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    Fractal analysis of asphaltene aggregation phenomena in live oils at elevated pressure and temperature

    , Article Particulate Science and Technology ; 2016 , Pages 1-9 ; 02726351 (ISSN) Mohammadi, S ; Rashidi, F ; Mousavi Dehghani, S. A ; Ghazanfari, M. H ; Sharif University of Technology
    Taylor and Francis Inc  2016
    Abstract
    In this work, high-pressure microscopy technique was used to measure the size and fractal dimension of asphaltene aggregates formed in different live oil samples at elevated pressures and temperatures. It was found that the asphaltene aggregates in live oil samples are irregular fractal-like structures with pressure−temperature-dependent fractal dimensions. By monitoring the variation of the fractal dimension and size of the asphaltene aggregates with pressure and temperature, the mechanisms responsible for asphaltene aggregation process at elevated pressures and temperatures can be well predicted. The range of fractal dimension of asphaltene aggregates in live oils is similar to that... 

    Improving Temperature Stability of Drilling Fluids Polymers Using Nano Particles

    , M.Sc. Thesis Sharif University of Technology Halali, Mohamad Amin (Author) ; Ghotbi, Siroos (Supervisor)
    Abstract
    Water base drilling fluids are the most common drilling fluids in oil and gas operations and biopolymers are the requisite additives used in such kind of fluids frequently. Unfortunately, at harsh conditions of HPHT the polymers undergo thermal degradation which cause serious loss in fluid rheological and filtration properties. Accordingly, this will induce operational pitfalls and tremendous cost. The power of economy along with environmental regulations force us to search for reasonable chemically benign additives to fulfill this need. Nanoparticles are the most promising additives proposed in this study to address this challenge. Regarding their unique exclusive properties, they are able... 

    A novel field applicable mud formula with enhanced fluid loss properties in High Pressure-High temperature well condition containing pistachio shell powder

    , Article Journal of Petroleum Science and Engineering ; Volume 162 , March , 2018 , Pages 378-385 ; 09204105 (ISSN) Davoodi, S ; Ramazani Ahmad, S. A ; Jamshidi, S ; Fellah Jahromi, A ; Sharif University of Technology
    Elsevier B.V  2018
    Abstract
    Sustainable technologies are the main concerns of the 21st century modified oilfield industries. The insufficiency of conventional drilling fluid formulations with a combination of hardly degradable hazardous chemicals as additives raise the demands of field-applicable innovative and environmentally friendly methods. Pistachio Shell discards as degradable wastes, which can intellectually apply in drilling fluid formulation. The experimental oilfield investigations of utilizing pistachio shell powder prove the significant enhancement of rheological properties, reduction of fluid loss and mud cake thickness in both API (Low Pressure —Low Temperature) and High Pressure—High Temperature (HPHT)... 

    Integrated Geomechanical Modeling of Casing Failure; From Lab to Simulation

    , Ph.D. Dissertation Sharif University of Technology Taheri, Reza (Author) ; Pak, Ali (Supervisor) ; Shad, Saeed (Co-Supervisor)
    Abstract
    Casing failure is one of the mainly problems of hydrocarbon fields that may cause wells out of service and impose heavy costs on oil companies. There exist many theories that may cause casing failure including: the plastic behavior of surrounding formations, the effects of reservoir depletion, over-pressured formations, weak cementing operations, fault activation, and local stresses applied on casing. In salt-rich formations, creep behavior can be the main cause of casing failure, too.The purpose of this study is to evaluate the causes affecting casing failure via experimental studies and numerical simulation with the focus on the conditions governing south-west Iranian oil fields, where the... 

    Experimental and modelling investigations of asphaltene precipitation during pressure depletion and gas injection operations

    , Article Petroleum Science and Technology ; Vol. 32, issue. 15 , August , 2014 , pp. 1868-1875 ; ISSN: 10916466 Nakhli, H ; Alizadeh, A ; Afshari, S ; Kharrat, R ; Ghazanfari, M ; Sharif University of Technology
    Abstract
    Asphaltene precipitation problems manifest themselves in different stages of oil reservoirs production. Experimental and modeling investigations are, therefore, employed as promising tools to assist in predictions of asphaltene precipitation problems and selection of proper production facilities. This study concerns experimental and modeling investigations of asphaltene precipitation during natural production and gas injection operations for a heavy Iranian crude oil at reservoir conditions. First, with design and performance of high pressure-high temperature experiments, asphaltene precipitation behavior is comprehensively investigated; the effects of pressure and temperature are fully... 

    Precipitated asphaltene amount at high-pressure and high-temperature conditions

    , Article Energy and Fuels ; Vol. 28, Issue. 3 , 2014 , pp. 1596-1610 ; ISSN: 08870624 Tavakkoli, M ; Panuganti, S. R ; Taghikhani, V ; Pishvaie, M. R ; Chapman, W. G ; Sharif University of Technology
    Abstract
    In the upstream asphaltene flow assurance community, both academics and industries are actively involved to predict the asphaltene deposit profile in wellbores and pipelines. Essential information for such a study is the amount of asphaltenes that can precipitate and, hence, deposit. In this work, the perturbed chain form of the statistical associating fluid theory (PC-SAFT) is applied to predict the asphaltene precipitation onset condition as well as the amount of precipitate under pressure depletion and high-pressure and high-temperature gas injection conditions. Previous PC-SAFT asphaltene studies in crude oil required the compositional data for both flashed gas and flashed liquid. This... 

    Investigating the effects of temperature, pressure, and paraffin groups on the N2 miscibility in hydrocarbon liquids using the interfacial tension measurement method

    , Article Industrial and Engineering Chemistry Research ; Volume 52, Issue 29 , 2013 , Pages 9851-9857 ; 08885885 (ISSN) Zolghadr, A ; Riazi, M ; Escrochi, M ; Ayatollahi, S ; Sharif University of Technology
    2013
    Abstract
    In this study, interfacial tension measurement (IFT) is utilized to assess the impact of temperature, pressure, and paraffin type on a nitrogen injection process as an efficient enhanced oil recovery method. The pure and equilibrium densities of oil in contact with nitrogen are examined to find IFT behavior and gas solubility in oil. The minimum miscible pressure (MMP) of different systems has been measured using the vanishing interfacial tension technique. The experimental results show that IFT decreases linearly with pressure, with two different slopes. The results indicate that IFT values decrease linearly with temperature at different pressure conditions. The obtained IFT values for... 

    Modeling of asphaltene aggregation phenomena in live oil systems at high pressure-high temperature

    , Article Fluid Phase Equilibria ; Volume 423 , 2016 , Pages 55-73 ; 03783812 (ISSN) Mohammadi, S ; Rashidi, F ; Mousavi Dehghani, S. A ; Ghazanfari, M. H ; Sharif University of Technology
    Elsevier 
    Abstract
    In spite of the development of different experimental methods and theoretical models devoted to understand and predict the asphaltene behavior in dead/model oils, the asphaltene aggregation phenomena in live oil systems at high pressure-high temperature conditions has been grossly missing in the available literature. In this study, a population balance model with geometric scaling approach is proposed to simulate the asphaltene aggregates growth in time for live oil systems. Appropriate collision kernels are incorporated to describe the aggregation mechanisms taking into account the effect of pressure, temperature and oil characteristics. In modeling of the asphaltene aggregation phenomena... 

    On the effect of temperature on precipitation and aggregation of asphaltenes in light live oils

    , Article Canadian Journal of Chemical Engineering ; Volume 94, Issue 9 , 2016 , Pages 1820-1829 ; 00084034 (ISSN) Mohammadi, S ; Rashidi, F ; Mousavi Dehghani, S. A ; Ghazanfari, M. H ; Sharif University of Technology
    Wiley-Liss Inc 
    Abstract
    Asphaltene precipitation and deposition is a serious issue in all facets of petroleum production and processing. Despite the numerous experimental efforts concerning asphaltenes, the effect of temperature on asphaltene precipitation and aggregation in live oils remains an elusive and controversial subject in the available literature. In this work, a series of high pressure-high temperature depressurization experiments were designed to assess the effect of temperature on asphaltene precipitation and aggregation in light live oils. Asphaltene related experiments were performed using a high pressure microscope and high pressure-high temperature filtration setup on a light live oil with a low... 

    The Role of Carbon Nanotubes in Improving Thermal Stability of Polymeric Fluids: Experimental and Modeling

    , Article Industrial and Engineering Chemistry Research ; Volume 55, Issue 27 , 2016 , Pages 7514-7534 ; 08885885 (ISSN) Halali, M. A ; Ghotbi, C ; Tahmasbi, K ; Ghazanfari, M. H ; Sharif University of Technology
    American Chemical Society  2016
    Abstract
    At harsh conditions of high pressure high temperature (HPHT), polymers undergo thermal degradation leading to serious loss in fluid rheological and filtration properties. Nanoparticles are the most promising additives proposed to address this challenge. The stability of nanofluids is perused from various facets including rheological and filtration properties, shale stability, and zeta potential. The presence of nanoparticles could amazingly reduce the filtration at high temperatures even by 95%, and it also had a conspicuous effect on shale stability, thermal conductivity, and zeta potential. Experimental data were fit to rheological models to determine the best models describing the... 

    Comparison of the effect of temperature on asphaltene destabilisation in light and heavy live oils

    , Article International Journal of Oil, Gas and Coal Technology ; Volume 16, Issue 4 , 2017 , Pages 342-362 ; 17533317 (ISSN) Mohammadi, S ; Rashidi, F ; Mousavi Dehghani, S. A ; Ghazanfari, M. H ; Sharif University of Technology
    Abstract
    The main objective of this study is to investigate the effect of temperature on asphaltene destabilisation (precipitation/aggregation) in live oils at elevated pressure conditions. Here, the asphaltene related experiments were performed using solid detection systems, high pressure microscope, and high pressure-high temperature filtration apparatuses in two Iranian light and heavy live oils with different characteristics and stability. The obtained results were interpreted in terms of asphaltene onset pressure, size distribution and average diameter of the aggregates, fractal analysis of the aggregates structures, and the amount of asphaltene precipitation. As well, the results of the... 

    Application of a novel acrylamide copolymer containing highly hydrophobic comonomer as filtration control and rheology modifier additive in water-based drilling mud

    , Article Journal of Petroleum Science and Engineering ; Volume 180 , 2019 , Pages 747-755 ; 09204105 (ISSN) Davoodi, S ; Ramazani S.A, A ; Soleimanian, A ; Fellah Jahromi, A ; Sharif University of Technology
    Elsevier B.V  2019
    Abstract
    Deep wells suffer from the instability and disintegration of natural polymers and other commonly used additives under high pressure and high temperature condition. As a result, serious problems such as hydraulic loss, stuck pipe, and high torque and drag are expected to take place which leads to a dramatic increase in cost and time. This study presents the functionality of a novel synthetic based acrylamide-styrene copolymer (SBASC) as a supersede additive for water-based drilling mud. First, the SBASC was synthesized using an emulsion polymerization process and its particle morphological and polymer chain structural properties were determined by Field Emission Scanning Electron Microscopy... 

    Wettability Alteration of Reservoir Rocks to Super Gas-Wet Condition Using Nanocomposite by Applying Contact Angle Measurement for Gas-Crude Oil System

    , M.Sc. Thesis Sharif University of Technology Zandi, Ahmad (Author) ; Ghazanfari, Mohammad Hossien (Supervisor) ; Fatemi, Mobeen (Supervisor) ; Esmaeilzadeh, Pouriya (Co-Supervisor)
    Abstract
    Today, increasing the productivity of reservoirs is more important than in the past, while the use of nanoparticles to change the wettability of rock and increase the recovery factor from the reservoir has been considered by many researchers. Despite previous studies on the use of nanoparticles to change the wettability of rock to gas-wet, the use of nanocomposites with super gas-wet at high temperature and pressure in the crude oil-gas system has rarely been considered. In this research, several nanocomposites with different structures have been synthesized in the laboratory and nanofluids with different formulations have been used to coat the rock thin sections and measure droplet contact... 

    Experimental Investigation of the Effect of Pressure and Gas Composition on the Interfacial Behavior of Gas/Oil System under High Pressure High Temperature Conditions

    , M.Sc. Thesis Sharif University of Technology Meghrazi, Emad (Author) ; Fatemi, Mobeen (Supervisor) ; Ghazanfari, Mohammad Hossein (Co-Supervisor)
    Abstract
    Gas injection process is one of the main methods to increase the hydrocarbon reservoirs. Minimum Miscibility pressure is a key parameter that controls the efficiency of the gas injection process. It depends on the temperature, the composition of the injected gas and the composition of the reservoir fluids. In this study, the interfacial tension of the live oil-gas system of one of the reservoirs of southwestern Iran was obtained by analyzing the Pendant drop method at 225 ° F and different pressures, and then by using the Vanishing Interfacial Tension method, the Minimum Miscibility Pressure has been computed .In this study, pure and base gases such as nitrogen, methane and injection gas of... 

    The effects of nano Mgo on physical and mechanical properties of Al 2O3-SiC composites

    , Article Journal of Ceramic Science and Technology ; Volume 3, Issue 1 , 2012 , Pages 29-34 ; 21909385 (ISSN) Nemati, A ; Surani, F ; Abdizadeh, H ; Baharvandi, H. R ; Sharif University of Technology
    2012
    Abstract
    In this research, the effects of nano-sized MgO in Al2O 3-SiC composites were investigated. The overall changes in the density and mechanical properties of sintered samples (hardness, bending strength and toughness) were evaluated. After mixing, drying and uniaxial compaction of the powders, they were first heat-treated at low temperature in an electric furnace to remove any residuals. They were then heat-treated at high temperature (1700 °C) inside a graphite furnace in argon atmosphere for sintering (at normal and high pressure). The content of MgO in the Al 2O3-10 vol% SiC composite was 0, 500, 1000, and 1500 ppm. Thefracture toughness(KIC)of sintered composite with 10... 

    The Effects of Various Parameters on Wellbore Stability During Drilling Through Shale Formations

    , Article Petroleum Science and Technology ; Volume 33, Issue 12 , 2015 , Pages 1275-1285 ; 10916466 (ISSN) Rafieepour, S ; Ghotbi, C ; Pishvaie, M. R ; Sharif University of Technology
    Taylor and Francis Inc  2015
    Abstract
    Field evidence indicates that the thermal and chemical regimes in wellbore considerably affect the wellbore stability. This study presents a general coupled model for transport of solute, solvent and heat including their combined effects on the wellbore stability. Optimization of drilling fluid parameters is crucial for wellbore stability analysis particularly in high pressure-high temperature environments. The coupled effects of chemical potential and temperature gradients on fluid flow significantly change the pore pressure and stress around a borehole. The effects of various parameters such as mud weight, solute concentration gradient, shale properties, and temperature gradient on... 

    Kinetics of asphaltene aggregation phenomena in live oils

    , Article Journal of Molecular Liquids ; Volume 222 , 2016 , Pages 359-369 ; 01677322 (ISSN) Mohammadi, S ; Rashidi, F ; Ghazanfari, M. H ; Mousavi Dehghani, S. A ; Sharif University of Technology
    Elsevier 
    Abstract
    The thorough knowledge of the asphaltene aggregation phenomena and pressure/temperature related kinetics is helpful for accurate prediction/control of the asphaltene issues in all facets of petroleum production/processing. However, characterizing the asphaltene aggregation phenomena in live oils at high pressure-high temperature conditions is not well discussed in the available literature. In this work, the asphaltene aggregation phenomena as well as the kinetics of aggregation at different levels of pressure and temperature are investigated in light and heavy live oils using high pressure microscope. The results are presented and discussed in terms of asphaltene onset pressure, aggregates... 

    An improvement of thermodynamic micellization model for prediction of asphaltene precipitation during gas injection in heavy crude

    , Article Fluid Phase Equilibria ; Volume 308, Issue 1-2 , September , 2011 , Pages 153-163 ; 03783812 (ISSN) Tavakkoli, M ; Masihi, M ; Ghazanfari, M. H ; Kharrat, R ; Sharif University of Technology
    Abstract
    Thermodynamic micellization model is known as an appropriate approach for prediction of asphaltene precipitation. However, the reliability (i.e. accuracy) of this model for whole range of pressure or injected gas mole percent must be checked. In practice, the accuracy can be improved by using a suitable characterization method. In this research, a computer code for implementing the thermodynamic micellization model has been developed. Having used this program, we make the prediction of asphaltene precipitation by using data reported in the literature as well as the experimental data obtained from high pressure, high temperature asphaltene precipitation experiments under gas injection... 

    Application of Hydrated Basil Seeds (HBS) as the herbal fiber on hole cleaning and filtration control

    , Article Journal of Petroleum Science and Engineering ; Volume 152 , 2017 , Pages 212-228 ; 09204105 (ISSN) Movahedi, H ; Vasheghani Farahani, M ; Jamshidi, S ; Sharif University of Technology
    Elsevier B.V  2017
    Abstract
    Application of the fiber contained fluids has been extensively increased in many industries. In the petroleum industry, fibrous fluids are utilized for different applications. For instance, they have been applied in drilling operations for hole cleaning and cutting removal. In this article, the results of the studies performed on the application of Hydrated Basil Seeds (HBS) as the herbal eco-friendly fiber on hole cleaning and filtration control were presented. In order to investigate the application of HBS on hole cleaning, Polyacrylamide (PA) was added to the pure water to provide the base fluid and HBS at different concentrations were suspended in the base fluid and the effect of HBS on... 

    Estimating the drilling fluid density in the mud technology: Application in high temperature and high pressure petroleum wells

    , Article Heavy Oil: Characteristics, Production and Emerging Technologies ; 2017 , Pages 285-295 ; 9781536108675 (ISBN); 9781536108521 (ISBN) Kamari, A ; Gharagheizi, F ; Shokrollahi, A ; Arabloo, M ; Mohammadi, A. H ; Sharif University of Technology
    Nova Science Publishers, Inc  2017
    Abstract
    Appropriate execution of drilling operation, in particular for high pressure and high temperature wells, requires accurate knowledge of behavior of the drilling fluid density as a function of pressure and temperature. In this communication, a novel mathematicalbased approach is presented to develop a reliable model for predict the density of four drilling fluid including water-based, oil-based, Colloidal Gas Aphron (CGA) and synthetic. To pursue our objective, a predictive model is proposed using a robust soft computing approach namely least square support vector machine (LSSVM) modeling optimized with coupled simulated annealing (CSA) optimization tool. Moreover, leverage approach, in which...