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    Impact of ionic composition on modulating wetting preference of calcite surface: Implication for chemically tuned water flooding

    , Article Colloids and Surfaces A: Physicochemical and Engineering Aspects ; Volume 568 , 2019 , Pages 470-480 ; 09277757 (ISSN) Saeedi Dehaghani, A. H ; Badizad, M. H ; Sharif University of Technology
    Elsevier B.V  2019
    Abstract
    Despite previous researches on ion-engineered waterflooding (IEWF), its underlying mechanisms are not fully understood, particularly in presence of additives, like surfactants. This paper concerned with the contribution of Ca 2+ , Mg 2+ , SO 4 2- and Na + into altering wettability of oil-wet carbonate minerals towards water preferred state. As a mechanistic study, an experiment workflow was conducted to probe the impact of ions' concentrations in SW, either with or without sodium dodecylbenzene sulfonate (SDBS) which is an anionic surfactant. At first, contact angle (CA) measurement was carried out to evaluate the degree of wettability reversal upon treating the oil-aged calcite slabs with... 

    Green synthesis of PEG-coated MIL-100(Fe) for controlled release of dacarbazine and its anticancer potential against human melanoma cells

    , Article International Journal of Pharmaceutics ; Volume 618 , 2022 ; 03785173 (ISSN) Barjasteh, M ; Vossoughi, M ; Bagherzadeh, M ; Pooshang Bagheri, K ; Sharif University of Technology
    Elsevier B.V  2022
    Abstract
    In this study, the potential of using MIL-100(Fe) metal–organic framework (MOF) for loading and controlling the release of dacarbazine (DTIC) was evaluated for in vitro treatment of melanoma. The drug loading was performed during the green synthesis of MIL-100(Fe) in an aqueous media without using any harmful solvents, to obtain MIL-DTIC. The surface of this structure was then coated with polyethylene glycol (PEG) in the same aqueous solution to synthesize MIL-DTIC-PEG. The synthesized samples were characterized using various methods. Their release profile was studied in phosphate-buffered saline (PBS) and simulated cutaneous medium (SCM). The cytotoxicity of DTIC and its nano-MOF...