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    Novel multifunctional capacitor-varistor ceramics based on SnO2

    , Article Ceramics International ; Volume 44, Issue 16 , 2018 , Pages 20386-20390 ; 02728842 (ISSN) Maleki Shahraki, M ; Alipour, S ; Mahmoudi, P ; Karimi, A ; Sharif University of Technology
    Elsevier Ltd  2018
    Abstract
    Up to now, multifunctional varistor-capacitor materials were based on TiO2, even though these materials failed to have practical applications. For the first time, in this research, multifunctional varistor-capacitor properties are observed in the CuO-doped SnO2-CoO-Sb2O3 system. The XRD analysis showed that this system has a single phase microstructure. SEM images indicated that the CuO addition resulted in a better densification and larger grain size. The very low electric breakdown field of the CuO-doped SnO2-CoO-Sb2O3 system (12 V/mm, similar to TiO2), is a consequence of coarse-grained microstructure. This varistor had a suitable surge withstand capability as well. The colossal... 

    Stable high dielectric properties in (Cr, Nb) co-doped SnO2 ceramics

    , Article Materials Chemistry and Physics ; Volume 246 , May , 2020 Maleki Shahraki, M ; Golmohammad, M ; Chermahini, M. D ; Mahmoudi, P ; Moghadam, H. A ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    In this research, the microstructure, dielectric, and non-Ohmic properties of (Cr, Nb) co-doped SnO2 ceramics, (Cr0.5, Nb0.5)xSn1-xO2 with x% = 0, 0.5, 1.0, 2.0, 5.0, and 10.0, as a colossal dielectric material and a prospective alternative to co-doped TiO2 ceramics were studied. The X-ray diffraction results indicated that in all compositions, the cassiterite phase was achieved without any secondary phases. Moreover, field-emission secondary electron microscopy showed that the microstructure of samples has different morphologies including typical grains, enlarged grains and prism-like grains microstructure for various sintered samples. The maximum dielectric constant (2737) accompanied by...