Sharif Digital Repository

The corrosion inhibition effect of zinc acetylacetonate (ZAA) and benzothiazole (BTH) mixture was evaluated for mild steel in 3.5% NaCl solution. To this end, ZAA:BTH mixtures ranged from 6:1 to 1:6 mol ratios were examined by weight loss and open circuit potential to obtain optimal mole ratio. The optimal mixture of ZAA:BTH at 1:5 mol ratio showed a significant corrosion inhibition efficiency proved by electrochemical impedance spectroscopy and polarization studies. The addition of the optimal mixture of ZAA:BTH to epoxy coating showed a considerable increase of corrosion protection evaluated by salt spray exposure  

Electrochemical potential noise analysis was used to investigate corrosion behavior of copper electrodes in presence of 0.001, 0.005, 0.01 and 0.02 M benzotriazole (BTA) inhibitor. Energy distribution of the potential noise was obtained from wavelet transformation using the 4th order Daubechies pattern. Two lowest frequencies were added-up and fitted to the impulse response of the first order circuit to achieve the time-constant vs. concentration (T-C) diagram. T-C diagram can be used either as a conventional diagram of inhibition efficiency or a tool for evaluation of the surface film dielectric constant. The assumptions made in this treatment were confirmed by EIS method. © 2009 Elsevier... 

In this study, effects of dried saffron purple petals (SPP) powder were examined on the rheological, fluid loss, and corrosion inhibition properties of bentonite-based drilling fluids. Drilling fluids containing different amounts of the SPP powder were prepared and their rheological behavior was investigated via the rotary viscometry and rheometric mechanical spectroscopy (RMS). Rotary viscometer results were fitted with Power-law, Bingham plastic, and Herschel-Bulkley models and the obtained data were compared with that of the base mud. All models fitted the rotary viscometer data with the determination coefficients higher than 0.93. The presence of 3 wt% of the SSP in the fluid... 

Seawater, which has been frequently applied in cooling and injection water systems, imposes severe pitting corrosion to mild steel. Addition of green and sustainable inhibitors based on renewable sources is one of the promising methodologies for restricting metal corrosion in chloride-containing electrolytes. In this study, for the first time, from both theoretical and experimental faces, the role of Juglans regia green fruit shell (JRS) extract as a sustainable potent corrosion inhibitor for mild steel was studied. The chemical structure of the JRS extract was deliberated by Fourier transform infrared spectroscopy (FT-IR). By electrochemical techniques including polarization, EIS and... 

In this study, the different parts of carthamus tinctorius plant, including petal (SPE), leaf (SLE), and shoot (SSE), have been extracted. Adsorption of the extracts on mild steel in 3.5 wt. % NaCl solution was evaluated employing electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, and electrochemical noise measurements (EN). The field-emission scanning electron microscopy (FE-SEM) and attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) were employed to appraise the morphology of the samples surface subjected to the test solutions. According to the EIS results, the maximum adsorption efficiency belonged to the solution containing 1 g L−1 of...