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    Synthesis and microstructural properties of a geopolymer cement with high silica materials

    , Article Journal of Ceramic Processing Research ; Volume 13, Issue 4 , 2012 , Pages 425-428 ; 12299162 (ISSN) Asadi, M ; Naghizadeh, R ; Nemati, A ; Arzani, K ; Nassiri, R ; Sharif University of Technology
    JCPR  2012
    Abstract
    Activities conducted in this study can be divided into two general sections: synthesis and analysis and identifies the properties. A geopolymeric cement production process includes two steps of thermal activation and alkaline activation. Geopolymers are cementitious materials synthesized by a polycondensation reaction between an aluminate and silicate. The geopolymeric structures of the products were investigated by Fourier transform infrared spectroscopy (FTIR), X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). XRD results showed that there are no significant differences between the XRD patterns of geopolymers and metakaolin. The structure of the geopolymer is typically... 

    Investigation of interfacial and mechanical properties of alumina-coated steel fiber reinforced geopolymer composites

    , Article Construction and Building Materials ; Volume 288 , 2021 ; 09500618 (ISSN) Riahi, S ; Nemati, A ; Khodabandeh, A. R ; Baghshahi, S ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    In this study, alumina coated steel reinforced geopolymer composites were successfully fabricated and their interfacial and mechanical properties were investigated. The fiber–matrix interface characteristics were assessed using single-fiber push-out and water contact angle experiments as well as SEM-EDS analysis. Finally, the role of alumina coating on the compressive, flexural and toughness of the geopolymer composites was investigated. The morphological studies revealed that alumina coating on steel can chemically bonded and microstructurally integrated with the surrounding matrix. The push-out test showed that the interfacial shear strength was increased approximately 150% in composites... 

    Waste ceramic powder-based geopolymer mortars: effect of curing temperature and alkaline solution-to-binder ratio

    , Article Construction and Building Materials ; Volume 227 , 2019 ; 09500618 (ISSN) Shoaei, P ; Musaeei, H. R ; Mirlohi, F ; Narimani zamanabadi, S ; Ameri, F ; Bahrami, N ; Sharif University of Technology
    Elsevier Ltd  2019
    Abstract
    In this study, the optimum curing temperature and alkaline solution-to-binder (S:B) ratio of geopolymer mortars based on waste ceramic powder (WCP) were investigated. For this purpose, mixes with S:B ratios of 0.4–0.7 were prepared and cured at 60, 75, 90, and 105 °C. The density, compressive and flexural strengths were measured at 3, 7, 14, and 28 days. Higher S:B ratios enhanced the flow of the fresh mortar. The optimum mortar was obtained for S:B ratio of 0.6 and curing temperature of 90 °C. The SEM analysis revealed that the optimal mix had a dense matrix with minimum pores. © 2019 Elsevier Ltd  

    Corrigendum: “geopolymers vs. alkali-activated materials (AAMs): a comparative study on durability, microstructure, and resistance to elevated temperatures of lightweight mortars” (JCBM 222 (2019) (49–63), (S0950061819315089), (10.1016/j.conbuildmat.2019.06.079))

    , Article Construction and Building Materials ; Volume 283 , 2021 ; 09500618 (ISSN) Ameri, F ; Shoaei, P ; Zareei, A. R ; Behforouz, B ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    The authors regret that there was an error in the XRD pattern for pumice shown in Fig. 8. The authors have re-analyzed the pumice to address the concerns over the reliability of the pattern due to the presence of noises, and the updated XRD pattern has been shown in Fig. 8 here for more accuracy of the presented information. It is noteworthy that this change does not affect any of the conclusions. The authors would like to apologise for any inconvenience caused. © 2021 Elsevier Ltd  

    Geopolymers vs. alkali-activated materials (AAMs): A comparative study on durability, microstructure, and resistance to elevated temperatures of lightweight mortars

    , Article Construction and Building Materials ; Volume 222 , 2019 , Pages 49-63 ; 09500618 (ISSN) Ameri, F ; Shoaei, P ; Zareei, S. A ; Behforouz, B ; Sharif University of Technology
    Elsevier Ltd  2019
    Abstract
    This paper studied the durability, microstructure, and fire behavior of lightweight mortars based on cement, metakaolin (MK), ultrafine ground granulated blast furnace slag (UGGBFS), ceramic waste powder (CWP), and clay brick waste powder (CBWP). Two sets of mixes were prepared with two types of lightweight aggregate including lightweight expanded clay aggregate (LECA) and pumice aggregate. Regarding the durability assessment, the electrical resistivity and water absorption of the mortars were measured. The UGGBFS-based alkali-activated mortar with pumice aggregate exhibited the highest electrical resistivity and lowest water absorption, while CBWP-based geopolymer mortar with LECA showed... 

    Lightweight geopolymer concrete: A critical review on the feasibility, mixture design, durability properties, and microstructure

    , Article Ceramics International ; Volume 48, Issue 8 , 2022 , Pages 10347-10371 ; 02728842 (ISSN) Tale Masoule, M. S ; Bahrami, N ; Karimzadeh, M ; Mohasanati, B ; Shoaei, P ; Ameri, F ; Ozbakkaloglu, T ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Lightweight geopolymer concretes have gained attention because of their superior durability, lower environmental impact and sustainable characteristics. They are the product of natural or artificial aggregates with low specific gravities mixed with aluminosilicate binders, and an alkaline solution. In this study, different aspects of lightweight geopolymer concretes and mortars such as environmental and economic considerations, materials and mixture, durability-related properties like permeability, chloride attacks and performance at high temperatures, thermal conductivity, and the microstructure are reviewed. This study also discusses the effect of different geopolymer binders and various... 

    Experimental and probabilistic investigation on the durability of geopolymer concrete confined with fiber reinforced polymer

    , Article Construction and Building Materials ; Volume 334 , 2022 ; 09500618 (ISSN) Anvari, M ; Toufigh, V ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    This study investigates the durability of confined geopolymer concrete with fiber-reinforced polymer and compares the results with ordinary Portland cement concrete (OPCC). Two hundred and seventy geopolymer concrete (GPC) specimens with different mix designs (fly ash- and granulated blast furnace slag(GBFS)-based GPC) were prepared and then wrapped with two different fiber-reinforced polymers (carbon and glass FRPs). For 12,960 hrs (eighteen months), the specimens were exposed to four different pHs (2.5, 7 (water), 7.25 (saltwater), 12.5). The reliability analysis was performed after modeling the compressive strength over time. Based on the results, the ductility of all specimens decreased... 

    Mechanical Characteristics of Activated Slag Concrete with Alkaline Solution

    , M.Sc. Thesis Sharif University of Technology Esmati, Ali (Author) ; Kazemi, Mohammad Taghi (Supervisor)
    Abstract
    Nowadays, due to the increasing importance of environmental issues, cement replacement has been considered by many researchers .Determination of behavioral characteristics and fracture of materials such as fracture hardness and energy is used to describe the formation and progress of cracks in new building materials. On the other hand, one of the concrete that can be replaced ordinary concrete is slag concrete. Slag concrete is in the category of Geopolymer Concrete. This concrete is produced by activation of puzzulanic material by alkaline solution.There have not been many studies on the failure of slag concrete. Therefore, in this study, the mechanical properties of slag concrete were... 

    Effect of the Blast Furnace Slag on Microstructural and Transport Properties of the Fly Ash-based Geopolymers

    , M.Sc. Thesis Sharif University of Technology Azimi, Zahir (Author) ; Toufigh, Vahab (Supervisor)
    Abstract
    Alkali-activated fly ash-slag (AAFS) is a new type of sustainable construction material widely studied in recent years for its desirable mechanical properties and low environmental impacts. In this study, the effects of the slag incorporation from 10 to 30% of fly ash are investigated on the strength, pore structure, and transport properties of the AAFS with various levels of fly ash replacements with slag. The unconfined compression and ultrasonic pulse velocity tests were performed to evaluate the mechanical properties of the AAFS concrete. Microstructural and mineralogical changes were studied by porosity, N2-adsorption/desorption, and SEM/EDX tests. Additionally, transport properties... 

    Post-fire Behavior Evaluation of Slag-Based Geopolymer Concrete

    , M.Sc. Thesis Sharif University of Technology Palizi, Soheil (Author) ; Toufigh, Vahab (Supervisor)
    Abstract
    Concrete, a versatile construction material, combines cement, aggregates, and water to form a composite known for its durability and adaptability in various architectural and engineering applications. Its widespread use stems from its ability to efficiently bear heavy loads while maintaining longevity. However, producing concrete's key ingredient, cement, contributes significantly to environmental harm by emitting substantial carbon dioxide during its manufacturing process. This carbon footprint underscores the urgent need for sustainable alternatives and innovative practices in the construction industry to mitigate the detrimental effects on our planet. On the other hand, understanding the... 

    Effects of free quartz on mechanical behaviour of kaolinite based geopolymers

    , Article Materials Technology ; Volume 26, Issue 2 , Jul , 2011 , Pages 96-99 ; 10667857 (ISSN) Yousefi, E ; Majidi, B ; Sharif University of Technology
    2011
    Abstract
    Quartz is usually detected as an impurity of kaolinite clays. The present work attempts to evaluate the role and behaviour of quartz particles in geopolymerisation and its probable effects on mechanical behaviour of geopolymeric products. Two kaolinite clays with different free quartz contents were used as raw materials to produce geopolymers. Results showed that using high content quartz kaolin causes higher compressive strength. Scanning electron microscopy studies confirmed that quartz does not participate in geopolymerisation and completely remains in the structure as fine particles. High hardness quartz particles by retarding crack growth in the geopolymer matrix enhance mechanical... 

    The effect of mixing molar ratios and sand particles on microstructure and mechanical properties of metakaolin-based geopolymers

    , Article Materials Chemistry and Physics ; Volume 240 , 2020 Riahi, S ; Nemati, A ; Khodabandeh, A. R ; Baghshahi, S ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    In this study the influence of the molar ratios such as SiO2:Al2O3:Na2O:H2O, as well as the sand particles on the mechanical performance, shrinkage and microstructure of metakaolin based geopolymers was studied. Considering different content of the reactive silica and alumina in metakaolin, forty eight different compositions were prepared. The proper condition for achieving the highest mechanical performance as well as less structural defects by tailoring the curing condition, molar ratios and addition of sand particles are presented. Special attention was paid to the incorporation of sand particles up to 70 wt% on the microstructure, shrinkage and mechanical properties of metakaolin based... 

    Evaluation of compressive and split tensile strength of slag based aluminosilicate geopolymer reinforced by waste polymeric materials using Taguchi method

    , Article Materials Research Express ; Volume 8, Issue 2 , February , 2021 ; 20531591 (ISSN) Khezrloo, A ; Tayebi, M ; Shafiee, A ; Aghaie, A ; Sharif University of Technology
    IOP Publishing Ltd  2021
    Abstract
    In this work, slag based aluminosilicate geopolymer was reinforced with polymeric fibers including, polyester (PES) (waste tire cap plies), polymeric particles including polyethylene terephthalate (PET) (waste water bottle), styrene-butadiene rubber (SBR) (waste tire), and polyvinyl chloride (PVC) (waste water hose). The tensile and compressive strength of the material was evaluated. Taguchi method was employed to assess the influence of the effective parameters on the mechanical characteristics of the geopolymer composite. QUALITEK-4 software was used to create the L32 orthogonal array with 192 (96+96) geopolymer specimens and 32+32 experiments. Analysis of variance (ANOVA) was utilized to... 

    Evaluation of geopolymer concrete at high temperatures: An experimental study using machine learning

    , Article Journal of Cleaner Production ; Volume 372 , 2022 ; 09596526 (ISSN) Rahmati, M ; Toufigh, V ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Studying the mechanical performance of concrete after being exposed to high temperatures is an important step in the damage assessment of buildings and fire safety applications. However, predicting the compressive strength of GPC accurately after exposure to high temperatures is a challenging task. In this paper, artificial neural network (ANN) and support vector regression (SVR) models were developed to predict the compressive strength of geopolymer concrete (GPC) at high temperatures ranging from 100 °C to 1000 °C. A series of experiments consisting of different mix designs were conducted at elevated temperatures to prepare a dataset. Besides experiments' results, the data of previously... 

    An innovative inverse analysis based on the Bayesian inference for concrete material

    , Article Ultrasonics ; Volume 124 , 2022 ; 0041624X (ISSN) Nouri, A ; Toufigh, V ; Sharif University of Technology
    Elsevier B.V  2022
    Abstract
    Nondestructive tests and evaluations are robust techniques for inspecting different attributes of concrete configuration. However, most nondestructive techniques focused on an aspect of concrete configuration based on comparison to other samples. In this paper, an innovative inverse analysis technique was developed to inspect different attributes of concrete configuration simultaneously. The methodology was based on the scattering feature of the ultrasonic waves during propagation in heterogeneous media. The transition matrix method was employed to determine the scattered wavefield. This method considers the shape of objects, unlike most other numerical methods. Furthermore, a novel... 

    Multi-scale dispersive gradient elasticity model with rotation for the particulate composite

    , Article Composite Structures ; Volume 294 , 2022 ; 02638223 (ISSN) Nouri, A ; Toufigh, V ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Research on the characteristics of composites material has received enormous interest in recent years. The multi-scale nature of composite material leads to employing advanced techniques. Moreover, the presence of a wave with the high-frequency source adds complexity to the analysis. In this paper, a novel multi-scale elasticity model was developed to predict the wave dispersion property of particulate composites. The methodology was based on the simultaneous participation of translational and rotational degrees of freedom in motion equations. The method scheme of gaining motion equations was accomplished by using Taylor's expansion as a continualization method. The framework of the motion... 

    Investigation of Fracture Behavior of Geopolymer Concrete

    , M.Sc. Thesis Sharif University of Technology Karamian, Mohammad Hossain (Author) ; Toufigh, Vahab (Supervisor)
    Abstract
    Geopolymer concrete is one of the most environmentally friendly concretes that does not have any pollutants harmful to the environment. By-products that are normally harmful to the environment can be used in manufacturing this product, therefore, the use of this concrete is known as the first concrete replacement in the world. In order to use geopolymer concrete, it is necessary to an essential to know the mechanical information of these materials.In this study, the mechanical behavior of geopolymer concrete for fly ash and slag in terms of its stress and strain uniaxial loading and triaxial loading at , and15MPa pressures for three concrete mixing design are investigated.Then the... 

    Nondestructive Test in Geopolymer Concrete with Aid of Ultrasonic Waves

    , M.Sc. Thesis Sharif University of Technology Nouri, Ali (Author) ; Toufigh, Vahab (Supervisor)
    Abstract
    In recent decades, particle composite materials have a wide range of applications in engineering. Particle composites are a group of heterogeneous materials with different length scales and are characterized by particles that are randomly distributed in a matrix phase. Geopolymer concrete is a special type of concrete that its binder is made by reacting alumina and silicate carriers with an activating agent and in recent years with the expansion of its use has reduced the amount of cement consumption. In addition to the many advantages of geopolymer concrete, it has disadvantages in terms of setting time. That is why the use of cement has been proposed as a solution to the problem. This... 

    Investigation of Mechanical Properties and Durability of Alkali-activated Slag Concrete Lightened with Scoria and Its Microstructural Study

    , M.Sc. Thesis Sharif University of Technology Mahmoudzadeh Vaziri, Nima (Author) ; Khaloo, Alireza (Supervisor)
    Abstract
    Concrete has long been one of the most widely used materials in the world. Cement, as a major component of concrete, due to the use of fossil fuels in its production process, emitting greenhouse gases such as carbon dioxide, which cause air pollution and environmental issues such as climate change. On the other hand, the wastes of industrial factories such as slag of the Blast furnace, due to their large volume and lack of sufficient space for storage of these wastes, lead to the release of these wastes that have alkaline structures into enviroment, causing environmental pollution Such as embankment pollution. Alkali-activated concrete has prevented the release of these pollutant into the... 

    Damage Detection and Health Monitoring of Geopolymer Concrete Using Ultrasound Waves and Machine Learning

    , M.Sc. Thesis Sharif University of Technology Rahmati, Mohammad (Author) ; Toufigh, Vahab (Supervisor)
    Abstract
    The behavior of construction materials at high temperatures has been an important aspect of researches in recent years. The first part of the current research aims to non-destructively monitor the formation and growth of damage at geopolymer concrete (GPC) after being exposed to high temperatures using linear and nonlinear ultrasonic techniques. Ultrasonic waveform and pulse velocity (UPV) tests were conducted on the specimens before and after exposure to the temperatures. Nonlinear wave signals were processed in phase-space domain for qualitative health monitoring of GPC. Furthermore, feature extraction was applied to phase-plane attractors using fractal dimension for quantitative...