Sharif Digital Repository

Precipitation and scaling of calcium sulfate have been known as major problems facing process industries and oilfield operations. Most scale prediction models are based on aqueous thermodynamics and solubility behavior of salts in aqueous electrolyte solutions. There is yet a huge interest in developing reliable, simple, and accurate solubility prediction models. In this study, a comprehensive model based on least-squares support vector machine (LS-SVM) is presented, which is mainly devoted to calcium sulfate dihydrate (or gypsum) solubility in aqueous solutions of mixed electrolytes covering wide temperature ranges. In this respect, an aggregate of 880 experimental data were gathered from... 

The burning of fossil fuels such as gasoline, coal, oil, natural gas in combustion reactions results in the production of carbon dioxide. The phase behavior of the carbon dioxide + water system is complex topic. Unlike methane, CO2 exhibits a minimum in the water content. These minima cannot be predicted by existing methods accurately. In this communication, two mathematical-based procedures have been proposed for accurate computation of CO2 water content for tempe-ratures between 273.15 and 348.15 K and the pressure range between 0.5 and 21 MPa. The first is based on least squares support vector machine (LSSVM) algorithm and the second applies multilayer perceptron (MLP) artificial neural... 

Permeability as a fundamental reservoir property plays a key role in reserve estimation, numerical reservoir simulation, reservoir engineering calculations, drilling planning, and mapping reservoir quality. In heterogeneous reservoir, due to complexity, natural heterogeneity, non-uniformity, and non-linearity in parameters, prediction of permeability is not straightforward. To ease this problem, a novel mathematical robust model has been proposed to predict the permeability in heterogeneous carbonate reservoirs. To this end, a fairly new soft computing method, namely least square support vector machine (LSSVM) modeling optimized with coupled simulated annealing (CSA) optimization technique... 

Deposition of barium sulfate (or BaSO4) has already been recognized as a devastating problem facing process industries and oilfield operations, mainly owing to its low solubility in aqueous solutions. Predicting and also preventing the overall damage caused by BaSO4 precipitation requires a profound knowledge of its solubility under different thermodynamic conditions. The main aim of this study is to develop a solubility prediction model based on a hybrid of least squares support vector nachines (LSSVM) and coupled simulated annealing (CSA) aiming to predict the solubility of barium sulfate over wide ranges of temperature, pressure and ionic compositions. Results indicate that predictions of... 

Due to problems followed by asphaltene deposition, which cause many remedial processes and costs, it seemed necessary to develop equations for determining asphaltene precipitation quantitatively or qualitatively. In this study a new scaling equation as a function of temperature, molecular weight, and dilution ratio (solvent) has been developed. This equation can be used to determine the weight percent of precipitated asphaltene in the presence of different precipitants (solvents). The proposed methodology utilizes least square support vector machines/regression (LSSVM/LSSVR) to perform nonlinear modeling. This paper proposes a new feature selection mechanism based on coupled simulated... 

In this investigation, application of the least square support vector machine (LSSVM) for modeling of the electrical resistivity of the magnetic Zn-Mn-S nanocrystalline semiconductor films has been described. The model has been trained based on the experimental data obtained from a published work by Sreekantha Reddy et al. The model inputs are temperature and variations in the concentrations of Zn, Mn. The results indicate that LSSVM is able to be used for accurate prediction of the electrical resistivity of the Zn-Mn-S nanocrystalline semiconductor films  

Nitrogen has been valued as an economical alternative injection gas for gas-based enhanced oil recovery (EOR) processes. Minimum miscibility pressure (MMP) is the most important parameter to successfully design N2 flooding. In this communication, a data bank covering wide ranges of thermodynamic and compositional conditions was gathered from open literature. Afterward, a rigorous approach, namely least square support vector machine (LSSVM) optimized with coupled simulated annealing (CSA) was proposed to develop a reliable and robust model for the prediction of MMP of pure/impure N2–crude oil. The results of this study showed that the proposed model is more reliable and accurate than the... 

The higher heating value (HHV) parameter of biomass is well known for its wide application in bioenergy industry and the economical study of energy resources. In the present study, the least squares support vector machine (LSSVM) strategy is used as a novel approach to estimate HHV of biomass as a function of volatile matters (VM), fixed carbon (FC), and ash content (ASH). A total number of 350 experimental data points have been extracted from previous works to train and test the proposed algorithm. In order to judge the proposed model, the statistical parameters such as R2, RMSE, and AARD are calculated as 0.92936, 4.2731%. Based on the calculated parameters, it can be concluded that the... 

Precipitation of strontium sulfate (or SrSO4) has already been distinguished as one of the most costly and critical problems which may occur in process industries and oilfield operations. Costs due to scaling and remedial actions that need to be taken afterward are generally high owing to low solubility of SrSO4 in aqueous solutions. Therefore, a thorough understanding of the SrSO4 thermodynamic behavior under various operating conditions is vital to predict or even avoid the overall damage caused by scaling. The primary aim of this work is to develop a model based on Least Squares Support Vector Machine (LSSVM) and Coupled Simulated Annealing (CSA) referred to as CSA-LSSVM to predict... 

Through this work, a novel mathematical-based approach was proposed to develop reliable models for calculation of PVT properties of crude oils at various reservoir conditions. For this purpose, a new soft computing approach namely Least Square Support Vector Machine (LSSVM) modeling optimized with Coupled Simulated Annealing (CSA) optimization technique was implemented. The constructed models are evaluated by carrying out extensive experimental data reported in open literature. Results obtained by the proposed models were compared with the corresponding experimental values. Moreover, in-depth comparative studies have been carried out between these models and all other predictive models. The... 

Appropriate execution of drilling operation, in particular for high pressure and high temperature wells, requires accurate knowledge of behavior of the drilling fluid density as a function of pressure and temperature. In this communication, a novel mathematicalbased approach is presented to develop a reliable model for predict the density of four drilling fluid including water-based, oil-based, Colloidal Gas Aphron (CGA) and synthetic. To pursue our objective, a predictive model is proposed using a robust soft computing approach namely least square support vector machine (LSSVM) modeling optimized with coupled simulated annealing (CSA) optimization tool. Moreover, leverage approach, in which... 

Estimation of the viscosity of naturally occurring petroleum gases is essential to provide more accurate analysis of gas reservoir engineering problems. In this study, a new soft computing approach, namely, least square support vector machine (LSSVM) modeling, optimized with a coupled simulated annealing technique was applied for estimation of the natural gas viscosities at different temperature and pressure conditions. This model was developed based on 2485 viscosity data sets of 22 gas mixtures. The model predictions showed an average absolute relative error of 0.26% and a correlation coefficient of 0.99. The results of the proposed model were also compared with the well-known predictive... 

Accurate knowledge of pure hydrocarbon and natural gas viscosity is essential for reliable reservoir characterization and simulation as well as economic design of natural gas processing and transport units. The most trustable sources of pure hydrocarbon and natural gas viscosity values are laboratory experiments. When there is no available experimental data for the required composition, pressure, and temperature conditions, the use of predictive methods becomes important. In this communication, a novel approach was proposed to develop for prediction of viscosity of pure hydrocarbons as well as gas mixtures containing heavy hydrocarbon components and impurities such as carbon dioxide,... 

In this study, a reliable and predictive model namely, least-squares support vector machine (LS-SVM) was developed to predict dye removal efficiency. Four LS-SVM models have been developed and tested using more than 630 series of experimental data which were obtained from our previous paper. These data consist of adsorbate type, adsorbent dosage, initial dye concentration, salt, absorbance time and dye removal efficiency. Direct Red 31 (DR31), Direct Green 6 (DG6) and Acid Blue (AB92) were used as a model dyes. The results show that the developed model is more accurate and reliable with the average absolute relative deviation of 0.678%, 0.877%, 0.581% and 0.978% for single systems and... 

Viscosity of crude oil is a fundamental factor in simulating reservoirs, forecasting production as well as planning thermal enhanced oil recovery methods which make its accurate determination necessary. Experimental determination of reservoir oil viscosity is costly and time consuming. Hence, searching for quick and accurate determination of reservoir oil viscosity is inevitable. The objective of this study is to present a reliable, and predictive model namely, Least-Squares Support Vector Machine (LSSVM) to predict reservoir oil viscosity. To this end, three LSSVM models have been developed for prediction of reservoir oil viscosity in the three regions including, under-saturated, saturated... 

Vapor liquid equilibrium (VLE) data has significant role in designing processes which include vapor and liquid in equilibrium. Since it is impractical to measure equilibrium data at any desired temperature and pressure, particularly near critical region, thermodynamic models based on equation of state (EOS) are usually used for VLE estimating. In recent years due to the development of numerical tools like artificial intelligence methods, VLE prediction has been find new alternatives. In the present study a novel method called Least-Squares Support Vector Machine (LSSVM) used for predicting bubble/dew point pressures of binary mixtures containing carbon dioxide (CO 2) + cyclic compounds as... 

Demands for hydrocarbon production have been increasing in recent decades. As a tertiary production processes, chemical flooding is one of the effective technologies to increase oil recovery of hydrocarbon reservoirs. Retention of surfactants is one of the key parameters affecting the performance and economy of a chemical flooding process. The main parameters contribute to surfactant retention are mineralogy of rock, surfactant structure, pH, salinity, acidity of the oil, microemulsion viscosity, co-solvent concentration, and mobility. Despite various theoretical studies carried out so far, a comprehensive and reliable predictive model for surfactant retention is still found lacking. In this... 

Multiple contact miscible floods such as injection of relatively inexpensive gases into oil reservoirs are considered as well-established enhanced oil recovery (EOR) techniques for conventional reservoirs. A fundamental factor in the design of gas injection project is the minimum miscibility pressure (MMP), whereas local sweep efficiency from gas injection is very much dependent on the MMP. Slim tube displacements, and rising bubble apparatus (RBA) are two main tests that are used for experimentally determination of MMP but these tests are both costly and time consuming. Hence, searching for quick and accurate mathematical determination of gas-oil MMP is inevitable. The objective of this... 

In the design of a carbon dioxide capture and storage (CCS) process, the thermal conductivity of carbon dioxide is of special concern. Hence, it is quite important to search for a quick and accurate determination of thermal conductivity of CO2 for precise modeling and evaluation of such a process. To achieve this aim, a robust computing methodology, entitled least square support vector machine (LSSVM) modeling, which is coupled with an optimization approach, was used to model this transport property. The model was constructed and evaluated employing a comprehensive data bank (more than 550 data series) covering wide ranges of pressures and temperatures. Before constructing the model, outlier... 

Various parameters affect thermal conductivity of nanofluid; however, some of them are more influential such as temperature, size and type of nano particles and volumetric concentration. In this study, artificial neural network as well as least square support vector machine (LSSVM) are applied in order to predict thermal conductivity ratio of alumina/water nanofluid as a function of particle size, temperature and volumetric concentration. LSSVM, Self-Organizing Map and Levenberg-Marquardt Back Propagation algorithms are applied to predict thermal conductivity ratio. Obtained results indicated that these algorithms are appropriate tool for thermal conductivity ratio prediction. The...