Sharif Digital Repository

Nickel hydroxide modified nickel electrodes prepared by cycling the potential of a nickel electrode in alkaline solution exhibited electrocatalytic activity for the oxidation of methane in alkaline media. In the presence of methane the oxidation peak current of nickel hydroxide increases while that of the reverse process decreases. This is attributed to the mediation of nickel species, probably β-NiOOH phase, in the process of electrocatalysis. The mechanism of methane oxidation has also been discussed in terms of the formations of intermediates normally encountered in small organics electro-oxidation. It has also been suggested that in the further oxidation of the intermediates, ions in the... 

The compound, lead hydroxide Pb6O4(OH)4, was prepared by a method used for the first time in the authors laboratory. The compound was identified by XRD and it's purity was determined by analytical methods (100%). The thermal characteristics of this compound were investigated by using a thermogravimetry (TGA). This compound was found to be stable at room temperature and at 160°C will decompose completely to produce lead (II) oxide. © Sharif University of Technology, April 2007  

Desulfurization by molten caustic leaching (MCL) at 400–500 °C has been investigated in order to reduce the sulfur content of petroleum coke. Effective parameters on desulfurization of petroleum coke, other than temperature, include alkali to feed (petroleum coke) mass ratio, time and mesh size in the ranges of 0.5–1.5, 1–3 h and 200–600 µm, respectively. In this work, petroleum coke desulfurization conditions using solid KOH have been studied. Maximum petroleum coke desulfurization by MCL method has been obtained by Taguchi L9 design using alkali to feed mass ratio of 1, temperature of 600 °C, time of 2 h and mesh size of 200 µm. The changes in the main groups on the coke surface have been... 

A novel amperometric non-enzymatic glucose sensor is designed by the facile preparation method. It is made by electrodeposition of Cu clusters and converting them to Cu(OH)2 nanotubes (Cu(OH)2NTs) arrays along with thin-film electro-polymerized of spindle-shaped polypyrrole (PPy@Cu(OH)2NTs), which have been doped by using sodium Benzene-1,3-disulfonate as an anion dopant. Various electrochemical methods investigate the electrochemical performance of the modified electrode toward glucose detection. Under the optimized conditions, a significant electrochemical response improvement is observed toward the electro-oxidation of glucose on the PPy@Cu(OH)2NTs electrode's surface relative to the... 

In this work the effects of backwash pressure, duration of acid and sodium hydroxide backwashing, sodium hydroxide concentration, and the duration of forward washing on performance of permeate flux recovery (PFR) were investigated. A two-level fractional factorial design (FFD) was used to design the experiments. The ability of back propagation neural network (BPNN) and radial basis function neural network (RBFNN) in predicting the performance of cleaning-in-place (CIP) of hydrophilic polyethersulfone (PES) membrane were investigated. It is found that BPNN has better ability in predicting the PFR performance than RBFNN. The best architecture of BPNN was a network consisting of 1 hidden layer... 

Demand for more efficient energy storage devices stimulates efforts to search and develop new materials and composites with promising properties. In this regard, composite materials, including carbonaceous materials and metal oxides have attracted a great attention due to better electrochemical performance as compared to their single material analogues. For the first time, herein, we report a new and simple procedure for preparing porous highly oriented pyrolytic graphite/nickel hydroxide composite (P-HOPG/Ni(OH)2) via a fast and simple two-step electrochemical method including potentiostatic routes. In the first step, a low anodic potential (2 V) was applied to pristine HOPG in 0.5 M H2SO4... 

The present work reports the synthesis of a Pt-modified NiO–Al2O3 nanocomposite derived from graphene-supported layered double hydroxide (Pt–NiO/G) and demonstrates its catalytic activity. The resulting Pt–NiO/G nanocomposite was characterized by FT-IR, XRD, FE-SEM, TEM and XPS techniques and used for catalytic reduction of p-nitrophenol (P-NP) to p-aminophenol (P-AP). The influence of graphene on catalytic activity was comparatively considered by preparation of Pt–NiO nanoparticles derived from layered double hydroxide. The superior catalytic performance of Pt–NiO/G was ascribed to the synergistic effect between Pt and NiO. Furthermore, reduction of P-NP was considered to follow a... 

In this work, a novel heterogeneous organocatalyst was synthesized by immobilization of hydroxide ions on the modified salep as a natural polymer. Because of the grafting of ionic polymer chains onto the salep backbone, catalyst has high loading level of hydroxide ions (3.01 mmol/g). The resulting catalyst shows excellent activity in the synthesis of 4H-benzo[b]pyrans in water at room temperature in short reaction times. The present catalyst and protocol represent a simple, ecologically safe and cost-effective route to synthesize 4H-benzo[b]pyrans with high product yield, as well as easy catalyst recycling