Sharif Digital Repository

Combination of fast high-performance liquid chromatography–diode array detection (HPLC–DAD) technique and ultrasonic assisted emulsification micro-extraction (USAEME) as extraction method are used for simultaneous determination of sixteen polycyclic aromatic hydrocarbons (PAHs) in river samples. The optimum conditions of USAEME procedure are selected according to the literature. Due to presence of different chromatographic issues and the complexity of water matrices, multivariate curve resolution-alternating least squares (MCR-ALS) is a good resolution technique for simultaneous quantification of PAHs in standard and real samples. On this matter, region-based and whole chromatographic data... 

In recent years, convolutional neural networks and deep neural networks have been used extensively in various fields of analytical chemistry. The use of these models for calibration tasks has been highly effective; however, few reports have been published on their properties and characteristics of analytical figures of merit. Currently, most performance measures for these types of networks only incorporate some function of prediction error. While useful, these measures are incomplete and cannot be used as an objective comparison among different models. In this report, a new method for calculating the sensitivity of any type of neural network is proposed and studied on both simulated and real... 

Porous PZT-PCN ceramics were fabricated with this formula, “0.8 Pb(Zr1/2Ti1/2)O3-0.2 Pb(Co1/3Nb2/3)O3”, abbreviated as “PZTPCN” by introducing Polyvinyl chloride(PVC) and stearic acid (SA) as pore forming agents (PFA) with varied percentages (5, 10 and 15 wt%). The optimum sintering procedure was designed according to the thermogravimetric analysis of pore formers. XRD and FESEM were applied to study the formed phase and the microstructure of the system. Electrical Characterization was conducted using Piezo meter. A decrease in density reduced longitudinal piezoelectric coefficient (d33) and relative dielectric constant (ε) and enhanced hydrostatic figure of merit (dhgh) of PZTPCN ceramics.... 

Owing to the fact that obtaining useful information from complex analytical systems is one of the keys to make correct decisions about the systems under study, in this chapter, the capabilities and versatility of multivariate curve resolution (MCR) methods are discussed in light of the nowadays issues in qualitative and quantitative analysis in analytical chemistry. In this regard, classification of MCR methods, data structures, data arrangement, bilinear model, and pros and cons of MCR methods is presented. Then, MCR scenarios for qualitative and quantitative purposes in analytical chemistry are discussed in the course of some of the recent applications of MCR methods. Furthermore,... 

Multisensor arrays employing various sensing principles are a rapidly developing field of research as they allow simple and inexpensive quantification of various parameters in complex samples. Quantitative analysis with such systems is based on multivariate regression techniques, and deriving of traditional analytical figures of merit (e.g., sensitivity, selectivity, limit of detection, and limit of quantitation) for such systems is not obvious and straightforward. Nevertheless, it is absolutely needed for further development of the multisensor research field and for introducing these instruments into the general context of analytical chemistry. Here, we report on the protocol for... 

This study presents an up to date progress of the national and international laser research and developments. The number of scientific publications and accepted patents are considered as a figure of merit and based on these numbers the growth pace for the period of 1990-2003 is investigated. The share of top nations in scientific publications and in particular laser publications in term of their Gross Domestic Product (GDP) is presented. Four countries including the USA, Japan, Germany and China have a laser publication contribution of 58.9% while the rest of the world including (189) countries contribute 41.1%. However, for the case of accepted patents, which are the more important factor,... 

Technology scaling increases clock rates and die sizes; therefore, power dissipation is predicted to soon become the key limiting factor on the performance of single-chip designs. NoC as an efficient and scalable on-chip communication architecture for SoC architectures, enables integration of a large number of computational and storage blocks on a single chip. Since different applications impose different traffic models to the network, in this paper we will analyze the power and energy consumption of the most popular traffic models, i.e., Uniform, Local, HotSpot and First Matrix Transpose, in two famous and well designed topologies, mesh and torus. We will also compare these topologies with... 

In this work we investigate the thermal conductivity of graphene-based antidot lattices. A third nearest-neighbor tight-binding model and a forth nearest-neighbor force constant model are employed to study the electronic and phononic band structures of graphene-based antidot lattices. Ballistic transport models are used to evaluate the electronic and the thermal conductivities. Methods to reduce the thermal conductivity and to increase the thermoelectric figure of merit of such structures are studied. Our results indicate that triangular antidot lattices have the smallest thermal conductivity due to longer boundaries and the smallest distance between the neighboring dots  

In this paper, the relation between gain and resolution of an ideal analog optical differentiator in two different cases and their fundamental limits are investigated. Based on this relation, a figure of merit for comparison of the designed differentiators in recent papers is proposed. The differentiators are optimized using this figure of merit, and they are compared with each other to determine the best one. Also, a new differentiator is presented based on the dielectric slab waveguide in which the trade-off between its gain and resolution is easily controllable, and its best operating point is determined. © 2020 Optical Society of America under the terms of the OSA Open Access Publishing... 

In a coherent pulse Doppler radar, ambiguity can occur in both range and radial velocity measurements. PRF staggering has been considered as one of the most effective ways by which these consequential blind speeds can be eliminated. As it stands the optimization of such staggering has not been convincingly provided in a clear format in past studies. In this article previously reported techniques have been studied and also a comprehensive simulation tool which provides interesting results based on different techniques is developed. Furthermore a comparison of various common staggering methods has been given and a cost function has been proposed to describe a figure of merit for each of the... 

Abstract Porous lead zirconate titanate-lead cobalt niobate 0.8Pb(Zr1/2Ti1/2)O3-0.2Pb(Co1/3Nb2/3)O3 (PZT-PCN) piezoelectric ceramics were fabricated by introducing pore-forming agent polymethyl methacrylate (PMMA), and the effect of sintering behavior on their microstructure, dielectric, and piezoelectric properties were investigated. The optimum sintering procedure was designed according to the thermogravimetric analysis of pore former. Finally the electrical properties were measured. The porosity of PZT-PCN ceramics decreased and the grain size increased with an increase in the sintering temperature at a fixed PMMA addition. "An increase in density with sintering temperature from 1050 to... 

In the present study, multivariate analytical figures of merit (AFOM) for three well-known second-order calibration algorithms, parallel factor analysis (PARAFAC), PARAFAC2 and multivariate curve resolution-alternating least squares (MCR-ALS), were investigated in simulated hyphenated chromatographic systems including different artifacts (e.g., noise and peak shifts). Different two- and three-component systems with interferences were simulated. Resolved profiles from the target components were used to build calibration curves and to calculate the multivariate AFOMs, sensitivity (SEN), analytical sensitivity (γ), selectivity (SEL) and limit of detection (LOD). The obtained AFOMs for different... 

This article proposes the theory and implementation of an even-harmonic class-E CMOS oscillator that displays an excellent phase noise performance. Starting from zero voltage switching (ZVS) and zero derivative switching (ZDS) conditions, expressions for drain voltage and current waveforms are derived. Based on a 1:1 transformer, a custom-designed tank is proposed, which satisfies ZVS and ZDS conditions for the core transistors, provides high-Q resonances at both fundamental and second harmonics of the oscillation frequency, and yields a passive voltage gain from the drain to the gate of the core transistors. Satisfying ZVS and ZDS conditions reduces the overlap between the voltage and... 

In recent years, convolutional neural networks and deep neural networks have been used extensively in various fields of analytical chemistry. The use of these models for calibration tasks has been highly effective; however, few reports have been published on their properties and characteristics of analytical figures of merit. Currently, most performance measures for these types of networks only incorporate some function of prediction error. While useful, these measures are incomplete and cannot be used as an objective comparison among different models. In this report, a new method for calculating the sensitivity of any type of neural network is proposed and studied on both simulated and real... 

In this paper we introduce a new low phase noise cascode Cross-coupled oscillator by use of the general topology of Cross-coupled oscillator and cascode amplifier. By simulation a comparison between the conventional Cross-coupled oscillator and the new cascode Cross-coupled oscillator is also presented, which shows that the latter improves the phase noise by 2dB under the same conditions. The figure of merit (FOM) of -186.4 dBc/Hz is achieved for the new oscillator by simulation  

The present contribution is devoted to develop multivariate analytical figures of merit (AFOMs) as a new metric for evaluation of quantitative measurements using comprehensive two-dimensional gas chromatography–mass spectrometry (GC × GC–MS). In this regard, new definition of sensitivity (SEN) is extended to GC × GC–MS data and then, other multivariate AFOMs including analytical SEN (γ), selectivity (SEL) and limit of detection (LOD) are calculated. Also, two frequently used second- and third-order calibration algorithms of multivariate curve resolution-alternating least squares (MCR-ALS) as representative of multi-set methods and parallel factor analysis (PARAFAC) as representative of... 

Thermal stability of the topological color code in the presence of a thermal bath is studied. We study the Lindblad evolution of the observables in the weak-coupling limit of the Born-Markov approximation. The autocorrelation functions of the observables are used as a figure of merit for the thermal stability. We show that all of the observables autocorrelation functions decay exponentially in time. By finding a lower bound of the decay rate, which is a constant independent of the system size, we show that the topological color code is unstable against thermal fluctuations from the bath at finite temperature, even though it is stable at T=0 against local quantum perturbations  

New geometrical counterparts to the conventional Einzel lens, cubic, and the continuous body electrostatic (CBE) lenses are introduced and their performances are investigated in terms of different aberrations and input beam properties. Design curves for the continuous body electrostatic lens are presented. Relative sensitivity is proposed as a figure of merit, based on which the focusing characteristics of the two new lenses are compared with that of a conventional Einzel, and a quadrupole lenses of the same size, as well. Moreover, performance and characteristics of the lenses are compared in terms of their corresponding sensitivities to the applied voltage and the incidence beam...