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    The Experimental Study of Adsorption and Separation of Hydrogen Gas Using Metal-organic Frameworks

    , M.Sc. Thesis Sharif University of Technology Hashemi, Mohammad Mahdi (Author) ; Ghotbi, Cyrus (Supervisor) ; Karimi Sabet, Javad (Supervisor)
    Abstract
    Hydrogen gas is considered as a clean fuel and energy carrier that its storage for future uses is a challenging issue. One of the methods to store it, is adsorption on a group of adsorbents called metal-organic frameworks. In this research, one of these frameworks called ZIF-8, has been selected to study hydrogen storage capability. To evaluate the effect of having two metals, a mixture of two metals was used in the synthesis process. To characterize the structure of the synthesized adsorbents, X-ray powder diffraction (XRD),adsorption and desorption of nitrogen at temperature of 77 K, Field Emission Scanning Electron Microscopy (FESEM), energy-dispersive X-ray Spectroscopy (EDS) and... 

    Synthesis and Investigation of Antistatic Coating Properties Based on Tin Oxide by Sol-Gel Method

    , Ph.D. Dissertation Sharif University of Technology Zakerizadeh, Ali Mohammad (Author) ; Dolati, Abolghasem (Supervisor) ; Abdollah Afshar (Supervisor)
    Abstract
    In order to prevent electrostatic attraction on non-conductive surfaces, the most practical solution is to put antistatic coatings to reduce surface resistance. Nano tin oxide coatings are designed to produce surfaces with antistatic properties in the resistance range of 108-1012 Ω/cm. In this project, using a simple method, low temperature, without heat treatment and without the use of additive (dopant), tin oxide films with antistatic property were placed on the glass. Further, in order to obtain a coating with a suitable morphology and structure to increase the surface conductivity, the synthesis of tin oxide using the sol-gel method at ambient temperature was used. And to place the... 

    Solution Combustion Synthesis of Spinel-type (Cu,Co) 3O4 Nanopowder

    , M.Sc. Thesis Sharif University of Technology Ghorbanzadeh, Milad (Author) ; Yoozbashizadeh, Hossein (Supervisor)
    Abstract
    In this study, nano-powders of copper-cobalt spinel (CuCo2O4) were fabricated by solution combustion synthesis (SCS) of Cu and Co nitrates with urea, glycine,acid citric and alanine. The method involved exothermic decomposition of viscous liquid nitrates and the fuel. Products which were synthesized by using this fuels contained less impurity constituents. Duo to low purity, other factors which have influence on synthesis process investigated and observed that pH have key role on process. X-ray diffraction (XRD) patterns gave crystal structure and the existing phases. Particle size distribution and morphology changes were studied by dynamic light scattering (DLS) and field emission scanning... 

    Microstructure Modification and Electrical Conductivity Development in PA6/PS Blend using PANI Coated CNT

    , M.Sc. Thesis Sharif University of Technology Soleimani, Elahe (Author) ; Bagheri, Reza (Supervisor)
    Abstract
    In this research, a nanocomposite blend of polyamide 6/polystyrene containing polyaniline-coated carbon nanotubes was fabricated via melt blending method, aiming to achieve electrical conductivity in the range of static dissipation. The effect of weight percentage of nanofillers and surface modification of carbon nanotubes with polyaniline on the electrical properties and microstructure of the nanocomposite was investigated. To promote compatibility between the immiscible polyamide 6 and polystyrene polymers, PS-g-MA compatibilizer was utilized, and its effect on the morphology of the nanocomposite blend was examined. Additionally, the influence of weight percentage of nanofillers and the... 

    Structural Rietveld refinement and magnetic features of prosademium (Pr) doped Cu nanocrystalline spinel ferrites

    , Article Ceramics International ; Volume 45, Issue 8 , 2019 , Pages 10187-10195 ; 02728842 (ISSN) Niaz Akhtar, M ; Babar, M ; Qamar, S ; ur Rehman, Z ; Azhar Khan, M ; Sharif University of Technology
    Elsevier Ltd  2019
    Abstract
    Pr doped spinel nanoferrites having following composition Cu Pr x Fe 2-x O 4 (x = 0, 0.25, 0.50, 0.75, 1.00) were synthesized using sol-gel route. Prosademium (Pr) which is a rare earth metal was doped to tailor the properties of the Cu spinel nanoferrites. Characterization tools such as FTIR, XRD, FESEM and VSM were employed to investigate the phase, absorption bands, structure, microstructure and magnetic properties. FTIR was used to see the absorption bands and force constants of the Pr doped Cu spinel nanoferrites. Crystallite size, lattice parameters, cell volume and micro strains were determined from XRD data. Bulk density, X-ray density and porosity of the Pr doped Cu spinel...