Sharif Digital Repository

Thermal oxidation of commercial ilmenite concentrate from Kahnouj titanium mines, Iran, at 500-950 C was investigated for the first time. Fractional conversion was calculated from mass change of the samples during oxidation. Maximum FeO to Fe2O3 conversion of 98.63 % occurred at 900 C after 120 min. Curve fit trials together with SEM line scan results indicated constant-size shrinking core model as the closest kinetic mechanism of the oxidation process. Below 750 C, chemical reaction with activation energy of 80.65 kJ mol-1 and between 775 and 950 C, ash diffusion with activation energy of 53.50 kJ mol-1 were the prevailing mechanisms. X-ray diffraction patterns approved presence of... 

In this article, a standard 2D Two-Fluid Model (TFM) closed by the kinetic theory of granular flow (KTGF) has been applied to simulate the behavior of tapered-in and tapered-out fluidized bed reactors. In this regard, two types of chemical reactions with gas volume reduction and increase were considered to investigate the effects of initial static bed height on the fractional conversion and bed pressure drop. To validate the CFD model predictions, the results of hydrodynamic simulations concerning bed pressure drop and bed expansion ratio were compared against experimental data reported in the literature and excellent agreement was observed. The obtained simulation results clearly indicate... 

This article presents a simulation study of tapered-in and tapered-out fluidized bed reactors to investigate the influences of apex angle on the fractional conversion and the pressure drop of the fluidized beds in the presence of two types of chemical reaction with gas volume increase and reduction. The 2D behavior of tapered-in and -out fluidized beds was also compared with a columnar one from fractional conversion and bed pressure drop point of views. To validate the simulation results, the numerical predictions for the expansion ratio and the pressure drop of a tapered fluidized bed were compared with experimental data and good agreement was observed. The obtained simulation results... 

This article presents a simulation study of tapered-in and tapered-out fluidized bed reactors to investigate the influences of apex angle on the fractional conversion and the pressure drop of the fluidized beds in the presence of two types of chemical reaction with gas volume increase and reduction. The 2D behavior of tapered-in and -out fluidized beds was also compared with a columnar one from fractional conversion and bed pressure drop point of views. To validate the simulation results, the numerical predictions for the expansion ratio and the pressure drop of a tapered fluidized bed were compared with experimental data and good agreement was observed. The obtained simulation results... 

This article presents a simulation study of tapered-in and tapered-out fluidized bed reactors to investigate the influences of apex angle on the fractional conversion and the pressure drop of the fluidized beds in the presence of two types of chemical reaction with gas volume increase and reduction. The 2D behavior of tapered-in and -out fluidized beds was also compared with a columnar one from fractional conversion and bed pressure drop point of views. To validate the simulation results, the numerical predictions for the expansion ratio and the pressure drop of a tapered fluidized bed were compared with experimental data and good agreement was observed. The obtained simulation results... 

A modelling of the anaerobic digestion process of molasses was conducted in a 70-L multistage anaerobic biofilm reactor or hybrid anaerobic baffled reactor with six compartments at an operating temperature of 26 °C. Five hydraulic retention times (6, 16, 24, 72 and 120 h) were studied at a constant influent COD concentration of 10,000 mg/L. Two different kinetic models (one was based on a dispersion model with first-order kinetics for substrate consumption and the other based on a modification of the Young equation) were evaluated and compared to predict the organic matter removal efficiency or fractional conversion. The first-order kinetic constant obtained with the dispersion model was... 

An experimental investigation was conducted on the oxidative desulfurization of model sulfur compounds such as dibenzothiophene and benzothiophene in toluene as a simulated light fuel oil with a mixture of hydrogen peroxide as the oxidant and various acids as the catalyst. The influences of various parameters including reaction temperature (T), acid to sulfur molar ratio (Acid/S), oxidant to sulfur molar ratio (O/S), type of acid, and the presence of sodium tungstate and commercial activated carbon as a co-catalyst on the fractional conversion of the model sulfur compounds were investigated. The experimental data obtained were used to determine the reaction rate constant of the model sulfur...