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indium-compounds
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Solvent Extraction of Indium from PlS Solution Produced of Zinc Concentrate Leaching
, M.Sc. Thesis Sharif University of Technology ; Yoozbashizadeh, Hossein (Supervisor)
Abstract
Indium is one of the most important metals in electronics and nuclear industry with increasing demand. The most important application of Indium is in the preparation of thin films containing this metal in LCD manufacturing, television, laptops, monitors and CD players. Indium is a rare metal and it has not original mineral. The most important source of it is zinc minerals and regularly obtained from processing by-products of this minerals. The main problem of production of Indium is the simultaneous presence iron ions in the solution of dissolved minerals of zinc. In this project, extraction of Indium from acidic pregnant leaching solution of roasted zinc concentrate contained at less than...
On optimal dynamic pegging in rescheduling for new order arrival
, Article Computers and Industrial Engineering ; Volume 136 , 2019 , Pages 46-56 ; 03608352 (ISSN) ; Saitou, K ; Sharif University of Technology
Elsevier Ltd
2019
Abstract
A rescheduling method for new order arrival is presented based on the concept of dynamic pegging in multi-level production. Upon the arrival of new, unplanned orders, dynamic pegging enables the re-assignment of the Work-In-Progress (WIP) to the existing or newly arrived orders in such a way that the cost of rescheduling is minimized. A simple yet inspiring Mixed Integer Programming (MIP) model is proposed that combines dynamic pegging with rescheduling. The resulting schedules are compared with the ones obtained from two other basic rescheduling approaches. Analysis of the comparisons confirm the superiority of the proposed method in terms of total rescheduling costs. © 2019
Influence of coloring voltage and thickness on electrochromical properties of e-beam eaporated W O3 thin films
, Article Journal of the Electrochemical Society ; Volume 153, Issue 2 , 2006 , Pages E11-E16 ; 00134651 (ISSN) ; Akhavan, O ; Moshfegh, A. Z ; Sharif University of Technology
2006
Abstract
In this investigation, the effect of coloring voltage and thickness on optical and also electrochromical properties of W O3 thin films has been studied. The W O3 thin films were grown on glass and indium tin oxide coated conducting glass substrates by e-beam evaporation at different thicknesses of 200, 400, and 700 nm. Optical properties of the deposited samples were characterized in the ultraviolet-visible range (300-1100 nm). The optical bandgap energy of the W O3 was obtained in a range of 3.3-3.5 eV showing its increase by decreasing the film thickness. The refractive index of the W O3 films was measured around 2 in the visible range. Surface chemical states of the films were studied by...
Determining influence of different factors on production optimization by developing production scenarios
, Article Journal of Petroleum Exploration and Production Technology ; Volume 8, Issue 2 , June , 2018 , Pages 505-520 ; 21900558 (ISSN) ; Daryasafar, A ; Bakhshi, P ; Tavakoli, R ; Ghayyem, M. A ; Sharif University of Technology
Springer Verlag
2018
Abstract
Production optimization is defined as the process of maximizing oil production over the long term while minimizing total production costs. The overall goal is to achieve the optimum profitability from the well or field. In this process, the reservoir system can be considered as a multiple input–output system. In this complex system injection and production wells are known as inputs and outputs. The output of the system is often affected by various parameters consisting reservoir conditions, petrophysics, and PVT data. The optimization of the injector rates and number and installation of submersible pumps are the main issues which have been studied in this paper. Determining the factor with...
Investigation of precursors concentration in spray solution on the optoelectronic properties of CuInSe2 thin films deposited by spray pyrolysis method
, Article Journal of Materials Science: Materials in Electronics ; 2020 ; Ghorashi, S. M. B ; Tajabadi, F ; Taghavinia, N ; Sharif University of Technology
Springer
2020
Abstract
Copper indium selenide CuInSe2(CISe) thin films were deposited by chemical spray pyrolysis (CSP) method of CuInS2(CIS) and subsequent selenization process. To study the effects of solution concentration, we prepared different precursors solution of CIS including different amount of indium salts from 0.025 to 0.100 M with In/Cu 1.25 and S/In 4. These results propose that solution concentration is critical for inflecting the morphological, optical, electrical, and electrochemical characteristics of solution-processed CISe films and device performance. The studied morphological properties of deposited samples were homogenous, crack-free with large grains in indium salt concentrations more than...
Predictive-reactive rescheduling for new order arrivals with optimal dynamic pegging
, Article 16th IEEE International Conference on Automation Science and Engineering, CASE 2020, 20 August 2020 through 21 August 2020 ; Volume 2020-August , 8 October , 2020 , Pages 710-715 ; Saitou, K ; Sharif University of Technology
IEEE Computer Society
2020
Abstract
This paper presents a new predictive-reactive rescheduling method for adjusting production schedules in response to the unplanned arrival of new orders in multi-level production. It is based on the concept of dynamic pegging, which enables the reassignment of the Work-In-Progress (WIP) to the existing or newly arrived orders at the time of rescheduling. Extending our previous work on reactive rescheduling with dynamic pegging, the new approach incorporates a probabilistic predictive model of new order arrival in the initial scheduling at the begging of the scheduling horizon. A Mixed Integer Programming (MIP) model is developed for two-phase, predictive-reactive scheduling before and after...
Investigation of precursors concentration in spray solution on the optoelectronic properties of CuInSe2 thin films deposited by spray pyrolysis method
, Article Journal of Materials Science: Materials in Electronics ; Volume 32, Issue 21 , 2021 , Pages 25748-25757 ; 09574522 (ISSN) ; Ghorashi, S. M. B ; Tajabadi, F ; Taghavinia, N ; Sharif University of Technology
Springer
2021
Abstract
Copper indium selenide CuInSe2(CISe) thin films were deposited by chemical spray pyrolysis (CSP) method of CuInS2(CIS) and subsequent selenization process. To study the effects of solution concentration, we prepared different precursors solution of CIS including different amount of indium salts from 0.025 to 0.100 M with In/Cu 1.25 and S/In 4. These results propose that solution concentration is critical for inflecting the morphological, optical, electrical, and electrochemical characteristics of solution-processed CISe films and device performance. The studied morphological properties of deposited samples were homogenous, crack-free with large grains in indium salt concentrations more than...
The laser-assisted field effect transistor gas sensor based on morphological zinc-excited tin-doped in2o3 nanowires
, Article Surface Review and Letters ; Volume 24, Issue 8 , 2017 ; 0218625X (ISSN) ; Khosravinejad, F ; Sharif University of Technology
Abstract
The gas nanosensor of indium oxide nanowires in laser assisted approach, doped with tin and zinc for gas sensing and 1D growth purposes respectively, was reported. The nanowires were very sensitive to H2S gas in low concentration of 20 ppb gas at room temperature. The fast dynamic intensive and sensitive response to gas was in a few seconds with an on/off sensitivity ratio of around 10. The square cross-section indium oxide nanowires were fabricated through physical vapor deposition (PVD) mechanism and annealing approach. The field emission scanning electron microscopy (FESEM) observations indicated that the annealing temperature was vital in nanostructures' morphology. The fabricated...
Improved performance of low cost CuInS2 superstrate-type solar cells using Zinc assisted spray pyrolysis processing
, Article Journal of Physics D: Applied Physics ; Volume 50, Issue 48 , 2017 ; 00223727 (ISSN) ; Mahjoub, A. R ; Taghavinia, N ; Sharif University of Technology
Abstract
Superstrate configuration CuInS2 (CIS) solar cells are fabricated using a spray pyrolysis method. We avoided selenization process, cyanide etching and CdS buffer layer, to keep the process 'green'. CIS layers are formed by spray pyrolysis of an aqueous precursor ink containing metal chloride salts and thiourea at 350 °C. We investigated the effect of intentional Zn doping on structural, morphological and photovoltaic response of the fabricated CIS films by dissolving ZnCl2 in aqueous precursor solution. At a zinc doping level ranging between 0.25 and 1.00 mol%, Zn doping is found to improve the CIS crystal growth and surface morphology of CIS films. Compared with the performance of the...
Wake and structure model for simulation of cross-flow/in-line vortex induced vibration of marine risers
, Article Journal of Vibroengineering ; Volume 20, Issue 1 , February , 2018 , Pages 152-164 ; 13928716 (ISSN) ; Mazaheri, S ; Tabeshpour, M. R ; Sharif University of Technology
JVE International
2018
Abstract
Three dimensional responses of riser subjected to Vortex Induced Vibration (VIV) are investigated. Proportionality relations of stress and fatigue damage are mentioned. A computer code has been developed for time domain modeling of VIV of riser accounting for both Cross-Flow (CF) and In-Line (IL) vibration. The wake oscillator model is used to calculate the VIV of each strip. The wake oscillators are coupled to the dynamics of the long riser, while the Newmark-beta method is used for evaluating the structural dynamics of riser. The wake dynamics, including IL and CF vibrations, is represented using a pair of non-linear Van der Pol equations that solved using modified Euler method. The...
A Rapid synthesis of vertically aligned taper-like k-doped zno nanostructures to enhance dye-sensitized solar cell efficiency
, Article JOM ; Volume 71, Issue 12 , 2019 , Pages 4850-4856 ; 10474838 (ISSN) ; Musavi, M ; Nanchian, H ; Pezeshkzadeh, S. A ; Sharif University of Technology
Springer
2019
Abstract
Large-scale K-doped ZnO nanotapers were successfully grown on an indium tin oxide (ITO) substrate using a facile electrochemical route. The structural and morphologic analysis exhibited that the K-doped ZnO nanostructures had a nanotaper morphology and strong preferential [0001] c-axis direction with a hexagonal polycrystalline structure. The optical results show that the incorporation of K+ ions as the donors in a ZnO lattice leads to substantial modulation of the band gap structure of ZnO nanotapers, which results in a redshift in the ultraviolet emission peaks. The considerable enhancement of performance in K-doped ZnO-based dye-sensitized solar cells (DSSCs) can be related to the doping...
Designing highly stable yet efficient solar cells based on a new triple-cation quasi-2D/3D hybrid perovskites family
, Article Ceramics International ; Volume 45, Issue 16 , 2019 , Pages 20788-20795 ; 02728842 (ISSN) ; Abdizadeh, H ; Mirhosseini, M ; Taghavinia, N ; Sharif University of Technology
Elsevier Ltd
2019
Abstract
In a nutshell, this study outlines the efficacy of mixed dimensional (2D/3D) hybrid perovskites by developing a new class of triple-cation quasi-2D perovskites having (S0.97S′0.03)2[Cs0.05(FA0.97MA0.03)0.95]n-1Pbn(I0.07Br0.03)3n+1 general composition, in which a mixture of ý5-ammonium valeric acid ýiodideý (S) and tetra-n-octylammonium ýbromide (S′) was employed ýas a spacer.ý The effect of the 2D and 3D structures molar ratios (i.e., C=2D/2D+3D) in the range of 0-100 % on photovoltaic performance of the deposited photoanodes was systemically studied. Drawing a comparison between such compounds and an analogous triple-cation 3D counterpart (i.e., Cs0.05(FA0.83MA0.17)0.95Pb(I0.83Br0.17)3) as...
Optimization of CuIn1-XGaXS2 Nanoparticles and Their Application in the Hole-Transporting Layer of Highly Efficient and Stable Mixed-Halide Perovskite Solar Cells
, Article ACS Applied Materials and Interfaces ; Volume 11, Issue 34 , 2019 , Pages 30838-30845 ; 19448244 (ISSN) ; Marandi, M ; Khosroshahi, R ; Malekshahi Byranvand, M ; Dehghani, M ; Zad, A. I ; Tajabadi, F ; Taghavinia, N ; Sharif University of Technology
American Chemical Society
2019
Abstract
Inorganic hole-transport materials (HTMs) have been frequently applied in perovskite solar cells (PSCs) and are a promising solution to improve the poor stability of PSCs. In this study, we investigate solution-processed copper indium gallium disulfide (CIGS) nanocrystals (NCs) as a dopant-free inorganic HTM in n-i-p type PSCs. Moreover, Cs0.05(MA0.17-FA0.83)0.95Pb(I0.83Br0.17)3 mixed-halide perovskite with proper crystalline quality and long-time stability was utilized as the light-absorbing layer under ambient conditions. To optimize the cell performance and better charge extraction from the perovskite layer, the Ga concentration in the Cu(In1-XGaX)S2 composition was changed, and the X...
Impact of indium substitution on dielectric and magnetic properties of Cu 0.5 Ni 0.5 Fe 2-x O 4 ferrite materials
, Article Ceramics International ; Volume 45, Issue 10 , 2019 , Pages 13431-13437 ; 02728842 (ISSN) ; Khan, M. A ; Akhtar, M. N ; Hussain, A ; Warsi, M. F ; Sharif University of Technology
Elsevier Ltd
2019
Abstract
Indium substituted Cu[sbnd]Ni nanoferrites with nominal compositions Cu 0.5 Ni 0.5 In x Fe 2-x O 4 (x = 0.00–0.32)were successfully synthesized by sol-gel auto ignition method. X-ray diffraction patterns illustrated the single phase spinel structure for x ≤ 0.24. The lattice parameter ‘a’ increased from 8.3349 to 8.3723 Å and then it decreased for x = 0.32. X-ray density increased from 5.43 to 5.79 g/cm 3 . The average crystallite sizes lie in the range 33.21–17.78 nm. The cell volume was increased from 579.03 to 586.86 Å 3 with the substitution of indium ions into the spinel lattice of copper nickel ferrites. The compositional dependence of tetrahedral and octahedral radii was explained on...
Effective carbon composite electrode for low-cost perovskite solar cell with inorganic CuIn0.75Ga0.25S2 hole transport material
, Article Solar RRL ; Volume 4, Issue 5 , 2020 ; Forouzandeh, M ; Khosroshahi, R ; Meraji, K ; Badrabadi, M. N ; Dehghani, M ; Li, X ; Zhan, Y ; Liao, Y ; Ning, Z ; Taghavinia, N ; Sharif University of Technology
Wiley-VCH Verlag
2020
Abstract
Perovskite solar cells are well known for being low cost, solution-based, and efficient solar cells; however, the high price of the conventional hole-collector electrode (Spiro-OMeTAD/Gold) and the high price and complexity of depositing gold on large scales are major barriers against commercializing them. Herein, an effective carbon composite electrode is introduced for a low-cost perovskite solar cell with CuIn0.75Ga0.25S2 hole transport material to solve this problem. The carbon electrode is deposited by the doctor blade method using a paste composed of flakes of graphite, carbon black, and a kind of hydrophobic polymer (polystyrene or poly-methyl methacrylate). It is investigated how the...
Effect of indium ratio in CuInxGa1-xS2/carbon hole collecting electrode for perovskite solar cells
, Article Journal of Power Sources ; Volume 475 , 2020 ; Behrouznejad, F ; Ghavaminia, E ; Khosroshahi, R ; Li, X ; Zhan, Y ; Liao, Y ; Ning, Z ; Taghavinia, N ; Sharif University of Technology
Elsevier B.V
2020
Abstract
Perovskite solar cells (PSCs) have excellent photovoltaic properties. There are, however, challenges of materials cost and device stability to be solved before commercializing them. Utilizing low-cost inorganic hole transport materials (HTM) as a replacement for spiro-OMeTAD, and replacing the Au electrode with printable carbon could be important steps in this regard. For this purpose, CuInxGa1-xS2 (x = 1, 0.75, 0.5, 0.25, 0) nanoparticle layers are deposited as inorganic HTMs with carbon composite electrode as the back electrode. Photovoltaic properties of PSCs with CuInxGa1-xS2/Carbon hole collecting electrodes are studied by changing the In ratio in the HTM layer. Results from impedance...
A novel high gain extendable dc-dc bidirectional boost-buck converter
, Article 237th ECS Meeting with the 18th International Meeting on Chemical Sensors, IMCS 2020, 10 May 2020 through 14 May 2020 ; Volume 97, Issue 7 , 2020 , Pages 845-856 ; Siavash Moakhar, R ; Soleimani, F ; Goudarzi, A ; Sadrnezhaad, S. K ; Sharif University of Technology
Institute of Physics Publishing
2020
Abstract
In-situ deposition of cupric oxide (CuO) thin films on fluorine-doped tin oxide is performed through a rapid microwave-assisted method. The duration of microwave (MW) irradiation is optimized in order to prepare efficient and stable photocathodes for photoelectrochemical (PEC) water splitting. We obtain CuO with a unique morphology consisted of intermingled nanosheets. We evaluate PEC performance of the photocathodes through Linear Sweep Voltammetry (LSV) and current stability analyses. The highest achieved photocurrent density is -1.15 mA.cm-2 at 0 V vs. RHE for the sample MW-irradiated for 60 min. This value is comparable or superior to several other CuO-based photocathodes prepared by...
Electrostatic accumulation and determination of triclosan in ultrathin carbon nanoparticle composite film electrodes
, Article Analytica Chimica Acta ; Volume 593, Issue 1 , 2007 , Pages 117-122 ; 00032670 (ISSN) ; Shahrokhian, S ; Psillakis, E ; Marken, F ; Sharif University of Technology
2007
Abstract
A film composed of carbon nanoparticles and poly(diallyldimethylammonium chloride) or CNP-PDDAC is formed in a layer-by-layer deposition process at tin-doped indium oxide (ITO) substrates. Excess positive binding sites within this film in aqueous phosphate buffer at pH 9.5 are quantified by adsorption of iron(III)phthalocyanine tetrasulfonate and indigo carmine. Both anionic redox systems bind with Langmuirian characteristics (K ≈ 105 mol-1 dm3) and show electrochemical reactivity throughout the film at different thicknesses. Therefore, the electrical conductivity in CNP-PDDAC films is good and the positive binding sites are approximately 140 pmol cm-2 per layer. Structural instability of...
Polyvinylcarbazole as an efficient interfacial modifier for low-cost perovskite solar cells with CuInS2/Carbon hole-collecting electrode
, Article Solar RRL ; Volume 5, Issue 7 , 2021 ; 2367198X (ISSN) ; Behrouznejad, F ; Forouzandeh, M ; Khosroshahi, R ; Darbari, S ; Zhan, Y ; Taghavinia, N ; Sharif University of Technology
John Wiley and Sons Inc
2021
Abstract
Different polymers have been already introduced for passivating the interfacial defects at the interface of perovskite and the organic hole transport material, meanwhile as an environmental barrier in perovskite solar cells (PSCs). Herein, polyvinylcarbazole (PVK) compared to polymethylmethacrylate (PMMA) at the interface of the perovskite (Cs0.05(MA0.83FA0.17)0.95Pb(Br0.17I0.83)3) layer and CuInS2/carbon as a low-cost inorganic hole-collecting electrode are investigated. By suppressing interfacial recombination using PMMA and PVK, saturation current density (in dark current) decreases one order of magnitude from 7.9 × 10−10 to 4.0 × 10−11 mA cm−2 by adding PMMA and two orders of magnitude...
Engineering of CIGS nanoparticle inks for colloidal stability, uniform film formation and application as HTL for perovskite solar cells
, Article Journal of Industrial and Engineering Chemistry ; 2021 ; 1226086X (ISSN) ; Tehrani, N. A ; Forouzandeh, M ; Behrouznejad, F ; Taghavinia, N ; Bagherzadeh, M ; Sharif University of Technology
Korean Society of Industrial Engineering Chemistry
2021
Abstract
In this work, synthesis of CuIn0.75Ga0.25S2 (CIGS) nanoparticles, the formation of stable dispersion, deposition of high-quality films and, fabrication of thin-film Perovskite solar cells are reported. The stability of nanoparticle ink is crucial in the formation of device-quality films. The chalcogenide-based materials are widely used in thin-film solar cells; in particular, Cu(In,Ga)S2 are used as an absorber and hole transporting layer. In the present study, the nanoparticles of about 20 nm size and bandgap of 1.5 eV are synthesized using a heat-up method. A variety of solvents are used as dispersing media and the stability of the inks is evaluated by precise optical monitoring. We...