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The Synthesis of Graphene-Nanobubbles and Investigation of their Potential Synergistic Effect on Bacterial Cells
, Ph.D. Dissertation Sharif University of Technology ; Akhavan, Omid (Supervisor) ; Maddah Hosseini, Hamid Reza (Supervisor) ; Bakhsi, Bita (Co-Supervisor)
Abstract
Recently, nanotechnology has promised to create and/ or improve therapeutic methods which in turn remain minimum side effects by employing synergistic effects of nanostructures. However, a comprehensive understanding of the interactions between nanostructures and building blocks of the biological systems (cells) is essential to create innovative therapeutic methods and compound and also predict their behavior for upcoming applications. In this thesis for the first time, synergistic effects of graphene-nanobubbles in interactions with bacterial (as the simplest model) cells were investigated. Therefore, at the first step, production of nanobubbles (NBs) in the presence of two-dimensional...
Developing Classical and Nonlocal Interlayer Shear Models for Free Vibration Analysis of Multilayer Graphene Plates
, Ph.D. Dissertation Sharif University of Technology ; Asghari, Mohsen (Supervisor)
Abstract
Experimental observations on multilayer graphene structures show that interlayer interactions including compressive and shear effects between layers are very important in their mechanical behavior. Existing analytical investigations have generally addressed the issue of pressure interactions between layers using interatomic potentials, while the models which consider the interlayer shear effect are rarely found in the literature. To address this shortcoming, this thesis presents a new formulation for multilayer graphene structures with desired shapes and boundaries, taking into account the interlayer shear effect according to the classical continuum mechanics theory. Next, size-dependent...
Fabrication and characterization of graphene-based carbon hollow spheres for encapsulation of organic corrosion inhibitors
, Article Chemical Engineering Journal ; Volume 352 , 2018 , Pages 909-922 ; 13858947 (ISSN) ; Ramazani, S. A. A ; Mahdavian, M ; Taheri, P ; Mol, J. M. C ; Sharif University of Technology
Elsevier B.V
2018
Abstract
In this work, we synthesized carbon hollow spheres (CHSs) using the silica templating method, encapsulated 2-mercaptobenzimidazole (MBI) inhibitor in the CHSs and evaluated their corrosion inhibition performance upon exposure of mild steel to a saline solution containing the released inhibitor. The effects of silica template surface modification on the CHS structure was evaluated, while the structure and morphology of the synthesized CHS was analyzed using field emission scanning electron microscope (FE-SEM), transmission electron microscope (TEM), Raman spectroscopy and X-ray diffraction (XRD) spectroscopy. Furthermore, thermogravimetric analysis (TGA), energy-dispersive X-ray spectroscopy...