardness tests were carried out at room temperature. The ductile-brittle transition temperature was determined from impact data at different temperatures. The results showed that steel with bainite - 0.34 ferrite microstructure has the highest elongation and charpy impact energy, while its tensile strength and yield stress decreased in comparison to other microstructures. This increment was noticeable when bainite - 0.34 ferrite steel was tempered. The... 

In this study, a thermo-mechanical model was utilized to investigate the effects of welding parameters on the distribution of residual stresses in dissimilar TIG welds of low carbon and ferritic stainless steels. To solve the governing thermal and mechanical problems, a finite element program, ANSYS, was employed while the different aspects such as welding sequence and dilution were considered in the numerical solution. To validate the predictions, the model results were compared with the residual stresses measured by X-ray diffraction technique and a reasonable agreement was found. The results show that the magnitude of tensile residual stresses decrease as the welding current increases... 

The effects of intermediate nickel layer on seal strength and chemical compatibility of seal glass and interconnect materials for solid oxide fuel cells (SOFCs) were investigated. Two types of samples (metal/glass/metal sandwiches and glass coated metals) were prepared with the sheet of AISI 430 (nickel plated and uncoated) and slurry of compliant silicate sealing glass (SCN-1). The joined and coated samples were heated at 850 °C for different time durations (0.5-100 h). Tensile and impact tests were performed and SEM micrographs were used to analyze the glass/metal interaction. The results indicate that nickel plated AISI 430 shows higher adhesion strength at short durations of heating due... 

Solid oxide fuel cell (SOFC) is one of the promising candidates for clean energy production. Due to the high operating temperature of SOFCs, a protective coating is commonly applied on the surface of interconnects to prevent oxidation. In this study, electrophoretic deposition was employed to prepare a manganese-cobalt spinel coating on ferritic stainless steel (AISISAE430) substrates. Nanostructured MnCo2O4 powder with an average crystallite size of 60nm was utilized and the sintering behavior of the coatings at different temperatures was studied. Non-isothermal and isothermal sintering behavior of the powder were examined by employing a sensitive dilatometer. Master sintering curve of the... 

This paper addresses the microstructure and mechanical performance of dissimilar resistance spot welds between AISI 430 ferritic stainless steel and drawing quality special killed (DQSK) low-carbon steel. The mechanical properties of the welds are described by peak load, failure energy, and failure mode during the tensile-shear test. Phase transformations in the fusion zone (FZ) and heat-affected zone (HAZ) are analyzed. The main metallurgical features of the weldment are the formation of a dual-phase, ferrite-martensite microstructure in the FZ, grain growth and martensite formation in the HAZ of the ferritic stainless steel side, and martensitic and eutectoid transformations in the HAZ of... 

Implementation of new materials in automotive body-in-white requires through knowledge of their metallurgical response to welding process thermal cycle. This two-part paper aims at understanding the physical and mechanical metallurgy of stainless steels, as interesting candidates for automotive application, during resistance spot welding. The second part addresses the phase transformations in the heat affected zone of three types of stainless steels including austenitic, ferritic and duplex steels. Failure modes and mechanical properties of stainless steel resistance spot welds are discussed. The peak load and energy absorption of stainless steel resistance spot welds are compared with... 

Weldability is one of the key requirements for automotive materials. This two-part paper aims at understanding the metallurgical phenomena during resistance spot welding of stainless steels, as interesting candidates for automotive body in white. Part I addresses the phase transformations in the fusion zone of three types of stainless steels including austenitic, ferritic and duplex types. The solidification and solid state phenomena including columnar to equiaxed transition, ferrite– austenite post-solidification transformation, martensitic transformation and carbide precipitation are discussed. Particular attention is given to the effect of high cooling rate of resistance spot welding... 

To improve both strength and toughness of AISI 4340 steel three microstructures, full bainite, bainite-ferrite and tempered bainite-ferrite, were produced by heat treatment of this steel. Tensile, impact and hardness properties of these microstructures were compared. The results showed that with tempering of bainite-34% ferrite dual phase steel, elongation and charpy impact energy increased significantly in comparison to bainite and bainite-ferrite microstructures. Also ductile-brittle transition temperatures of bainite-ferrite and tempered bainite-ferrite steels were measured and confirmed superior toughness properties of this microstructure. Fracture surface analysis of charpy specimens... 

The oxidation behavior of three types of stainless steels, namely AISI 321, AISI 316, and AISI 409, was compared. In all stainless steels, oxide layers were formed and their masses and thicknesses increased with oxidation time. Among them, AISI 409 ferritic stainless steel demonstrated higher oxidation rate. According to the kinetical oxidation behavior of them at elevated temperatures, the oxidation mechanism was determined. Among them, the AISI 409 ferritic stainless steel showed the lowest and AISI 321 austenitic stainless steel demonstrated the highest oxidation resistance. Based on the experimental results, it was suggested that the kinetic of oxide growth in stainless steels was... 

The paper addresses the microstructure and failure characteristics of dissimilar resistance spot welds between austenitic stainless steel and ferritic stainless steel. The fusion zone (FZ) of dissimilar welds exhibited complex microstructure consisting of ferrite, austenite and martensite. The development of this triplex structure in the FZ was explained by analysing the phase transformation path and austenite stability. Results showed that all dissimilar welds failed in partial thickness-partial pull-out failure mode. It was shown that the fraction of the nugget fracture of the weld is reduced by increasing the FZ size improving the mechanical performance of the weld. Peak load and energy... 

The possible interactions near the triple-phase boundaries (TPB) metal/glass/air, and their effects on joint strength are investigated. Two types of samples (joined couples and glass coated coupons) are prepared with the coupon of AISI 430 (nickel plated and uncoated) and a slurry of compliant silicate sealing glass (SCN-1). The joined and coated samples are heated at 850 °C for 1000 h in air. The joined couples are cooled using two different schedules and then tested in uniaxial tension. For investigating the metal-oxides precipitation procedure in glass near the TPB, glass coated coupons are either cooled at the rate of 5 °C min−1 or water-quenched from aging temperature. The mechanical...