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    Effect of annealing temperature on growth of Ce-ZnO nanocomposite thin films: X-ray photoelectron spectroscopy study

    , Article Thin Solid Films ; Volume 520, Issue 2 , November , 2011 , Pages 721-725 ; 00406090 (ISSN) Yousefi, M ; Azimirad, R ; Amiri, M ; Moshfegh, A. Z ; Sharif University of Technology
    2011
    Abstract
    Ce-doped ZnO nanocomposite thin films with Ce/Zn ratio fixed at optimum value (10 at.%) have been prepared via sol-gel method at different annealing temperatures varied from 180 to 500 °C. The synthesized samples were characterized employing atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD) techniques. According to AFM analysis, the average grain size increased from about 70 nm to 150 nm by increasing the annealing temperature from 300 to 500 °C. Moreover, based on the XPS data analysis, it was found that three major metal ions namely Ce 3+, Ce4+, and Zn2+ coexist on the surface of the nanocomposite films. XPS data analysis also revealed that... 

    Enhanced photoelectrochemical activity of Ce doped ZnO nanocomposite thin films under visible light

    , Article Journal of Electroanalytical Chemistry ; Volume 661, Issue 1 , 2011 , Pages 106-112 ; 15726657 (ISSN) Yousefi, M ; Amiri, M ; Azimirad, R ; Moshfegh, A. Z ; Sharif University of Technology
    Abstract
    Ce-doped ZnO and pure ZnO nanocomposite thin films with different Ce/Zn ratios (0, 2, 5, 10, 15, 20, and 30 at.%) have been prepared by sol-gel method at optimum annealing temperature of 500 °C. The synthesized samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and UV-vis spectrophotometry. According to our XPS data analysis, there are three major metal ions namely Ce3+, Ce4+ and Zn 2+ that coexist on the surface. The XRD measurements indicate that the ZnO thin films have a hexagonal wurtzite structure, and CeO2 crystallites formed in the Ce-doped ZnO nanocomposite thin films. Photoelectrochemical property of the samples was studied by three... 

    Well-designed Ag/ZnO/3D graphene structure for dye removal: Adsorption, photocatalysis and physical separation capabilities

    , Article Journal of Colloid and Interface Science ; Volume 537 , 2019 , Pages 66-78 ; 00219797 (ISSN) Kheirabadi, M ; Samadi, M ; Asadian, E ; Zhou, Y ; Dong, C ; Zhang, J ; Moshfegh Zaker, A. R ; Sharif University of Technology
    Academic Press Inc  2019
    Abstract
    In this research, adsorption and photocatalytic degradation process were utilized to remove organic dye from wastewater. To accomplish that, a newly-designed ternary nanostructure based on Ag nanoparticles/ZnO nanorods/three-dimensional graphene network (Ag NPs/ZnO NRs/3DG) was prepared using a combined hydrothermal-photodeposition method. The three-dimensional structure of graphene hydrogel as a support for growth of ZnO nanorods was characterized using field emission scanning electron microscopy (FESEM). In addition, diameter of silver nanoparticles grown on the ZnO nanorods with the average aspect ratio of 5 was determined in the range of 30–80 nm by using transmission electron microscopy...