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    As, Sb, and Fe removal from industrial copper electrolyte by solvent displacement crystallisation technique

    , Article Canadian Metallurgical Quarterly ; 2018 ; 00084433 (ISSN) Shabani, A ; Hoseinpur, A ; Yoozbashizadeh, H ; Vahdati Khaki, J ; Sharif University of Technology
    Taylor and Francis Ltd  2018
    Abstract
    The presence of impurities in the copper electrolyte increases the energy consumption of an electrorefining process and contaminates the deposited copper on cathode. The concentration of impurities increases over time making it necessary to remove them from the solution. This research introduces a fast, effective, and simple method to refine the industrial electrolyte from arsenic, iron and antimony by solvent displacement crystallisation technique. In this method, when alcohol is added to the electrolyte, the impurities precipitate from the solution as amorphous arsenato antimonite phase. Results show that Fe, Sb, and As are removed from the copper electrolyte by 75.2, 96.9 and 99.8%,... 

    As, Sb, and Fe removal from industrial copper electrolyte by solvent displacement crystallisation technique

    , Article Canadian Metallurgical Quarterly ; Volume 58, Issue 3 , 2019 , Pages 253-261 ; 00084433 (ISSN) Shabani, A ; Hoseinpur, A ; Yoozbashizadeh, H ; Vahdati Khaki, J ; Sharif University of Technology
    Taylor and Francis Ltd  2019
    Abstract
    The presence of impurities in the copper electrolyte increases the energy consumption of an electrorefining process and contaminates the deposited copper on cathode. The concentration of impurities increases over time making it necessary to remove them from the solution. This research introduces a fast, effective, and simple method to refine the industrial electrolyte from arsenic, iron and antimony by solvent displacement crystallisation technique. In this method, when alcohol is added to the electrolyte, the impurities precipitate from the solution as amorphous arsenato antimonite phase. Results show that Fe, Sb, and As are removed from the copper electrolyte by 75.2, 96.9 and 99.8%,... 

    Synthesis of magnetic mesoporous nanocomposites: A promising candidate for diagnostic and therapeutic biomedical applications

    , Article Materials Chemistry and Physics ; Volume 167 , November , 2015 , Pages 201-208 ; 02540584 (ISSN) Bagherzadeh, E ; Hosseini, H. R. M ; Khakzadian, J ; Sharif University of Technology
    Elsevier Ltd  2015
    Abstract
    In the present research, iron oxide nanoparticles were synthesized through the hydrothermal method, and the influence of processing parameters such as pH of the initial coprecipitation reaction, time and temperature of hydrothermal treatment was studied. The magnetic iron oxide nanoparticles were coated with a negatively charged, thin layer of silica. The product is then coated with a layer of mesoporous silica. As a result of the electrostatic attraction between the cationic CTAB and the primary silica coating, the formation of mesoporous silica would be mainly localized on the surface of nanoparticles. Calcination was performed in an argon atmosphere tube furnace at 550 °C, through which...