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inorganic-organic-hybrid-materials
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Preparation of a Polyoxotungstate-Based Inorganic-Organic Hybrid Catalyst and the Application in Sulfide Oxidation and Azide-Alkyne Cycloaddition Reactions
, M.Sc. Thesis Sharif University of Technology ; Bagherzadeh, Mojtaba (Supervisor)
Abstract
In this study polyoxotungstate-based inorganic-organic hybrid [C272H162N80Cu16.5W36O129Na9] .80.5H2O was synthesized in situ. This inorganic-organic hybrid resulted from the reaction between copper salt and sodium tungstate with the benzimidazole ligand. Combining inorganic-organic hybrid with polyoxotungstate improved the ability of this catalytic system in oxidation and cycloaddition reactions. The resulting product was identified by IR, X-ray diffraction (XRD), elemental analysis (CHNS), inductively coupled plasma (ICP-OES), field emission scanning electron microscope (FE-SEM) and EDX were technique. The catalyst was used in optimal conditions in sulfide oxidation and azide-alkyne...
Synthesis and Characterization of Transition Metal Complexes Supported on Carbon-Based Nanocomposites and Their Application as Gene and Drug Delivery Systems
, Ph.D. Dissertation Sharif University of Technology ; Bagherzadeh, Mojtaba (Supervisor)
Abstract
In this dissertation, an attempt has been made to optimize some smart nanocarriers and the controllable release of drug (doxorubicin) and genetic material (plasmid CRISPR). Regarding, some metal nanoparticles, metal-organic frameworks, transition metal complexes, graphene oxide, and functionalized carbon nanotubes have been synthesized and also characterized and their hybrids and nanocomposites have been prepared successfully. All the abovementioned nanomaterials were designed and synthesized due to achieve biodegradable, biocompatible, higher positive surface potential, lower cytotoxicity, better responsivity to stimulus, and greener compounds. Doxorubicin and plasmid CRISPR has been...
Magnetic inorganic-organic hybrid nanomaterial for the catalytic preparation of bis(indolyl)arylmethanes under solvent-free conditions: Preparation and characterization of H5PW10V 2O40/pyridino-Fe3O4 nanoparticles
, Article Applied Catalysis A: General ; Volume 468 , 2013 , Pages 75-87 ; 0926860X (ISSN) ; Amini, M. M ; Abdollahi, N ; Aliakbari, A ; Rabiei, S ; Ramshini, H ; Sharif University of Technology
2013
Abstract
Magnetically separable inorganic-organic hybrid material H 5PW10V2O40/pyridino-Fe 3O4 (HPA/TPI-Fe3O4) nanoparticles provide an efficient and economic route for the synthesis of substituted bis(indolyl)methanes by the electrophilic substitution of indole with various aldehydes and ketones under solvent-free conditions with excellent yields in <30 min. This catalyst was prepared by the chemically anchoring H 5PW10V2O40 onto Fe3O 4 nanoparticles via the use of N-[3-(triethoxysilyl)propyl] isonicotinamide (TPI) linker. High catalytic activity and ease of recovery using an external magnetic field are additional eco-friendly attributes of this new catalytic system. The catalyst was recycled at...