Search for: infrared-spectrum
Article Journal of Optics (United Kingdom) ; Volume 18, Issue 10 , 2016 ; 20408978 (ISSN) ; Bagheri, A ; Khavasi, A ; Mehrany, K ; Sharif University of Technology
Institute of Physics Publishing
We propose an effective medium theory for a one-dimensional periodic array of rectangular grooves covered by a graphene sheet. Parameters of the effective medium model are given by explicit analytical expressions for both major polarizations TM and TE, and for all incident angles. In extraction of this model, we assumed single mode approximation inside the grooves. The effect of non-specular diffraction orders outside the grating, as well as the plasmonic response of the graphene sheet in the far-infrared spectrum, is addressed by introducing an effective surface conductivity at the interface of the metallic grating and the ambient environment. It is shown that surface plasmons in graphene...
Article Ceramics International ; Volume 38, Issue 4 , 2012 , Pages 3281-3290 ; 02728842 (ISSN) ; Nemati, A ; Eftekhari Yekta, B ; Hamnabard, Z ; Sharif University of Technology
The effects of SiO 2 and K 2O were investigated on the glass forming ability (GFA) and structural characteristics of CaOTiO 2P 2O 5 system. Differential thermal analyzer (DTA), X-ray diffraction (XRD), scanning electron microscopy (SEM), FT-IR and 31P magic angle spinning NMR methods were applied for characterizations of the system. Unwanted crystallization in the initial three components base glass composition was observed by adding SiO 2 and crystalline phases such as TiP 2O 7, rutile (TiO 2) and cristobalite (SiO 2) were formed in it. The results showed that K 2O prevents crystallization of glasses and promotes the formation of glass. FT-IR and X-ray diffraction showed that the addition...
Article Chemical Reviews ; Volume 111, Issue 9 , June , 2011 , Pages 5610-5637 ; 00092665 (ISSN) ; Lynch, I ; Ejtehadi, M. R ; Monopoli, M. P ; Bombelli, F. B ; Laurent, S ; Sharif University of Technology
The significant role of protein nanoparticle interactions in nanomedicine and nanotoxicity is emerging recently through the identification of the nanoparticles (NP) protein (biomolecule) corona. The dynamic layer of proteins and/or other biomolecules adsorbed to the nanoparticle surface determines how a NP interacts with living systems and thereby modifies the cellular responses to the NP. Ehrenberg and co-workers used cultured endothelium cells as a model for vascular transport of polystyrene NP with various functional groups, which showed that the capacity of the various NP surfaces to adsorb proteins was indicative of their tendency to associate with cells. The quantification of the...
Investigation of structure, vibrational and NMR spectra of oxycodone and naltrexone: A combined experimental and theoretical study, Article Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy ; Volume 79, Issue 3 , 2011 , Pages 574-582 ; 13861425 (ISSN) ; Esfandyari, M ; Taheri, S ; Heydari, A ; Sharif University of Technology
In this work, two important opioid antagonists, naltrexone and oxycodone, were prepared from thebaine and were characterized by IR, 1H NMR and 13C NMR spectroscopy. Moreover, computational NMR and IR parameters were obtained using density functional theory (DFT) at B3LYP/6-311++G* * level of theory. Complete NMR and vibrational assignment were carried out using the observed and calculated spectra. The IR frequencies and NMR chemical shifts, determined experimentally, were compared with those obtained theoretically from DFT calculations, showed good agreements. The RMS errors observed between experimental and calculated data for the IR absorptions are 85 and 105 cm-1, for the 1H NMR peaks are...
Biohybrid oxidized alginate/myocardial extracellular matrix injectable hydrogels with improved electromechanical properties for cardiac tissue engineering, Article International Journal of Biological Macromolecules ; Volume 180 , 2021 , Pages 692-708 ; 01418130 (ISSN) ; Mashayekhan, S ; Baheiraei, N ; Pourjavadi, A ; Sharif University of Technology
Elsevier B.V 2021
Injectable hydrogels which mimic the physicochemical and electromechanical properties of cardiac tissue is advantageous for cardiac tissue engineering. Here, a newly-developed in situ forming double-network hydrogel derived from biological macromolecules (oxidized alginate (OA) and myocardial extracellular matrix (ECM)) with improved mechanical properties and electrical conductivity was optimized. 3-(2-aminoethyl amino) propyltrimethoxysilane (APTMS)-functionalized reduced graphene oxide (Amine-rGO) was added to this system with varied concentrations to promote electromechanical properties of the hydrogel. Alginate was partially oxidized with an oxidation degree of 5% and the resulting OA...
An efficient biosurfactant-producing bacterium pseudomonas aeruginosa MR01, isolated from oil excavation areas in south of Iran, Article Colloids and Surfaces B: Biointerfaces ; Volume 69, Issue 2 , 2009 , Pages 183-193 ; 09277765 (ISSN) ; Shourian, M ; Roostaazad, R ; Rouholamini Najafabadi, A ; Adelzadeh, M. R ; Akbari Noghabi, K ; Sharif University of Technology
A bacterial strain was isolated and cultured from the oil excavation areas in tropical zone in southern Iran. It was affiliated with Pseudomonas. The biochemical characteristics and partial sequenced 16S rRNA gene of isolate, MR01, was identical to those of cultured representatives of the species Pseudomonas aeruginosa. This bacterium was able to produce a type of biosurfactant with excessive foam-forming properties. Compositional analysis revealed that the extracted biosurfactant was composed of high percentages lipid (∼65%, w/w) and carbohydrate (∼30%, w/w) in addition to a minor fraction of protein (∼4%, w/w). The best production of 2.1 g/l was obtained when the cells were grown on...