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heterogeneous-reaction
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Physicochemical and Photocatalytic Properties of Fe, Gd and P Doped TiO2 Nanoparticles
, M.Sc. Thesis Sharif University of Technology ; Ghorbani, Mohammad (Supervisor)
Abstract
Improving the photocatalytic activity of titania nanoparticles and Cognition the mechanisms governing this property, has received more attention in the recent few years. One of the main strategies for improving the photocatalytic activity and modifying the bandgap structure of titania nanoparticles, is incorporation different metallic and nonmetallic ions in the titania lattice. In this study, 1%Fe, 1%Gd and 2%P (molar ratio) doped titania nanoparticles were successfully prepared by a modified sol-gel method in room temperature. The products were characterized with various spectroscopic and analytical techniques to determine their structural, morphological, physicochemical and...
Mathematical modeling of the reaction in an iron ore pellet using a mixture of hydrogen, water vapor, carbon monoxide and carbon dioxide: An isothermal study
, Article Advanced Powder Technology ; Volume 17, Issue 3 , 2006 , Pages 277-295 ; 09218831 (ISSN) ; Motamed Hashemi, M. Y ; Saboohi, Y ; Sharif University of Technology
VSP BV
2006
Abstract
A mathematical time-dependent and isothermal model based on the grain model has been developed to simulate the kinetic and thermal behaviors of a porous iron oxide pellet undergoing chemical reactions with a mixture of hydrogen, carbon monoxide, carbon dioxide and water vapor. Its novelty consists in fact that it can deal with a multi-species reducing gas and oxide pellet. In spite of previous models in which the pure reductant was applied as reducing gas, this model can indicate an actual view of pellet reduction including the effects of reducing gas utility and reducing gas ratio. A finite volume fully implicit technique was applied for solving the governing equations. The model has been...
A non-isothermal, transient model of a non-catalytic reaction in a packed bed with a multi-component high-temperature gas mixture
, Article 3rd M.I.T. Conference on Computational Fluid and Solid Mechanics, Boston, MA, 14 June 2005 through 17 June 2005 ; 2005 , Pages 1023-1025 ; 0080444814 (ISBN); 9780080444819 (ISBN) ; Saboohi, Y ; Sharif University of Technology
2005
Abstract
A mathematical model has been developed to simulate heterogeneous reactions with a complex set of physicochemical and thermal phenomena in a packed bed. These include the chemical reaction itself, the transport of gaseous species in the pores, the generation or consumption of heat by the reactions, and the transport of heat in the porous domain. Solution of complicated sets of governing equations is based upon the concept of a finite volume fully implicit approach. The model has then been applied to analyze the reduction of a hematite pellet in a moving packed bed reactor. © 2005 Elsevier Ltd