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    On variations of the interphase thickness and the slope of strengthening by clay addition in exfoliated polymer-clay nanocomposites

    , Article Polymer (United Kingdom) ; Volume 90 , 2016 , Pages 302-308 ; 00323861 (ISSN) Goodarzi Hosseinabadi, H ; Khederlou, Kh ; Payandehpeyman, J ; Bagheri, R ; Sharif University of Technology
    Elsevier Ltd 
    Abstract
    Polymer-clay nanocomposites (PCNs) have received intensive attention in recent years because of their wide domain of applications. The present report provides an approach to calculate the thickness of nanometric interphase region in exfoliated PCNs based on the information about their macroscopic modulus and their nanoclay content. First, the concept of interphase region in PCNs is explained with an “algae explanation”. Then, a series of parametric finite element simulations together with analytical equations are employed to derive an explicit relationship between the interphase thickness and the PCN macroscopic modulus. The obtained analytical model considers the structural impact of the...