Sharif Digital Repository

The behavior of three types of non-coking coals from Iranian's deposits in thermal regime of tunnel kiln direct reduction of the iron (TKDRI) process has been investigated. The heating condition of raw materials in tunnel kiln was simulated in a vertical TGA for three different non-coking coals. For non-isothermal devolatilization of coals from room temperature to 1100. C, the heating rates of 1.5, 3 and 7. C/min were chosen. Coal mass and volumetric changes during devolatilization were observed by TGA and dilatometry analysis. XRD and scanning electron microscopy of raw coals and chars were used to analyze coal structural changes. In non-isothermal low heating rate pyrolysis of coal, most... 

An interaction between ferrite recrystallization and austenite transformation in low-carbon steel occurs when recrystallization is delayed until the intercritical temperature range by employing high heating rate. The kinetics of recrystallization and transformation is affected by high heating rate and such an interaction. In this study, different levels of strain are applied to low-carbon steel using a severe plastic deformation method. Then, ultra-rapid annealing is performed at different heating rates of 200–1100°C/s and peak temperatures of near critical temperature. Five regimes are proposed to investigate the effects of heating rate, strain, and temperature on the interaction between... 

The behavior of three types of non-coking coals from Iranian's deposits in thermal regime of tunnel kiln direct reduction of the iron (TKDRI) process has been investigated. The heating condition of raw materials in tunnel kiln was simulated in a vertical TGA for three different non-coking coals. For non-isothermal devolatilization of coals from room temperature to 1100 °C, the heating rates of 1.5, 3 and 7 °C/min were chosen. Coal mass and volumetric changes during devolatilization were observed by TGA and dilatometry analysis. XRD and scanning electron microscopy of raw coals and chars were used to analyze coal structural changes. In non-isothermal low heating rate pyrolysis of coal, most... 

Ultra-rapid annealing (URA) of deformed low-carbon steel can provide refined microstructure. In this research, severely deformed low-carbon steel is ultra-rapidly annealed to subcritical and intercritical temperature ranges at the heating rates of 75-1800°C/s and then rapidly cooled. Also, conventional annealing by the heating rate of 0.3°C/s is performed at the same temperature ranges. The results show that conventional and subcritical ultra-rapid annealing cannot lead to a fully refined microstructure. High heating rate causes the interaction between recrystallization and transformation as the temperature exceed Ac1 (intercritical temperature range). High kinetics of transformation during... 

Concurrent precipitation in an age hardenable aluminum alloy determines recrystallization behavior especially grains structure and recrystallization texture during continuous heating. In this study, to investigate the effect of concurrent precipitation on the recrystallization texture and grains structure, a solution treated Al-Cu-Mg alloy has been multi-directionally forged at room temperature and continuously heated with different heating rates (800, 1600 and 2500 K·min− 1) up to 450 °C using Gleeble 3800 thermo-mechanical simulator. At lower heating rates (800 K·min− 1), Goss texture component {110} 〈001〉 (Φ1 = 90°/0°, Φ = 90°/45°, Φ2 = 45°/90°) is developed during continuous heating and... 

Transparent Conductive Electrode (TCE), as an essential part of the optoelectronic devices, has become popular owing to its unique properties such as high optical transmittance and conductivity. Among utilized materials for fabrication of TCE, copper nanofibers (NFs)-network have been attracting much attention due to its extraordinary properties such as low sheet resistance, the scalable manufacturing and low-cost fabrication method. However, many challenges exist in the way of multi-step fabrication of network to increase the NFs continuity and consequently, improvement of their electrical conductivity as TCE. Herein, we report a deep investigation of the effective parameters on diameter... 

Transparent Conductive Electrode (TCE), as an essential part of the optoelectronic devices, has become popular owing to its unique properties such as high optical transmittance and conductivity. Among utilized materials for fabrication of TCE, copper nanofibers (NFs)-network have been attracting much attention due to its extraordinary properties such as low sheet resistance, the scalable manufacturing and low-cost fabrication method. However, many challenges exist in the way of multi-step fabrication of network to increase the NFs continuity and consequently, improvement of their electrical conductivity as TCE. Herein, we report a deep investigation of the effective parameters on diameter... 

Different heating rates of 200-1200 deg;C/s were utilized during ultra-rapid annealing (URA) up to the temperatures of 730 and 760 °C on the severely deformed low carbon steel. Higher hardness, strength and ductility achieved for the sample heated at 730 °C with 600 °C/s due to formation of bimodal grain size (BGS) microstructure than them for non-BGS samples. The BGS enhancement for the hardness, strength and ductility with respect to those of as received sample was 67%, 80% and 7%, respectively, and, with respect to those of severely deformed one was 16%, 44% and 24%, respectively. URA with the heating rate of 200 °C/s and 1000 °C/s leads to fully recrystallized and non-recrystallized... 

(ZnO)1-x(CdO)x nanofibers were fabricated via electrospinning of polymer precursor by subsequent annealing in air. Field emission scanning electron microscopy (FESEM) showed the smooth and beadless nanofibers and X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) showed the ZnO hexagonal and the CdO cubic structure. Diffuse reflectance spectroscopy (DRS) showed the band gap energy reduction by increasing the amount of CdO in (ZnO)1-x(CdO)x nanofibers that resulted in the photocatalytic activity under the visible light for dye degradation. Under the UV light CdO acted as both electron and hole sink in the (ZnO) 1-x(CdO)x nanofibers and a possible photocatalytic activity... 

A molecular dynamics simulation study has been performed to investigate the solidification and remelting of aluminum using Sutton-Chen many body potential. Different numbers of atoms from 108 to 2048 atoms were considered to find an adequate size for the system. Three different cooling and heating rates, i.e. 10 12 K/s, 10 13 K/s and 10 14 K/s, were used. The structure of the system was examined using radial distribution function. The melting and crystallization temperatures of aluminum were evaluated by calculating the variation of heat capacity during the phase transformation. Additionally, Wendt-Abraham parameters were calculated to determine the glass transition temperature. It is shown... 

Particle stimulated nucleation (PSN) is one of the important mechanisms of recrystallization which is investigated in this research during non-isothermal annealing of multi-directionally forged solution treated aluminum alloy 2024. Non-isothermal annealing is performed up to temperatures of 380 °C and 450 °C at heating rates of 10, 100 and 200 K·min− 1 using a Gleeble 3800 thermo-mechanical simulator. In order to investigate the microstructure, field emission gun scanning electron microscope (FEG-SEM) equipped with electron backscatter diffractometer (EBSD) and differential scanning calorimetry (DSC) are utilized. The results show that the heating rate has a significant effect on the PSN and... 

The pyrolysis of low-volatile Tabas anthracite coal was investigated by thermogravimetric technique (TGA) in the temperature range from ambient to 1100 °C under non-isothermal heating conditions (1.5, 3, and 7 °C/min heating rates). Higher heating rates showed a small retarding effect on devolatilization toward higher temperatures. Iso-conversional method was used for the kinetic study of non-isothermal Thermogravimetric data. Activation energy calculated for coal conversion of 20–80% was about 319 kJ/mol which may be a result of stable ordered structure of this type of coal. Analysis of evolved gases by Fourier transform infrared spectrometry (FTIR) in 7 °C/min heating rate was conducted... 

In this study, apatite formation ability on TiO2 nanotubes (TNTs) synthesized by anodizing process were compared with TNTs decorated by MnO nanoparticles. The MnO nanoparticles used for decoration process were fabricated via thermal decomposition method. At first, it was strived to find the optimal condition of anodizing process and the effect of applied voltages (15 V, 20 V, and 25 V) and process times (15 min, 20 min, and 25 min) on the diameter of the synthesized TNTs was investigated. Results of microscopic characterizations showed that the completely uniform structure of nanotubes with a diameter in the range of about 100–130 nm was achieved after 20 min of anodizing process at an... 

This paper presents a numerical simulation approach to investigate the water effect as an auxiliary fluid in direct contact with various phase change materials (PCMs). The technique is defined as a hybrid method due to the using of an external intermediary for melting process improvement. Oleic acid (OA), coconut oil (CO), hexadecane, and heptadecane are selected as PCMs due to immiscibility in water and differences in density, melting point, and enthalpy of fusion. An auxiliary fluid is embedded above PCM in an enclosure subjected to sinusoidal wall temperature for melting rate increase through density differences improving heat transfer rate due to materials displacement during process....