Sharif Digital Repository

The fracture mechanism of hybrid iPP-EPR-GF composites has been studied by notched Charpy, three- and four-point bending fracture tests. The results of impact tests illustrate that increasing both temperature and EPR/GF ratio increases the impact energy of iPP-EPR-GF. Indeed, with increasing temperature, a brittle, ductile, transition temperature (BDTT) occurs. The results of a three-point bending test show that fracture toughness (KIC) can be improved by addition of both GF and EPR. Since the trend in the fracture toughness values is close to what would be expected by the rule of blends, it can be concluded that the use of both GF and EPR has no significant synergistic effect on toughening.... 

Copper based hybrid composites containing nano-sized silicon carbide and carbon nanotubes reinforcements with minimal porosity were fabricated via mechanical milling followed by hot pressing technique. Microstructures of the powders and consolidated materials were studied using scanning electron microscope, X-ray diffraction, Raman spectroscopy, and scanning transmission electron microscope. Microstructural characterization of the materials revealed that the addition of nanosized silicon carbide reinforcement lowered the grain growth rate and enhanced the homogenization during mechanical milling. Microhardness measurements and compression test showed considerable improvements in mechanical... 

The effect of MoS2 lubricant particles on the microstructure, microhardness and tribological behavior of A413/SiCp surface composite, fabricated via friction stir processing (FSP), was studied. For this purpose, the FSP was carried out with tool rotational speed of 1600 r/min, tool travel speed of 25 mm/min and tool tilt angle of 3° through only a “single pass”. The optical and scanning electron microscopies, microhardness and reciprocating wear tests were used to characterize the samples. The results showed that the addition of MoS2 lubricant particles to A413/SiCp surface composite leads to the decrease of friction coefficient and mass loss. In fact, the generation of mechanically mixed... 

A near fully dense mullite-TiB2-CNTs hybrid composite was prepared successfully trough spark plasma sintering. 1 wt%CNT and 10 wt%TiB2 were mixed with nano-sized mullite powders using a high energy mixer mill. Spark plasma sintering was carried out at 1350 °C under the primary and final pressure of 10 MPa and 30 MPa, respectively. XRD results showed mullite and TiB2 as dominant crystalline phases accompanied by tiny peaks of alumina. The microstructure of prepared composites demonstrated uniform distribution of TiB2 reinforcements in mullite matrix without any pores and porosities as a result of near fully densified spark plasma sintered composite. The fracture surface of composite revealed... 

Copper based hybrid composites containing nano-sized silicon carbide and carbon nanotubes reinforcements with minimal porosity were fabricated via mechanical milling followed by hot pressing technique. Microstructures of the powders and consolidated materials were studied using scanning electron microscope, X-ray diffraction, Raman spectroscopy, and scanning transmission electron microscope. Microstructural characterization of the materials revealed that the addition of nanosized silicon carbide reinforcement lowered the grain growth rate and enhanced the homogenization during mechanical milling. Microhardness measurements and compression test showed considerable improvements in mechanical... 

In this investigation, core-shell rubber particles and organically modified clay were added to an epoxy resin and the changes in mechanical behavior were studied. As expected, the yield strength of the organoclay-filled epoxies increased modestly with increasing clay content and the yield strength of the rubber-modified compounds decreased with rubber content. Interestingly, the compressive yield strength of epoxy resins containing both rubber particles and organoclay (a.k.a. hybrid nanocomposites) was found to be independent on organoclay content (up to 5 phr). The fracture toughness of organoclay-filled epoxies increased modestly with clay content and, as expected, the increases in... 

Hybrid composites of MIL-101(Cr) and Nanoporous Graphene with ratios in the range of 10–50% were prepared via hydrothermal synthesis method. This study deals with an experimental investigation on selective oxidation of H2S into elemental sulfur in the range of 200–270 °C, the catalyst activity and selectivity toward sulfur was studied. High-temperature reactor tests indicated that the MIL-101(Cr)–NPG50–Mo could be a promising candidate with conversion and selectivity of 100% and 99.5% at 200 °C. The MIL-101(Cr)–NPG50–Mo stability showed there were not any significant changes in physical properties, the activity was evaluated after 20 h which was completely stable without any changes  

A novel nanohybrid composite of TiO2, SiO2, γ-Fe2O3, and reduced graphene oxide (TiO2@Si:Fe:rGO) is fabricated by the sol-gel method. The properties of the coated film were examined by structural and self-cleaning analyses using simulated discoloration/soiling and roofing tests. The fabricated transparent TiO2@Si:Fe:rGO composite showed excellent photoactivity and wettability, behaving well in self-cleaning applications. The addition of SiO2 improved the crystalline structure and surface hydroxylation of TiO2 nanoparticles. γ-Fe2O3 decreased the recombination rate of e-/h+ pairs, and significantly improved photocatalytic activity under visible light. Moreover, rGO sheets as excellent... 

Nowadays, the significance of sustainability has urged composite manufacturers to replace traditional synthetic fibers with eco-friendly natural alternatives due to their environmental and economic benefits. This work aims to fabricate hybrid polypropylene (PP) composites with short flax fibers, octene-ethylene copolymer (POE) rubber particles, and maleic anhydride-grafted polypropylene (MAPP) compatibilizer. The main goal is to gain an insight into the combined effect of toughening mechanisms induced by the short fibers and rubber particles at the crack tip and wake of composites, which is a crucial step in reaching a balance between toughness and rigidity. In this regard, a novel... 

In the present research, the influence of nanodiamond (ND) and a physical hybrid of ND and fumed nano-SiO2 were investigated on the performance of a typical tire tread compound. The styrene-butadiene rubber (SBR) and cis-butadiene rubber (BR) blend filled with a commercial grade highly dispersive silica at 70 phr loading were used as typical tire tread compound. ND was substituted partially with silica at two different concentrations of 5 and 10phr. Meanwhile, 5 phr of ND/nano-SiO2 hybrids with the weight ratio of 2.5/2.5 and 1/4 were substituted with silica. ND-Filled compounds exhibit increased scorch and cure time compared to controls. Improvement in different characteristics of the...