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A water-oxidizing dinuclear iron complex as an efficient catalyst toward organic sulfide oxidation
, Article Journal of Coordination Chemistry ; Vol. 67, issue. 18 , Jul , 2014 , p. 3026-3032 ; Najafpour, M. M ; Zare, M ; Holynska, M ; Moghaddam, A. N ; Bagherzadeh, M ; Sharif University of Technology
Abstract
In this paper, we report that a known dinuclear Fe complex, [tpa(H2O)FeOFe(H2O)tpa](ClO4)4 (tpa: tris(2-pyridylmethyl)amine), is an efficient catalyst toward organic sulfide oxidation in the presence of urea-hydrogen peroxide
Synthesis, characterization and catalytic study of a novel iron(III)-tridentate Schiff base complex in sulfide oxidation by UHP
, Article Inorganic Chemistry Communications ; Volume 12, Issue 1 , 2009 , Pages 21-25 ; 13877003 (ISSN) ; Amini, M ; Sharif University of Technology
2009
Abstract
An hydrazone Schiff base-iron(III) complex using salicylidene benzoyl hydrazine (L) as ligand has been synthesized and characterized by elemental analyses, IR, 1H and 13C NMR and UV-Vis spectroscopy. Oxidation of sulfides to sulfoxides in one-step was conducted by this complex catalyst using urea hydrogen peroxide (UHP) in mixture of CH2Cl2/CH3OH (1:1) under air at room temperature. The effect of the reaction conditions on the oxidation of methylphenylsulfide was studied by varying the amount of the catalyst, reaction temperature, reaction time and the amount of UHP. The results showed that using this system in the oxidation of sulfides, sulfoxides were obtained as the main products,...
Investigation of the reaction of allyl(cyclopentadienyl)iron(II) dicarbonyl with iminium salts: Synthesis of ammonium salts of substituted five-membered-ring iron complexes
, Article Organometallics ; Volume 26, Issue 1 , 2007 , Pages 201-203 ; 02767333 (ISSN) ; Ziyaei Halimehjani, A ; Saidi, M. R ; Sharif University of Technology
2007
Abstract
Series of quaternary ammonium salts of substituted five-membered-ring iron complexes were prepared by reaction of allyl(cyclopentadienyl)iron(II) dicarbonyl with iminium salts. Also, reactions of allyl-(cyclopentadienyl) iron(II) dicarbonyl with in situ prepared iminium salts afford the same products in good to excellent isolated yields. © 2007 American Chemical Society
Synthesis and Study of Catalytic Activity of Iron (III)-bis(2-oxazolinyl) Methane complex by Urea Hydrogen Peroxide in Oxidation of Sulfides
, M.Sc. Thesis Sharif University of Technology ; Bagherzadeh, Mojtaba (Supervisor)
Abstract
Considerable effort has been directed in recent years towards the transition metal complex catalyzed oxidation of organic compounds. Herein the synthsis of the iron complex of bis(oxazoline) ligand as a novel catalyst is reported, and the catalytic activity of this complex in oxidation of sulfides is investigated. Bis(2-oxazolynil)methane as ligand is prepared by condensation of diethylmalonate with 2-aminoethanole in 1:2 molar ratio and finally corresponding complex is synthesized by the reaction between FeCl3.6H2O and Bis(2-Oxazolynil)methane in 1:1 molar ratio. The complex is characterized by using IR, UV-Vis, cyclic voltametery, conductometery and elemental analysis data. Moreover,...
Oxidative Degradation of Methylene Blue by Nano-Sized Particles of Metal Oxides and Synthesis, Characterization and Catalytic Activity of Novel Mo and Fe Complexes in Oxidation Reactions
, Ph.D. Dissertation Sharif University of Technology ; Mohammadi Boghaei, Davar (Supervisor) ; Amini, Mojtaba (Supervisor)
Abstract
In the first part of this thesis, the application of metal oxide nanoparticles in oxidative degradation of methylene blue is discussed. Nanoparticles of manganese tungstate (MnWO4) were prepared via an impregnation method using Mn(NO3)2.4H2O and WO3 as a source of Mn and W, respectively. The morphology of the manganese tungstate nanoparticles was studied in detail by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). MnWO4 nanoparticles showed severe catalytic performance for the degradation of organic dye (methylene blue) in the presence of tertiary-butyl hydrogen peroxide, TBHP, as the oxidant at room temperature in water. Mn doped ZnO...
Synthesis and Characterization of Various Transition Metal Complexes and the Application in Oxidation, Heck, Suzuki, Sonogashira and Olefin Metathesis
, Ph.D. Dissertation Sharif University of Technology ; Bagherzadeh, Mojtaba (Supervisor)
Abstract
In nature, catalysis is of vital importance in a wide variety of biochemical processes catalyzed by metalloenzymes. The functions performed by the metalloenzymes and their significance have inspired a range of biomimetic studies, and intense efforts have been concentrated on the synthesis of low molecular weight complexes to model the spectroscopic features of such enzymes. Concomitantly, a challenging frontier in the field of biomimetic chemistry is the development of highly reactive model compounds that are able to effect rapid and selective substrate conversion. Some important catalytic transformations that have gained attention in recent years involve the carbon-carbon coupling, olefin...
A novel iron complex containing an N,O-type bidentate oxazoline ligand: Synthesis, X-ray studies, DFT calculations and catalytic activity
, Article Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy ; Vol. 133, issue , Jun , 2014 , p. 432-438 ; Arab, A ; Derakhshandeh, P. G ; Bagherzadeh, M ; Ellern, A ; Woo, L. K ; Sharif University of Technology
Abstract
A five-coordinated Fe(III) complex with the distorted trigonal bipyramidal configuration was synthesized by reactions of FeCl36H2O and 2-(2′-hydroxyphenyl)oxazoline (Hphox) as a bidentate ON donor oxazoline ligand. Complex [Fe(phox)2Cl] was fully characterized, including by single-crystal X-ray structure analysis. DFT calculations were accompanied with experimental results in order to obtain a deeper insight into the electronic structure and vibrational normal modes of complex. Oxidation of sulfides to sulfoxides in one-step was conducted by this complex as catalyst using urea hydrogen peroxide (UHP) in mixture of CH2Cl 2/CH3OH (1:1) under air at room temperature. The results show that using...