Sharif Digital Repository

Recently separation technology has been developed and engineers are trying to find more rapid and more economic ways in order to reach pure materials. One of the most important needs of human being is natural gas which has some impurities. Acid gases such as carbon dioxide and hydrogen sulfide must be separated from methane. This operation is called gas sweetening. Membrane contactors are equipments recently developed and may be used instead of packed towers for gas sweetening in the future. In this project we designed and made a membrane contacting unit to separate carbon dioxide and hydrogen sulfide from methane. This unit lets you to study the effect of many parameters such as gas and... 

Zeolite membranes are of interest due to their special properties; thermal and mechanical resistances and non-plasticization property in gas separations. Therefore, separation of H2S from natural gas by these membranes is the main goal of this thesis which is not investigated in the world. After some theoretical investigations including diffusion mechanisms of gases in the zeolites and adsorption mechanism of H2S on the zeolites, pure silica CHA-type (Si-CHA) zeolite was selected. After successful synthesis of Si-CHA zeolite, adsorption isotherms of H2S, CO2, and CH4 on the Si-CHA zeolite were measured over pressure range of 0-190 kPa and temperatures of 25 °C, 50 °C, and 75 °C. Acid gases... 

The main application of flares is to protect facilities, staff, and surrounding area. Nevertheless, the flares flue gas contains environmental hazardous compounds like nitrogen oxides, sulfur oxides, and greenhouse gases like carbon dioxide and carbon monoxide. These compounds may spread in environment with unburned hydrocarbons. Due to the contamination risk and energy loss in flaring system, optimization and system enhancement is of vital importance. Flare gas recovery unit consist of equipment like multi-phase separator, Liquid Seal Drum, and compressor. The compressor is the most important part of this unit. Due to the process requirements and the probability of two-phase feed entering... 

Due to the presence of carbon dioxide and hydrogen sulfide in natural gas outlet of wells, it cannot be sent directly to the municipal pipelines. This study was trying to be select and made membranes for separation of CO2 and H2S from methane. Permeability of methane and carbon dioxide gases through the polyurethane membranes were studied. For this purpose, two commercial polyurethane and synthesized polyurethane with different formulations of the compounds that have been studied so far in the literature were used. Synthesized polyurethane and nano-composite membranes were characterized by using Scanning Electron Microscopy (SEM), Differential Scanning Calorimetry (DSC) and Fourier Transfer... 

In the present work, a comprehensive economic, environmental and exergy analysis and multi-objective optimization for gas sweetening plant are provided and the interaction between decision variables in these criterions is discussed. In the first part, potentials of three environmental features (global warming, acid rain, smog formation) of the operational plant are quantified and normalized using life cycle assessment (LCA) for both process waste and utility environmental impacts.Acid rain index is determined as the most important environmental impactindex in this unit. By choosing proper decision variables based on sensitivity analysis, LCA and EA results, optimization is performed to... 

Today, the usage of hollow membrane contactors is considered by the researchers as a novel solution in the separation and purification industry, including the sweetening of gas. Improving the performance of these devices requires a more detailed study of the process factors and changes in its chemistry. Hence, providing a suitable mathematical model by examining the details of the flow pattern within the contactor is based on the computational fluid dynamics technique in the agenda. Also, improving the absorption of components such as carbon dioxide and hydrogen sulfide from the gas mixture using chemical absorbents such as monoethanolamine will be investigated. The change in the mass... 

Acidic gases separation from hydrocarbon mixtures is very important in natural gas industry. In this study, the separation of CO2 and H2S from CH4 investigates by experimental and molecular dynamics simulation approaches. For achievement to this goal, it is used two polymeric families, as be divided to polyurethanes and PEBAX copolymers. It is used 4 polyurethane membranes as are named PU-1, PU-2, PU-Ether, and PU-Ester from polyurethanes group. Also, it is applied 5 PEBAX commercial membranes have be known PEBAX-2533, PEBAX-4033, PEBAX-5533, PEBAX-4011, and PEBAX-1074. It is compared between simulation and experimental works and found that there is good agreement between...