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    Experimental Investigation of Mobility and Reactivity of Iron Nanoparticles in Porous Media and Application for in-Situ Groundwater Remediation

    , Ph.D. Dissertation Sharif University of Technology Fadaei Tehrani, Mohammad Reza (Author) ; Shamsaei, Abolfazl (Supervisor) ; Vosoughi, Manoochehr (Supervisor)
    Abstract
    In the present study, synthesis, preparation, and application of bimetallic iron/nickel nano-particles were experimentally investigated with the aim of groundwater remediation. Firstly, iron/nickel nano-particles were synthesized according to chemical reduction and stabilization with starch biopolymer, and then characterized. Results confirmed the formation of bimetallic iron/nickel nano-particles with mean size of 75 nm that starch placed around of them. The more stability characteristic and also enough mobility ensure their diffusion through porous media. Secondly, reactivity of synthesized nano-particles for removal of various contaminants including nitrate, chromium, and lead were... 

    Solute dispersion by electroosmotic flow through soft microchannels

    , Article Sensors and Actuators, B: Chemical ; Volume 255, Part 3 , February , 2018 , Pages 3585-3600 ; 09254005 (ISSN) Hoshyargar, V ; Khorami, A ; Ashrafizadeh, S. N ; Sadeghi, A ; Sharif University of Technology
    Elsevier B.V  2018
    Abstract
    We study the hydrodynamic dispersion (HD) by electroosmotic flow in soft microchannels. Considering a fully developed flow in a slit microchannel of low surface potential and adopting the Taylor dispersion theory, we derive analytical solutions for the solute concentration field and the effective dispersion coefficient. We also conduct numerical analyses to broaden the paper's scope to high surface potentials and to specify a criterion for the validity of the Debye-Hückel linearization in soft microconduits as well as to investigate the broadening of an analyte band from the time of injection. It is demonstrated that the effective dispersion coefficient of a neutral solute band is generally... 

    Hydrodynamic dispersion by electroosmotic flow of viscoelastic fluids within a slit microchannel

    , Article Microfluidics and Nanofluidics ; Volume 22, Issue 1 , January , 2018 ; 16134982 (ISSN) Hoshyargar, V ; Talebi, M ; Ashrafizadeh, S. N ; Sadeghi, A ; Sharif University of Technology
    Springer Verlag  2018
    Abstract
    The biofluids being manipulated in lab-on-a-chip devices usually contain elastic macromolecules. Accordingly, for an accurate modeling of the relevant flow physics one should invoke viscoelastic constitutive equations. In this paper, attention is paid toward the hydrodynamic dispersion by the fully developed electroosmotic flow of PTT viscoelastic fluids in slit microchannels of low zeta potential. Adopting the Taylor–Aris approach, analytical solutions are derived for late-time solute concentration and effective dispersion coefficient. Finite element-based numerical simulations are also conducted to monitor the broadening of an analyte band from the moment of injection. Both approaches are... 

    The effect of pH and ionic strength on the transport of alumina nanofluids in water-saturated porous media: Experimental and modeling study

    , Article Journal of Thermal Analysis and Calorimetry ; Volume 137, Issue 4 , 2019 , Pages 1169-1179 ; 13886150 (ISSN) Zareei, M ; Yoozbashizadeh, H ; Madaah Hosseini, H. R ; Sharif University of Technology
    Springer Netherlands  2019
    Abstract
    Alumina nanofluids are one of the most useful nanofluids, especially for increasing the thermal conductivity. Due to importance of porous media in the improvement of heat transfer, this study investigates the transport and retention of gamma alumina/water nanofluid in the water-saturated porous media. For this purpose, alumina nanofluids were introduced to the porous media consisting of water-saturated glass beads possessing various pH values (4, 7 and 10) and different ionic strengths (0.001 M of KCl, CaCl2, AlCl3, K2SO4, CaSO4, Al2(SO4)3, K2CO3 and CaCO3). Then the break through curve of each experiment was drawn and modeled by combining classical filtration theory with... 

    Tuning the dispersion of reactive solute by steady and oscillatory electroosmotic-Poiseuille flows in polyelectrolyte-grafted micro/nanotubes

    , Article Journal of Fluid Mechanics ; 2019 , Pages 73-112 ; 00221120 (ISSN) Reshadi, M ; Saidi, M. H ; Sharif University of Technology
    Cambridge University Press  2019
    Abstract
    This paper extends the analysis of solute dispersion in electrohydrodynamic flows to the case of band broadening in polyelectrolyte-grafted (soft) capillaries by accounting for the effects of ion partitioning, irreversible catalytic reaction and pulsatile flow actuation. In the Debye-Hückel limit, we present the benchmark solutions of electric potential and velocity distribution pertinent to steady and oscillatory mixed electroosmotic-pressure-driven flows in soft capillaries. Afterwards, the mathematical models of band broadening based on the Taylor-Aris theory and generalized dispersion method are presented to investigate the late-time asymptotic state and all-time evolution of... 

    Tuning the dispersion of reactive solute by steady and oscillatory electroosmotic-Poiseuille flows in polyelectrolyte-grafted micro/nanotubes

    , Article Journal of Fluid Mechanics ; 2019 , Pages 73-112 ; 00221120 (ISSN) Reshadi, M ; Saidi, M. H ; Sharif University of Technology
    Cambridge University Press  2019
    Abstract
    This paper extends the analysis of solute dispersion in electrohydrodynamic flows to the case of band broadening in polyelectrolyte-grafted (soft) capillaries by accounting for the effects of ion partitioning, irreversible catalytic reaction and pulsatile flow actuation. In the Debye-Hückel limit, we present the benchmark solutions of electric potential and velocity distribution pertinent to steady and oscillatory mixed electroosmotic-pressure-driven flows in soft capillaries. Afterwards, the mathematical models of band broadening based on the Taylor-Aris theory and generalized dispersion method are presented to investigate the late-time asymptotic state and all-time evolution of... 

    Effect of gas impurity on the convective dissolution of CO2 in porous media

    , Article Energy ; Volume 199 , May , 2020 Mahmoodpour, S ; Amooie, M. A ; Rostami, B ; Bahrami, F ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    Growing needs for energy and the essential role of fossil fuels in energy market require attempts such as carbon dioxide (CO2) sequestration in saline aquifers to stabilize and mitigate atmospheric carbon concentrations. The possibility of co-injection of impurities along with CO2 allows for the direct disposal of flue gas and hence a significant reduction in the cost of CO2 sequestration projects by eliminating the separation process. In this study, the results of series of novel experiments in a high-pressure visual porous cell are reported, which allow for visually and quantitatively examining the dynamics of convective dissolution in brine-saturated porous media in the presence of an...