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Mechanical and Microstructural Behavior of Al1050/TiO2-Gr Nano-Composite Produced via Friction Stir Processing
, M.Sc. Thesis Sharif University of Technology ; Movahedi, Mojtaba (Supervisor) ; Kokabi, Amir Hossein (Supervisor)
Abstract
In the presented research, feasibility of producing hybrid nano-composite on the surface of Al1050 with TiO2 (~15 nm) and Graphite (~100 μm) reinforcement particles via Friction Stir Processing (FSP) has been investigated. 1.93%, 1.68% and 1.44% are the weight percentage of added reinforcement particles in the nano-composite. Rotational and travelling speeds (and their ratio, ω/v) and volume fraction of the embedded reinforcement particles, mentioned as variable parameters in this research. Despite, effect of these parameters on the microstructural evolution and mechanical properties such as strength, hardness and wear, were studied. Results in the ratio of Gr/TiO2 = 1/3, revealed that by...
In-Situ Synthesis of Zif-8 Nanocomposite Coating on Carbon Steel and Investigating the Effect of Adding Mbt on Corrosion Behavior and Sic Nanoparticles on Mechanical Properties
, M.Sc. Thesis Sharif University of Technology ; Abachi, Parvin (Supervisor) ; Dolati, Abolghasem (Supervisor)
Abstract
Nowadays, metal-organic frameworks have received a lot of attention due to their properties and characteristics such as controllable structure, high specific surface area and the tunable porosity size and have found many applications. One group of metal-organic frameworks are zeolitic imidazolate frameworks which ZIF-8 is a member of this family, and many studies have been conducted on it. In the present study, ZIF-8 nanocomposite coating was applied to the plain carbon steel substrate by synthesis at room temperature and immersion method, and its corrosion behavior and mechanical properties were investigated. The effect of Mercaptobenzothiazole (MBT) inhibitor on corrosion behavior and...
Fabrication and Mechanical Properties of Alumina- Zirconia- CNT Nanocomposite Parts
, M.Sc. Thesis Sharif University of Technology ; Faghihi Sani, Mohammad Ali (Supervisor) ; Shakhesi, Saeeid (Supervisor)
Abstract
Alumina as an engineering ceramic has special characteristics such as hardness, high abrasive, fatigue and corrosion resistance but suffers from low toughness. One effective method in improving toughness is adding second phases such as tetragonal zirconia and carbon nanotubes.
In this research, alumina- zirconia nanopowders has been prepared by solution combustion method and carbon nanotubes was added to it by two different ways: 1) in situ synthesis of CNTs by CVD 2) dispersion of CNTs by heterocoagulation method. In the case of in situ synthesis of CNTs in AZ matrix, the synthesis temperature and flow ratio of N2/C2H2 gases was investigated and optimum conditions were 800̊C and 300/30,...
In this research, alumina- zirconia nanopowders has been prepared by solution combustion method and carbon nanotubes was added to it by two different ways: 1) in situ synthesis of CNTs by CVD 2) dispersion of CNTs by heterocoagulation method. In the case of in situ synthesis of CNTs in AZ matrix, the synthesis temperature and flow ratio of N2/C2H2 gases was investigated and optimum conditions were 800̊C and 300/30,...
Producing and Study on Properties of TiB2–TiC–Al2O3 Composite Prepared by Mechanically Activated SHS Method
, M.Sc. Thesis Sharif University of Technology ; Youzbashizadeh, Hossein (Supervisor)
Abstract
Metal matrix composites (MMCs) reinforced with ceramic particulates have been attractive as high specific strength materials utilized in automobile and aerospace industries. In order to enhance refinement and dispersibility of the ceramic particulates, the synthesis process with in-situ reactions has been investigated. The in-situ synthesis can avoid complexity and harmfulness.processes of powder handling and produce fine inclusions in the matrix with rather lower costs than conventional fabrication methods. In this study, the Al-based composites with TiC, TiB2 and Al2O3 particulates have been prepared by the by mechanically activated self-propagating high-temperature synthesis (MASHS) on...
Preparation of a Polyoxotungstate-Based Inorganic-Organic Hybrid Catalyst and the Application in Sulfide Oxidation and Azide-Alkyne Cycloaddition Reactions
, M.Sc. Thesis Sharif University of Technology ; Bagherzadeh, Mojtaba (Supervisor)
Abstract
In this study polyoxotungstate-based inorganic-organic hybrid [C272H162N80Cu16.5W36O129Na9] .80.5H2O was synthesized in situ. This inorganic-organic hybrid resulted from the reaction between copper salt and sodium tungstate with the benzimidazole ligand. Combining inorganic-organic hybrid with polyoxotungstate improved the ability of this catalytic system in oxidation and cycloaddition reactions. The resulting product was identified by IR, X-ray diffraction (XRD), elemental analysis (CHNS), inductively coupled plasma (ICP-OES), field emission scanning electron microscope (FE-SEM) and EDX were technique. The catalyst was used in optimal conditions in sulfide oxidation and azide-alkyne...
In situ synthesis of quasi-needle-like bimetallic organic frameworks on highly porous graphene scaffolds for efficient electrocatalytic water oxidation
, Article Chemical Communications ; Volume 56, Issue 21 , 2020 , Pages 3135-3138 ; Hasanzadeh, M ; Mojaddami, M ; Shahriyar Far, H ; Simchi, A ; Sharif University of Technology
Royal Society of Chemistry
2020
Abstract
We present enhanced electrocatalytic activity of three-dimensional graphene scaffolds by decoration with one-dimensional CoxNi1-x MOF nanostructures (0 ≤ x ≤ 1). The decreased overpotential and fast kinetics of the oxygen evolution reaction as compared with the existing materials are shown. The developed bimetallic MOF/3DG composites have great potential to be used in electrocatalytic water oxidation. This journal is © The Royal Society of Chemistry
In situ synthesized TiO2-polyurethane nanocomposite for bypass graft application: In vitro endothelialization and degradation
, Article Materials Science and Engineering C ; Volume 114 , May , 2020 ; Bagheri, R ; Pourjavadi, A ; Ghanbari, H ; Sharif University of Technology
Elsevier Ltd
2020
Abstract
The in vitro endothelial response of human umbilical vein endothelial cells was investigated on a poly (caprolactone)-based polyurethane surface vs an in situ TiO2-polyurethane nanocomposite surface, which has been produced as scaffolds for artificial vascular graft. The in situ synthesis of TiO2 nanoparticles in polyurethane provided surface properties that facilitated cellular adhesion, cell sensing, cell probing and especially cell migration. Cells on the nanocomposite surface have elongated morphology and were able to produce more extracellular matrix. All of these advantages led to an increase in the rate of endothelialization of the nanocomposite scaffold surface vs pure polyurethane....
In situ synthesis of nanocrystalline Al6063 matrix nanocomposite powder via reactive mechanical alloying
, Article Materials Science and Engineering A ; Volume 527, Issue 18-19 , 2010 , Pages 4897-4905 ; 09215093 (ISSN) ; Simchi, A ; Kim, H. S ; Sharif University of Technology
2010
Abstract
In this work, nanocrystalline Al6063 composite powder reinforced with nanometric oxide ceramic particles was synthesized via an in situ solid-gas reaction during high-energy mechanical alloying under a mixture of argon-oxygen atmosphere. The effect of oxygen volume fraction on the morphological evolution and microstructural changes during mechanical alloying was studied by various analytical techniques including optical and electron microscopy, X-ray diffraction, laser particle size analysis, apparent density measurement, and microhardness test. The reactive mechanical alloying resulted in the formation of amorphous Al- and Al-Mg-Si-Fe oxides with a size range of 40-100. nm and volume...