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    Characterization of three-dimensional reduced graphene oxide/copper oxide heterostructures for hydrogen sulfide gas sensing application

    , Article Journal of Alloys and Compounds ; Volume 740 , 2018 , Pages 1024-1031 ; 09258388 (ISSN) Mirmotallebi, M ; Iraji zad, A ; Hosseini, Z. S ; Jokar, E ; Sharif University of Technology
    Elsevier Ltd  2018
    Abstract
    Three-dimensional reduced graphene oxide (3D-rGO) structures decorated with CuO particles (GCu) are synthesized through a simple and scalable method for detection of hydrogen sulfide (H2S) gas. For characterization and investigation of porous structure various techniques were employed. Decorated 3D structures demonstrated higher sensitivity and selectivity in comparison to pure structure. Optimized structure for sensing was obtained through introducing different amounts of CuO. The GCu heterostructures containing 35 μmol of CuO powder demonstrated reproducible response of about 30% to the concentration of 10 ppm at room temperature, while complete recovery was obtained through heating to 150... 

    Impact of rock mineralogy on reservoir souring: A geochemical modeling study

    , Article Chemical Geology ; Volume 555 , November , 2020 Li, H ; Zhang, L ; Liu, L ; Shabani, A ; Sharif University of Technology
    Elsevier B. V  2020
    Abstract
    The petroleum industry suffers from reservoir souring phenomena, which has negative impacts on production facilities, health, and environment. Injection of incompatible water into the reservoir (waterflooding), which is considered as an enhanced oil recovery (EOR) method, is one of the most common causes of reservoir souring. In general, injected brine, especially seawater, contains high amounts of sulfate ion (SO42−). A high concentration of sulfate in the presence of sulfate-reducing bacteria (SRB) leads to the microbial reservoir souring. During this phenomenon, sulfide, specifically hydrogen sulfide gas (H2S) appears in the producing fluid of the reservoir. In this paper, a coupled...